African linkage of Precambrian Sri Lanka

New age and isotopic data show that the high-grade basement rocks of Sri Lanka were not linked to the Archaean granulite domain of southern India but experienced their main structural and metamorphic development during the Pan-African event some 950 to 550 Ma ago. This occurred when West Gondwana and East Gondwana collided to form one of the longest collisional structures in the Supercontinent — the Mozambique belt that extends from Mozambique to Ethiopia and Sudan. A major tectonic boundary, interpreted as a thrust zone, divides the Highland/Southwestern Complex in the central part of Sri Lanka from the Vijayan Complex in the E and SE. The former is interpreted to represent the remnant of a once extensive passive margin extending west, in a Gondwana reconstruction, via Madagasgar to Tanzania and Mozambique. The Vijayan Complex may have been part of a separate continental margin plutonic assemblage, and its collision with the Highland/ Southwestern Complex marks the final amalgamation of East and West Gondwana into a supercontinent some 550 Ma ago. The Sri Lankan granulites cannot be correlated with the distinctly older granulites of the Eastern Ghats belt of India, and this suggests that Sri Lanka was situated close to the SE coast of Madagascar in a Gondwana reconstruction.

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Zusammenfassung Neue Isotopen- und Altersdaten aus dem metamorphen Grundgebirge von Sri Lanka zeigen, daß dieses Gebiet nicht, wie vielfach vermutet, Teil des archaischen Granulitkomplexes von Südindien war, sondern seine strukturelle und metamorphe Entwicklung während der panafrikanischen Orogenèse zwischen ca. 950 Ma und ca. 550 Ma hatte. Diese Orogenèse ist das Resultat der Kollision zwischen West-Gondwana (Afrika und Südamerika) und Ost-Gondwana (Südindien, Australien und Antarktis) und führte zur Bildung eines der längsten Kollisionsgürtel des Superkontinentes, dem Mosambik-Gürtel, der sich von Mosambik bis nach Äthiopien und in den Sudan erstreckt. Der West- und Zentralteil Sri Lankas mit den Wanni und Highland/Southwestern Komplexen wird vom Vijayan Komplex im Osten und Südosten durch eine Überschiebungszone getrennt, die möglicherweise eine Sutur darstellt. Die Gesteine im Westen und in den Highlands werden als der Rest eines ehemals weiträumigen passiven Kontinentalrandes interpretiert, zu dem wohl auch die lithologisch ähnlichen Abfolgen der hochmetamorphen Gebiete in Mosambik, Tansania und Madagaskar gehörten. Der Vijayan Komplex war wohl Teil der separaten plutonischen Suite eines aktiven Kontinentalrandes, und seine Kollision mit dem Highland/ Southwestern Komplex markiert das endgültige Verschweißen von West- und Ost-Gondwana zu einem Superkontinent vor ca. 550 Ma. Die Granulite Sri Lankas können nicht mit den deutlich älteren Granuliten des Gürtels der Eastern Ghats in Südost Indien korreliert werden sondern ähneln eher den hochgradigen Gesteinen in Südost Madagaskar. Damit ist die Lage Sri Lankas nahe Madagaskar in einer Gondwana Rekonstruktion wahrscheinlicher als nahe der Südostküste Indiens.

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Résumé De nouvelles données isotopiques et géochronologiques montrent que les roches métamorphiques du socle du Sri Lanka ne constituent pas, comme on l'a souvent cru, une partie du complexe granulitique archéen de l'Inde méridionale, mais qu'elles ont vécu leur propre histoire tectono-métamorphique au cours de l'orogenèse panafricaine, entre 950 et 550 Ma. Cette orogenèse est le résultat de la collision entre le Gondwana occidental (Afrique et Amérique du Sud) et le Gondwana oriental (Inde du sud, Australie et Antarctique) et constitue une des plus grandes chaînes de collision du Supercontinent: la chaîne du Mozambique, qui s'étend du Mozambique jusqu'au Soudan et en Ethiopie. Un contact tectonique majeur, interprété comme un charriage, sépare le »Highland/South-western Complex« (partie centrale du Sri Lanka) du »Vijayan Complex« (partie est et sud-est). Le premier de ces complexes est interprété comme un reste d'une ancienne marge passive de grande étendue, à laquelle appartenaient aussi les séries lithologiquement analogues du domaine très métamorphique du Mozambique, de Tanzanie et de Madagascar. Le «Vijagan Complex« a pu être une partie d'un ensemble plutonique séparé de marge active; sa collision avec le »Highland/Southwestern Complex« marque la réunion finale en un super-continent il y a quelque 550 Ma, des Gondwanas oriental et occidental. Les granulites du Sri Lanka ne peuvent pas être corrélées avec celles de la chaîne des Eastern Ghats (Inde du sud-est) qui sont nettement plus anciennes; elles se rapprochent plutôt des roches très métamorphiques du sud-est de Madagascar. On en déduit que la position du Sri Lanka, dans une reconstruction du Gondwana, devait être plus proche de Madagascar que de la côte sud de l'Inde.

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The Ca-Eskola component in eclogitic clinopyroxene as a function of pressure, temperature and bulk composition: an experimental study to 15 GPa with possible implications for the formation of oriented SiO2-inclusions in omphacite

Experiments have been conducted in the P-T range 2.5–15 GPa and 850–1,500°C using bulk compositions in the systems SiO₂–TiO₂–Al₂O₃–Fe₂O₃–FeO–MnO–MgO–CaO–Na₂O–K₂O–P₂O₅ and SiO₂–TiO₂–Al₂O₃–MgO–CaO–Na₂O to investigate the Ca-Eskola (CaEs Ca_0.5□_0.5AlSi₂O₆) content of clinopyroxene in eclogitic assemblages containing garnet + clinopyroxene + SiO₂ ± TiO₂ ± kyanite as a function of P, T, and bulk composition. The results show that CaEs_ss in clinopyroxene increases with increasing T and is strongly bulk composition dependent whereby high CaEs-contents are favoured by bulk compositions with high normative anorthite and low diopside contents. In this study, a maximum of 18 mol% CaEs_ss was found at 6 GPa and 1,350°C in a kyanite-eclogite assemblage garnet + clinopyroxene + kyanite + rutile + coesite. By comparison, no significant increase in CaEs_ss with increasing P could be observed. If the formation of oriented SiO₂-rods frequently observed in eclogititc clinopyroxenes is due to the retrogressive breakdown of a CaEs-component then these textures are a cooling rather than a decompression phenomenon and are most likely to be found in kyanite-bearing eclogites cooled from temperatures ≥750°C. The presence of clinopyroxene with approx. 4 mol% CaEs_ss in an experiment conducted at 2.5 GPa/850°C confirms earlier suggestions based on field data that vacancy-rich clinopyroxenes are not necessarily restricted to ultrahigh pressure metamorphic conditions. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Zircon U–Pb and Hf isotopic study of gneissic rocks from the Chinese Altai: Progressive accretionary history in the early to middle Palaeozoic

Gneissic rocks in the Chinese Altai Mountains have been interpreted as either Paleozoic metasedimentary rocks or Precambrian basement. This study reports geochemical and geochronological data for banded paragneisses and associated gneissic granitoids collected along a NE–SW traverse in the northwestern Chinese Altai. Petrological and geochemical data suggest that the protoliths of the banded gneisses were possibly immature sediments with significant volcanic input and that the gneissic granitoids were derived from I-type granites formed in a subduction environment. Three types of morphological features can be recognized in zircons from the banded gneisses and are interpreted to correlate with different sources. Zircons from five samples of banded paragneiss cluster predominantly between 466 and 528 Ma, some give Neoproterozoic ages, and a few yield discordant Paleoproterozoic to Archean ages. Zircon Hf isotopic compositions indicate that both juvenile/mantle and crust materials were involved in the generation of the source rocks from which these zircons were derived. In contrast, zircons occur ubiquitously as elongated euhedral prismatic crystals in the four samples of the gneissic granitoids, and define single populations for each sample with mean ages between 380 and 453 Ma. The general absence of Precambrian inheritance and positive zircon ?Hf values for these granitoids suggest insignificant crustal contribution to the generation of the precursor magmas. Our data can be interpreted in terms of a progressive accretionary history in early to middle Palaeozoic times, and the Chinese Altai may possibly represent a magmatic arc built on a continental margin dominated by Neoproterozoic rocks.     

Solar wind helium, neon, and argon isotopic and elemental composition: Data from the metallic glass flown on NASA’s Genesis mission

Solar wind (SW) helium, neon, and argon trapped in a bulk metallic glass (BMG) target flown on NASA’s Genesis mission were analyzed for their bulk composition and depth-dependent distribution. The bulk isotopic and elemental composition for all three elements is in good agreement with the mean values observed in the Apollo Solar Wind Composition (SWC) experiment. Conversely, the He fluence derived from the BMG is up to 30% lower than values reported from other Genesis bulk targets or in-situ measurements during the exposure period. SRIM implantation simulations using a uniform isotopic composition and the observed bulk velocity histogram during exposure reproduces the Ne and Ar isotopic variations with depth within the BMG in a way which is generally consistent with observations. The similarity of the BMG release patterns with the depth-dependent distributions of trapped solar He, Ne, and Ar found in lunar and asteroidal regolith samples shows that also the solar noble gas record of extraterrestrial samples can be explained by mass separation of implanted SW ions with depth. Consequently, we conclude that a second solar noble gas component in lunar samples, referred to as the “SEP” component, is not needed. On the other hand, a small fraction of the total solar gas in the BMG released from shallow depths is markedly enriched in the light isotopes relative to predictions from implantation simulations with a uniform isotopic composition. Contributions from a neutral solar or interstellar component are too small to explain this shallow sited gas. We tentatively attribute this superficially implanted gas to low-speed, current-sheet related SW, which was fractionated in the corona due to inefficient Coulomb drag. This fractionation process could also explain relatively high Ne/Ar elemental ratios in the same initial gas fraction.     

Phthalic acid complexation and the dissolution of forsteritic glass studied via in situ FTIR and X-ray scattering

Multiple Internal Reflection Fourier Transform Infra-Red (MIR-FTIR) spectroscopy was developed and used for in situ flow-through experiments designed to study the process of organic acid promoted silicate dissolution. In tandem with the FTIR analysis, ex situ X-ray scattering was used to perform detailed analyses of the changes in the surface structure and chemistry resulting from the dissolution process. Phthalic acid and forsteritic glass that had been Chemically Vapour Deposited (CVD) onto an internal reflection element were used as reactants, and the MIR-FTIR results showed that phthalic acid may promote dissolution by directly binding to exposed Mg metal ion centers on the solid surface. Integrated infrared absorption intensity as a function of time shows that phthalic acid attachment apparently follows a t^1/2 dependence, indicating that attachment is a diffusive process. The diffusion coefficient of phthalic acid was estimated to be approximately 7 × 10⁻⁶ cm² s⁻¹ in the solution near the interface with the glass. Shifts in the infrared absorption structure of the phthalate complexed with the surface compared to the solute species indicate that phthalate forms a seven-membered ring chelate complex. This bidentate complex efficiently depletes Mg from the glass surface, such that after reaction as much as 95% of the Mg may be removed. Surface depletion in Mg causes adsorbate density to fall after an initial attachment stage for the organic ligand. In addition, the infrared analysis shows that silica in the near surface polymerizes after Mg removal, presumably to maintain charge balance. X-ray reflectivity shows that the dissolution rate of forsteritic glass at pH 4 based on Mg removal in such flow-through experiments was equal to 4 × 10⁻¹² mol cm⁻² s⁻¹ (geometric surface area normalized). Reflectivity also shows how the surface mass density decreases during reaction from 2.64 g cm⁻³ to 2.2 g cm⁻³, consistent with preferential loss of Mg from the surface. Auxiliary batch experiments with forsteritic glass films deposited onto soda glass were also completed to add further constraints to the mechanism of reaction. By combining reflectivity with diffuse scatter measurements it is shown that the primary interface changes little in terms of atomic-scale roughness even after removal of several hundred angstroms of material. These measurements unequivocally show how a dicarboxylic acid bonds to and may chelate the dissolution of a magnesium-bearing silicate. At the molecular level the solid surface retreat may best be described by a depinning model where Mg is preferentially removed and residual silica tetrahedra polymerize and act to episodically “pin” the surface.     

Airports, mobility and the calculative architecture of affective control

Drawing on work surrounding the theorisation of concepts such as mobility, affect and emotion, the paper argues that their control is now being intertwined in places like airports which are employing a number of techniques that engineer affects. Airport affect is enacted, in one way, by planning and designing the situational affective context one inhabits - throwing up structures of ethological possibility that shape capacities for the corporeal body to move and be moved. It is shown that the engineering of airport affect is premised upon a wider discursive framework of calculation and indeterminacy, and that selective techniques summon a number of different modalities of control. The paper concludes with a series of implications for the understanding of power, and the study of mobility, emotion and affect.     

Atmospheric mercury near Salmon Falls Creek Reservoir in southern Idaho

Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over 2-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran Hg analyzers. GEM, RGM, and particulate Hg (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize Hg air concentrations in the southern Idaho area for the first time, estimate Hg dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 ± 0.9 ng m⁻³) and RGM (8.1 ± 5.6 pg m⁻³) concentrations occurring in the summer and lower values in the winter (1.32 ± 0.3 ng m⁻³, 3.2 ± 2.9 pg m⁻³ for GEM, RGM, respectively). The summer-average HgP concentrations were generally below detection limit (0.6 ± 1 pg m⁻³). Seasonally averaged deposition velocities calculated using a resistance model were 0.034 ± 0.032, 0.043 ± 0.040, 0.00084 ± 0.0017 and 0.00036 ± 0.0011 cm s⁻¹ for GEM (spring, summer, fall and winter, respectively) and 0.50 ± 0.39, 0.40 ± 0.31, 0.51 ± 0.43 and 0.76 ± 0.57 cm s⁻¹ for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 ± 3.3 μg m⁻², or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2–12 ng m⁻³) and RGM (50–150 pg m⁻³) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicate predominant source directions to the SE (western Utah, northeastern Nevada) and SW (north-central Nevada) with fewer inputs from the NW (southeastern Oregon and southwestern Idaho).     

The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2

Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H₂SO₄, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L⁻¹, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO₄–H⁺ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H⁺ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO₄–H⁺ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H⁺ solutions.