New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.     

Factors affecting sediment trapping in vegetated filter strips: simulation study using VFSMOD

Soil and water conservation practices have been promoted for a long time, in order to sustain agricultural activities and prevent environmental pollution. Vegetated filter strips (VFS) have been used to reduce sediment pollution into water bodies at or near the pollutant source. However, factors effecting VFS performance under natural conditions have not been well understood owing to the physical, time and financial limitations of field experiments. The use of well‐validated simulation models to understand the performance of VFS and factors affecting sediment deposition is highly justified. The objective of this research is to investigate sediment trapping in VFS and to study various factors affecting VFS performance using the simulation model VFSMOD, which was developed by researchers at University of North Carolina. Recently, VFSMOD has been validated successfully by using 21 filters with varying length, slope and vegetated cover. A wide range of five parameters was selected for the simulations, namely filter length, filter slope, manning roughness coefficient, soil type and characteristics of incoming sediment from adjacent fields. Computer simulations revealed that the length of filter is the most significant factor affecting sediment trapping in VFS. The relative increase in trapping efficiencies was not linearly related to an increase in filter length. Inflow sediment class also has a major influence on sediment trapping in VFS. The trapping efficiency of clay sediments in a 15 m length VFS was 47% compared with 92% for silt from incoming sediment. Manning roughness coefficient had a moderate effect on sediment trapping and was more significant in short filters. Land slope and soil type of VFS had a minor influence on the performance of VFS. Copyright © 2001 John Wiley & Sons, Ltd.     

Operation of two major reservoirs of Iran under IPCC scenarios during the XXI century

We assess the effects of prospective climate change until 2100 on water management of two major reservoirs of Iran, namely, Dez (3.34 × 10⁹ m³) and Alavian (6 × 10⁷ m³). We tune the Poly‐Hydro model suited for simulation of hydrological cycle in high altitude snow‐fed catchments. We assess optimal operation rules (ORs) for the reservoirs using three algorithms under dynamic and static operation and linear and non‐linear decision rules during control run (1990–2010 for Dez and 2000–2010 for Alavian). We use projected climate scenarios (plus statistical downscaling) from three general circulation models, EC‐Earth, CCSM4, and ECHAM6, and three emission scenarios, or representative concentration pathways (RCPs), RCP2.6, RCP4.5, and RCP8.5, for a grand total of nine scenarios, to mimic evolution of the hydrological cycle under future climate until 2100. We subsequently test the ORs under the future hydrological scenarios (at half century and end of century) and the need for reoptimization. Poly‐Hydro model when benchmarked against historical data well mimics the hydrological budget of both catchments, including the main processes of evapotranspiration and streamflows. Teaching–learning‐based optimization delivers the best performance in both reservoirs according to objective scores and is used for future operation. Our projections in Dez catchment depict decreased precipitation along the XXI century, with ?1% on average (of the nine scenarios) at half century and ?6% at the end of century, with changes in streamflows on average ?7% yearly and ?13% yearly, respectively. In Alavian, precipitation would decrease by ?10% on average at half century and ?13% at the end of century, with streamflows ?14% yearly and ?18% yearly, respectively. Under the projected future hydrology, reservoirs' operation would provide lower performance (i.e., larger lack of water) than now, especially for Alavian dam. Our results provide evidence of potentially decreasing water availability and less effective water management in water stressed areas like Northern Iran here during this century.     

Joint parameter estimation from magnetic resonance and vertical electric soundings using a multi‐objective genetic algorithm

Magnetic resonance sounding (MRS) has increasingly become an important method in hydrogeophysics because it allows for estimations of essential hydraulic properties such as porosity and hydraulic conductivity. A resistivity model is required for magnetic resonance sounding modelling and inversion. Therefore, joint interpretation or inversion is favourable to reduce the ambiguities that arise in separate magnetic resonance sounding and vertical electrical sounding (VES) inversions. A new method is suggested for the joint inversion of magnetic resonance sounding and vertical electrical sounding data. A one‐dimensional blocky model with varying layer thicknesses is used for the subsurface discretization. Instead of conventional derivative‐based inversion schemes that are strongly dependent on initial models, a global multi‐objective optimization scheme (a genetic algorithm [GA] in this case) is preferred to examine a set of possible solutions in a predefined search space. Multi‐objective joint optimization avoids the domination of one objective over the other without applying a weighting scheme. The outcome is a group of non‐dominated optimal solutions referred to as the Pareto‐optimal set. Tests conducted using synthetic data show that the multi‐objective joint optimization approximates the joint model parameters within the experimental error level and illustrates the range of trade‐off solutions, which is useful for understanding the consistency and conflicts between two models and objectives. Overall, the Levenberg‐Marquardt inversion of field data measured during a survey on a North Sea island presents similar solutions. However, the multi‐objective genetic algorithm method presents an efficient method for exploring the search space by producing a set of non‐dominated solutions. Borehole data were used to provide a verification of the inversion outcomes and indicate that the suggested genetic algorithm method is complementary for derivative‐based inversions.     

Pipe Service Age Effect on Chlorine Decay in Drinking‐Water Transmission and Distribution Systems

Maintaining acceptable quality of water transported in the transmission and distribution system requires the chlorination of water beyond the treatment plant. While flowing through pipes, the chlorine concentration decreases for different reasons. Reaction with the pipe material itself and the reaction with both the biofilm and tubercles formed on the pipe wall are known as pipe wall demand. This varies with pipe parameters. The aim of this paper was to assess the impact of the service age of pipes on the chlorine wall decay constant. One hundred and fifty three pipe sections of different sizes and four different pipe materials were collected and tested for their chlorine first‐order wall decay constants. The results showed that pipe service age was an important factor that must not be ignored. For the range of the 55 years of pipe service age used in this study, the change in the wall decay ranged from 8 to 531% of the corresponding values in the recently installed pipes. The effect of service age on the wall decay constants was most evident in steel pipes. Other important findings were reached.     

Seismic response of steel structures with seesaw systems using viscoelastic dampers

Vibration control systems are being used increasingly worldwide to provide enhanced seismic protection for new and retrofitted buildings. This paper presents a new vibration control system on the basis of a seesaw mechanism with viscoelastic dampers. The proposed vibration control system comprises three parts: brace, seesaw member, and viscoelastic dampers. In this system, only tensile force appears in bracing members. Consequently, the brace buckling problem is negligible, which enables the use of steel rods for bracing members. By introducing pre‐tension in rods, long steel rods are applicable as bracing between the seesaw members and the moment frame connections over some stories. Seesaw mechanisms can magnify the damper deformation according to the damper system configuration. In this paper, first, the magnification factor, that is, the ratio of the damper deformation to the story drift, is delivered, which includes the rod deformation. Results of a case study demonstrate that the magnification factor of the proposed system is greater than unity for some cases. Seismic response analysis is conducted for steel moment frames with the proposed vibration control system. Energy dissipation characteristics are examined using the time‐history response results of energy. The maximum story drift angle distributions and time‐history response results of displacement show that the proposed system can reduce the seismic response of the frames effectively. Copyright © 2012 John Wiley & Sons, Ltd.     

Multiperiodic semiregular variable stars in the ASAS data base: A pilot study

Based on a search for multi‐periodic variability among the semi‐regular red variable stars in the database of the All Sky Automated Survey (ASAS), a sample of 72 typical examples is presented. Their period analysis was performed using the Discrete Fourier Transform. In 41 stars we identified two significant periods each, simultaneously present, while the remaining 31 cases revealed even three such periods per star. They occur in a range roughly between 50 and 3000 days. Inter‐relationships between these periods were analyzed using the “double period diagram” which compares adjacent periods, and the so‐called “Petersen diagram”, the period ratio vs. the shorter period. In both diagrams we could identify six sequences of accumulation of the period values. For five of these sequences (containing 97 % of all data points) we found an almost perfect coincidence with those of previous studies which were based on very different samples of semiregular red variables. Therefore, existence and locations of these sequences in the diagrams seem to be universal features, which appear in any data set of semi‐regularly variable red giants of the AGB; we conclude that they are caused by different pulsation modes as the typical and consistent properties of similar stellar AGB configurations. Stellar pulsations can be considered as the principal cause of the observed periodic variability of these stars, and not binary, rotation of a spotted surface or other possible reasons suggested in the literature. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Depositional system and palaeoclimatic interpretations of Middle to Late Pleistocene travertines: Kocabaş, Denizli,south‐west Turkey

Travertine deposits in western Turkey are very well‐exposed in the area of Kocaba?, in the eastern part of the Denizli Basin. The palaeoclimatic significance of these travertines is discussed using U/Th dates, stable isotope data and palynological evidence. The Kocaba? travertine occurrences are characterized by successions of depositional terraces associated with palaeosols and karstic features. The travertines have been classified into eight lithotypes and one erosional horizon, namely: laminated, coated bubble, reed, paper‐thin raft, intraclasts, micritic travertine with gastropods, extra‐formational pebbles and a palaeosol layer. The analysed travertines mostly formed between 181 ka and 80 ka (Middle to Late Pleistocene) during a series of climatic changes including glacial and interglacial intervals; their δ¹³C and δ¹⁸O values indicate that the depositional waters were mainly of basinal thermal origin, occasionally mixed with surficial meteoric water. Palynological results obtained from the palaeosols showed an abundance of non‐arboreal percentage and xerophytic plants (Oleaceae and Quercus evergreen type) indicating that a drought occurred. Marine Isotope Stage 6 is represented by grassland species but Marine Isotope Stage 5 is represented by Pinaceae–Pinus and Abies, Quercus and Oleaceae. Uranium/thorium analyses of the Kocaba? travertines show that deposition began in Marine Isotope Stage 6 (glacial) and continued to Marine Isotope Stage 4 (glacial), but mostly occurred in Marine Isotope Stage 5 (interglacial). The travertine deposition continued to ca 80 ka in the south‐west of the study area, in one particular depression depositional system. Palaeoenvironmental indicators suggest that the travertine depositional evolution was probably controlled by fault‐related movements that influenced groundwater flow. Good correlation of the stable isotope values and dates of deposition of the travertines and palynological data of palaeosols in the Kocaba? travertines serve as a starting point for further palaeoclimate studies in south‐west Turkey. Additionally, the study can be compared with other regional palaeoclimate archives.     

Speckle observations with PISCO in Merate: VI. Astrometric measurements of visual binaries in 2006

We present relative astrometric measurements of visual binaries made during the second semester of 2006, with the speckle camera PISCO at the 102 cm Zeiss telescope of Brera Astronomical Observatory, in Merate. Our sample contains orbital couples as well as binaries whose motion is still uncertain. We obtained 175 new measurements of 169 objects, with angular separations in the range 0″.1–4″.2, and an average accuracy of 0″.01. The mean error on the position angles is 0°.6. Most of the position angles could be determined without the usual 180° ambiguity with the application of triplecorrelation techniques and/or by inspection of the long integration files.We also present the new orbits we have computed for ADS 11479, 11584 and 16538, for which our measurements lead to large residuals and/or for which the revision was justified by the significant number of observations made since the last orbit computation (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)