Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)

In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C₂₅ are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C₂₅ content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C₁₇ content compared to n-C₂₇, and phytane compared to n-C₁₈. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C₂₆ (hypersaline depositional environment), or isoprenoid C₂₅ and n-alkane C₂₂ for high alkalinity environment.This study showed that Sq/n-C₂₆ ratio can be used to assess the quality of organic substance in immature lacustrine sediments.     

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.     

Dynamical portrait of the Lixiaohua asteroid family

In this paper we present a comprehensive analysis of the dynamics in the region of the (3556) Lixiaohua asteroid family. The family lies in a particularly interesting region of the phase space, crossed by several two-body and three-body mean motion resonances. Also, members of this family can have close encounters with large asteroids, such as Ceres. We have identified the mean motion resonances which contribute to the long-term dynamical evolution of the family and our results confirm that the members of this family can be classified into a number of groups, exhibiting different dynamical behavior. We show for the first time that in the Lixiaohua region, apart from the chaotic diffusion in proper eccentricity and inclination (e _p and I _p ), there is at least one extended chaotic zone where several resonances overlap, thus giving rise to chaotic diffusion in proper semi-major axis (a _p ) as well. Using a code of Monte Carlo type, we simulate the evolution of the family, according to the model which combines the chaotic diffusion (in a _p , e _p and I _p ), Yarkovsky/YORP thermal effect and random walk in a _p due to the close encounters with massive asteroids. These simulations show that all these effects should be taken into account in order to accurately explain the observed distribution of family members in the space of proper elements, although a “minimal” model that accounts for chaotic diffusion in (e _p , I _p ), Yarkovsky-induced drift in a _p and random walk in a _p due to the close encounters with the most massive asteroids is enough to grossly characterize the shape of the family.     

The crystal structure of bøgvadite (Na2SrBa2Al4F20)

The crystal structure of bøgvadite, Na₂SrBa₂Al₄F₂₀, has been solved and refined to a R₁ factor of 4.4 % from single-crystal data (MoKα X-ray diffraction, CCD area detector) on a sample from the cryolite deposit at Ivittuut, SW Greenland. Bøgvadite is monoclinic, P2₁/n space group, with unit cell parameters a?=?7.134(1), b?=?19.996(3) and c?=?5.3440(8) Å, β?=?90.02(1)^o. A close proximity of the crystal structure to an orthorhombic symmetry and the presence of the two twin components in a nearly 1:1 ratio suggest that the investigated bøgvadite crystal has originally formed as a high-temperature orthorhombic polymorph which on cooling transformed to the stable low temperature monoclinic structure. The bøgvadite crystal structure has groupings of cation-fluoride coordination polyhedra similar to those found in the crystal structures of the genetically closely associated minerals jarlite and jørgensenite. However, its structure type is different from the latter two. The fluoridoaluminate framework of bøgvadite consists of infinite zig-zag chains of cis-connected AlF₆ coordination octahedra. The ¹ _∞[AlF₅] chains are interconnected by infinite chains of Na-F coordination polyhedra which extend in the same direction. Na is coordinated by nine F atoms if its full surrounding is taken in consideration, but makes significant chemical bonds only to closest five. The chains of AlF₆ and NaF₉ coordination polyhedra form double layers. In the centre of layers, relatively large voids in the form of pentagonal antiprisms are occupied by Sr atoms which make chemical bonds with the closest six F atoms. Between the SrF₁₀ coordinations in the centre of layers run empty channels. The double layers are interconnected by Ba atoms which are coordinated by eight F atoms and fill the spaces between the layers. Bøgvadite belongs to the group of fluoridoaluminates with infinite chains of cis-connected AlF₆ coordination octahedra, alike those found in the crystal structures of Ba-fluoridoaluminates.     

A note on the thermal component of the equation of state in solids

A simple method for determining the thermal component of the EOS of solids under high pressure is proposed. Application to the interior of the Earth gives results in agreement with recent geophysical data.     

A Photometric Investigation of the Eclipsing System OO Aql

The paper is concerning with the light curve analysis of an active binary system of OO Aql. Basic orbital and physical parameters of this system were estimated by analysing photometric observations by Lafta and Grainger (1985) and Essam et al. (1992). Both groups of observations gave quite different light curves with a conspicuous asymmetry arising from unequal height of successive maxima. A slightly changed programme by Djuraevi (1992a) was applied. The programme was based on the Roche model and it included an option of overcontact configuration and active (bright or dark) spotted regions on the system's components. An inverse-problem method by Djuraevi (1992b) was used to estimate the parameters of the system and active regions. The light-curve analysis suggested a significant change in the system. For Lafta and Grainger's light curves our analysis showed the presence of a dark spotted area near the polar region of the primary component. This dark area covered about 22% of the primary's hemisphere. Essam et al.'s light curves had very complex shape. In this case the mechanism of the mass transfer and the exchange of the thermal energy between the components could produce a bright-spot (bs) area on the secondary, near the Lagrange equilibrium point L₁ around the neck region between the stars. To explain a sharp increase of the system's brightness in the B filter immediately after the secondary minimum, we had to introduce also a hot-spot (hs) area of a high temperature contrast on the secondary. With the increase of the brightness in the V-filter being of much lower intensity, this hot spot region could be taken as a local eruption. The behaviour of the B–V colour index with the orbital phase is in favour of this hypothesis also. The obtained results show that the light-curve changes are due to development and moving of active spot regions on the components.     

Seeding agent dispersion within convective cloud as simulated by a 3-D numerical model

Summary The three-dimensional mesoscale cloud-resolving model ARPS (Advanced Regional Prediction System) was used to investigate the dispersal of an inert seeding agent within a cumulonimbus (Cb) cloud developing from two different initial states. In this paper, we stress the influence vortices in the cloud have on seeding agent dispersion. If a strong directional ambient wind shear is present in the lowest layer, a vortex pair formed at the flanks of the simulated cloud. Following the velocity field, a considerable amount of the injected seeding agent would be thrown out to the rear of the cloud, where both updrafts associated with vortices and downdrafts occurred. After a short time the agent was present only in the cloud periphery. If the Cb cloud developed under conditions where directional ambient wind shear did not exist, seeding agent dispersion would be quite different. In this case, almost all the seeding agent was transported into the main updraft, while the residence time of the agent within the cloud was longer due to the weaker cloud dynamics. Therefore, we must pay attention to whether or not the cloud contains vortices when we make the decision where to seed. This is necessary in order to minimize the loss of seeding material.     

The broad Fe Kα line and supermassive black holes

Here we present an overview of some of the most significant observational and theoretical studies of the broad Fe Kα spectral line, which is believed to originate from the innermost regions of relativistic accretion disks around central supermassive black holes of galaxies. The most important results of our investigations in this field are also listed. All these investigations indicate that the broad Fe Kα line is a powerful tool for studying the properties of the supermassive black holes (such as their masses and spins), space–time geometry (metric) in their vicinity, their accretion physics, probing the effects of their strong gravitational fields, and for testing the certain predictions of General Relativity.     

Rječina River sediments (Croatia): from captured spring to polluted prodelta

Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.