Tidal variability in the water quality of an urbanized estuary

Tide and water quality data were collected concurrently in the Hackensack River estuary (HRE), a tidal tributary of the New York-new Jersey Harbor estuary. Harmonic analyses of tidal elevation data indicate that HRE tides are predominantly semidiurnal, though modulated by diurnal and fortnightly components. Nearly uniform tidal ranges (averaging approximately 1.6 m) were observed at three stations within the HRE. Periodogram estimates reveal significant tidal variability for the water quality parameter NH₄−N under dry-weather conditions. Lag correlation analyses associate NH₄−N concentration variations with water level fluctuations. Longitudinal profile plots for NH₄−N reveal a consistent pattern of tidal translations, with peak concentrations oscillating about a major wastewater discharger. These analyses suggest that the distribution of NH₄−N concentrations in the HRE is controlled primarily by major point source loadings and horizontal advection. A simplified, one-dimensional model is used to describe this distribution. Effects of tidal variability in masking water quality status and waak trends are also analyzed. These analyses highlight the potential importance of short-term water quality variability in tidal estuaries where concentration gradients are large.     

The SHAND quaternary system for evaluating the supersilicic or subsilicic crystal-chemistry of eclogite minerals, and potential new UHPM pyroxene and garnet end-members

Summary The stoichiometry of pyroxenes {^viiiX^{2+ vi}Y^{2+ iv}Z⁴⁺ ₂ O₆} and garnets {^xiiX²⁺ ₃ ^viY³⁺ ₂ ^ivZ⁴⁺ ₃ O₁₂} is re-evaluated by a theoretical crystal-chemical approach that takes into account natural phenomena that do not fit with conventional anhydrous stoichiometric mineralogy: the existence in eclogites of microinclusions of other minerals that may have been exsolved from previous supersilicic or subsilicic UHPM pyroxene or garnet. Different definitions of supersilicic and subsilicic are discussed and the one based on the ability to exsolve SiO₂ and leave behind a stoichiometric pyroxene or garnet is recommended for general adoption. The SHAND system (S = Si et al.; H = H; A = Al et al.; N = Na et al.; D = divalents) for projecting multivariate chemical space involving 23 cations and 104 selected natural or potential mineral species on to two essential diagrams (SAND and SHND) is described in full for the first time. Numerous possible chemical exchanges are considered and justified with respect to known mineral phenomena such as cation vacancies, octahedral silicon or protonation. Several new potential end-members are presented, in particular “supersilipyx”, “supersiligar” and “subsiligar”. It is suggested that small quantities of these end-members can be incorporated into UHPM solid-solutions and lead to various exsolution phenomena during eclogite exhumation.     

The reaction MgCr2O4 + SiO2 = Cr2O3 + MgSiO3 and the free energy of formation of magnesiochromite (MgCr2O4)

Low-temperature heat capacity measurements for MgCr₂O₄ have only been performed down to 52 K, and the commonly quoted third-law entropy at 298 K (106 J K⁻¹ mol⁻¹) was obtained by empirical extrapolation of these measurements to 0 K without considering the magnetic or electronic ordering contributions to the entropy. Subsequent magnetic measurements at low temperature reveal that the Néel temperature, at which magnetic ordering of the Cr³⁺ ions in MgCr₂O₄ occurs, is at ∼15 K. Hence a substantial contribution to the entropy of MgCr₂O₄ has been missed. We have determined the position of the near-univariant reaction MgCr₂O₄+SiO₂=MgSiO₃+Cr₂O₃. The reaction, which has a small positive slope in P-T space, has been bracketed at 100 K intervals between 1273 and 1773 K by reversal experiments. The reaction is extremely sluggish, and lengthy run times with a flux (H₂O, BaO-B₂O₃ or K₂O-B₂O₃) are needed to produce tight reversal brackets. The results, combined with assessed thermodynamic data for Cr₂O₃, MgSiO₃ and SiO₂, give the entropy and enthalpy of formation of MgCr₂O₄ spinel. As expected, our experimental results are not in good agreement with the presently available thermodynamic data. We obtain Δ _f H ^∘ ₂₉₈=−1759.2±1.5 kJ mol⁻¹ and S ^∘ ₂₉₈=122.1±1.0 J K⁻¹ mol⁻¹ for MgCr₂O₄. This entropy is some 16 J K⁻¹ mol⁻¹ more than the calorimetrically determined value, and implies a value for the magnetic entropy of MgCr₂O₄ consistent with an effective spin quantum number (S') for Cr³⁺ of 1/2 rather than the theoretical 3/2, indicating, as in other spinels, spin quenching. Received: 9 May 1997 / Accepted: 28 July 1997     

On the link between GPS pseudorange noise and day-boundary discontinuities in geodetic time transfer solutions

When neglecting calibration issues, the accuracy of GPS-based time and frequency transfer using a combined analysis of code and carrier phase measurements highly depends on the noise of the GPS codes. In particular, the pseudorange noise is responsible for day-boundary discontinuities which can reach more than 1 ns in the time transfer results obtained from geodetic analysis. These discontinuities are caused by the fact that the data are analyzed in daily data batches where the absolute clock offset is determined by the mean code value during the daily data batch. This pseudorange noise is not a white noise, in particular due to multipath and variations of instrumental delays. In this paper, the pseudorange noise behavior is characterized in order to improve the understanding of the origin of the large day-boundary discontinuities in the geodetic time transfer results. In a first step, the effect of short-term noise and multipath is estimated, and shown to be responsible for only a maximum of 150 ps (picoseconds) of the day-boundary jumps, with only one exception at NRC1 where the correction provides a jump reduction of 300 ps. In a second step, a combination of time transfer results obtained with pseudoranges only and geodetic time transfer results is used to characterize the long-term evolution of pseudorange errors. It demonstrates that the day-boundary jumps, especially those of large amplitude, can be explained by an instrumental effect imposing a common behavior on all the satellite pseudoranges. Using known influences as temperature variations at ALGO or cable damages at HOB2, it is shown that the approach developed in this study can be used to look for the origin of the day-boundary discontinuities in other stations.     

Geiger avalanche photodiodes as tentative light detectors for VHE gamma ray astronomy

Due to its sensitivity and speed, the detector still widely used in Cerenkov astrophysics experiments remains the PhotoMultiplier Tube (PMT). For instance, recent pathbreaking experiments in Very High Energy astrophysics (VHE), such as MAGIC and HESS, have used mainstream PMT technology [Aharonian, F. et al Astron. Astrophys. 492(1):L25–L28 (2008)]. Moreover the Cerenkov Telescope Array (CTA) which is now in its design phase, is also planed to be based on PMT’s. However, there are some disadvantages to the PMT technology: the rather poor quantum efficiency, the use of high voltages, the high cost when used in large number in a matrix arrangement and the large weight. Hence, we have investigated the possibility to design future Cerenkov telescopes based on solid state technology, specifically Geiger avalanche photodiodes. In a preliminary development test, we placed HAMAMATSU avalanche photodiodes at the focal plane of a 60 cm diameter telescope at the Pic du Midi in the French Pyrénées, in order to record incident cosmic rays. In this paper, we describe not only the experimental setup but we also put special emphasis to the reduction of the semi-conductor noise. We also show first data that were recorded during two runs in the fall of 2006, and conclude by the presentation of the design of an “integrated, low-cost solid state photodiode arrangement” which might be an alternative to PMT’s for future VHE telescopes.     

Heterogenity of planetesimal collisional plume probed by glass inclusions in metal globules of Sierra Gorda 013, an unusual CBa-like chondrite

Metal-rich carbonaceous CB chondrites are generally assumed to be materials accreted from the gas–dust plume formed in catastrophic collisions of planetesimals, at least one of which was differentiated into a metal core and silicate shell. Micron-sized inclusions of siliceous alkali-rich glasses associated with sulfides were found in the metal globules of the Sierra Gorda 013 (SG 013), a CBa-like chondrite. These inclusions are unusual carriers of volatile alkalis which are commonly depleted in CB chondrites. The inclusions are presented by two types: (1) Al-bearing Nb-poor glass associated with daubréelite and (2) Nb-bearing Ca,Al,Mg-poor glass associated with an unknown Na-bearing Cr-sulfide. The glass compositions do not correspond to equilibrium condensation, evaporation, or melting. The Nb-bearing glass has a superchondritic Nb/Ta ratio (31) most likely indicating the fractionation of Nb and Ta in the high-temperature gas–dust impact plume due to condensation from vapor or evaporation of precursor Nb-rich particles. The glasses are interpreted as reaction products between refractory plume condensate particles (or possibly planetary or chondritic solids) with relatively low-temperature K-Na-Si-rich gas in oxidized conditions, possibly in a common plume vapor reservoir. Compositional differences indicate that the glasses and sulfides originated from several different sources under different fO₂, fS₂, and T conditions and were likely combined together and transported to the metal globule formation region by material flows in the heterogeneous impact plume. The glass–sulfide particles were enclosed in the globules aggregated from smaller solid or molten metal grains. The metal globules were further melted during transport to the high-temperature plume region or by plume shockwave heating. Thus, the composition of the glasses, the host metal, and the main mass of SG 013 shows dynamic heterogeneity of physical conditions and impact plume composition after a large-scale planetesimal collision.     

EChOSim: The Exoplanet Characterisation Observatory software simulator

EChOSim is the end-to-end time-domain simulator of the Exoplanet Characterisation Observatory (EChO) space mission. EChOSim has been developed to assess the capability of the EChO mission concept to detect and characterise the atmospheres of transiting exoplanets. Here we discuss the details of the EChOSim implementation and describe the models used to represent the instrument and to simulate the detection. Software simulators have assumed a central role in the design of new instrumentation and in assessing the level of systematics affecting the measurements of existing experiments. Thanks to its high modularity, EChOSim can simulate basic aspects of several existing and proposed spectrometers including instruments on the Hubble Space Telescope and Spitzer, ground-based and balloon-borne experiments. A discussion of different uses of EChOSim is given, including examples of simulations performed to assess the EChO mission.     

A mathematical programming approach for scheduling equipment in a surface coal mining operation

Summary A mathematical programming model for scheduling open pit mining was developed and validated using data from a surface mining operation. A two-phase solution procedure was used involving repeated evaluations of an integer scheduling model and a simple transportation model.     

Evacuation behaviour of households and drivers during a tornado

With increasing concerns over the possibility of tornadoes in highly populated areas in Canada, emergency managers are looking into ways to mitigate the impacts of tornadoes. Given that tornadoes can cause enormous destruction, early warnings and proper evacuation actions are critically important in helping save lives. In this paper, a survey was conducted to analyse the evacuation behaviour of households and drivers during a hypothetical tornado warning situation in the city of Calgary, Alberta. Nearly 500 Calgarians took part in the online survey and provided information on how they would respond to tornado warnings after receiving them. This paper presents the results of the survey. Using probit models, the factors influencing these evacuation decisions are identified and discussed in detail. The results of the household evacuation model show the importance of improving awareness about the safest locations during a tornado. It further highlights the need for targeting the population under the age of 30, who are more likely to take unsafe evacuation actions. The model for evacuation of drivers shows that several factors, such as knowing the difference between a watch and a warning, awareness of safe cover, receipt of warnings through natural environmental cues and the level of education, trigger evacuation actions in avoiding a tornado threat.