Corrosion behavior of anodic oxidized TiO<Subscript>2</Subscript> film in seawater

TiO₂ films were formed on metallic titanium substrates by the anodic oxidation method in H₂SO₄ solution under the 80V D.C.. Phase component and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Water contact angles on titanium oxide film surface were measured under both dark and sunlight illumination conditions. Corrosion tests were carried out in seawater under different illumination conditions by electrochemistry impedance spectrum (EIS) and polarization curves. The result showed that the TiO₂ film prepared by the anodic oxidation method was anatase with a uniform structure and without obvious pores or cracks on its surface. The average water contact angle of the film was 116.4° in dark, in contrast to an angle of 42.7° under the UV illumination for 2 hours, which demonstrates good hydrophobic property. The anti-corrosion behavior of the TiO₂ film was declining with the extended immersion time. Under dark conditions, however, the hydrophobic TiO₂ film retarded the water infiltrating into the substrate. The impedance changed slowly and the corrosion current density was 2 orders of magnitude lower than that with the film illuminated by sunlight. All of those mentioned above indicate that the TiO₂ film possesses much better performance under dark condition, and it can be applied as an engineering material under dark seawater environment.     

岩溶区地表水体惰性有机碳研究

岩溶作用所产生的岩溶碳汇对全球碳循环有着重要的影响。岩溶水生生物通过CO₂富集机制（CCM）固定岩溶水中的HCO₃^-,将其转化为有机碳。惰性有机碳（RDOC）为水生生物和微生物不能利用和降解的溶解性有机碳。RDOC长时间滞留水体,形成稳定碳汇。多次培养实验发现可以用原位微生物法对岩溶区地表水中的RDOC进行检测。以桂林漓江为对象,研究由外源水补给并流经岩溶峰林平原区的岩溶地表水中的RDOC及其相关因子,结果显示：1）漓江水中Ca²⁺,HCO₃^-浓度从上游到下游逐渐升高,表明外源水进入岩溶区,发生了岩溶作用。漓江水的C/N为6.29~10.50,表明水中有机碳的来源为外源水和水生生物作用。受岩溶作用和水生生物光合作用双重影响,δ¹³C-DIC值从上游到下游逐渐偏正,水生生物优先利用无机碳中的¹²C使得δ¹³C-POC从上游到下游逐渐偏负。C/N与δ¹³C-DIC、δ¹³C-POC的变化以及相关性体现了岩溶地表水体中无机环境和有机环境相关联;2）岩溶区地表水中检测出RDOC且浓度远大于非岩溶区,RDOC浓度的时空变化与水生生物利用岩溶作用所产生的HCO₃^-有关。漓江地表水中DOC、BDOC、RDOC浓度与HCO₃^-浓度变化趋势一致,从上游到下游逐渐升高,下游L6（岩溶区）RDOC浓度为上游L1（非岩溶区）的3倍,在季节上表现出秋季>冬季>夏季>春季,RDOC的含量平均占水体中DOC含量的78%左右,体现了岩溶作用强度和水生生物活动对岩溶地表水中RDOC的影响;3）结合流量数据计算RDOC通量：桂林水文站RDOC的通量为0.75×10⁷ kg/a,阳朔水文站的RDOC通量为1.3×10⁷ kg/a,是桂林水文站断面的1.7倍。

     

1996-2011 年南非人口空间分布格局与演变特征

南非是中国在非洲的最大投资目的地与经贸合作伙伴, 特别在基础设施建设方面发展迅速。南非人口空间分布研究对开展中南合作具有重要意义。本文通过收集整理南非历年来的全国人口普查资料统计数据, 运用空间自相关模型、不均衡指数、人口重心模型和偏移—分享模型, 分析了南非人口的空间分布格局和演变特征。研究结果表明, 南非人口分布具有显著的“东高西低”的空间格局, 呈现出以工业化程度较高的大都市区和港口城市为中心的“多核心”集聚的分布特征;空间自相关分析得出人口高集聚区主要分布在大都市区和沿海港口城市, 低密度集聚区主要集中分布在中西部地区;从变化趋势上来看, 1996-2011 年间人口分布不平衡趋势不断加强, 人口重心向西北方向移动;偏移—分享分析表明, 南非人口增长速度先后经历了从1996-2001 年快速增长到2001-2007 年缓慢增长, 再到2007-2011 年高速增长的“高—低—高”增长阶段;省域层面上看, 豪登省和西开普省一直是南非人口集聚较强地区。     

Sedimentary characteristics and the implications of cobalt-rich crusts resources at Caiwei Guyot in the Western Pacific Ocean

Abstract

Cobalt-rich crust has attracted increased attention due to their economic value. Studies have indicated that seamounts in the Western Pacific Ocean are rich in cobalt-rich crust resources. The Caiwei Guyot in Western Pacific Ocean is one of the cobalt-rich crust exploration areas contracted between China and the International Seabed Authority. A large volume of research has been conducted to elucidate the tectonic evolution, basement type, sediment type, gravity and magnetic anomaly characteristics, and geochemical characteristics of shallow surface sediments at Caiwei Guyot. However, a research gap exists on the sedimentary strata below the pelagic deposits and above the volcanic basement of the Caiwei Guyot. This paper summarizes that two main types of sediments existing on the top of Caiwei Guyot. The deposition thickness on the top of Caiwei Guyot is characterized by three sedimentary centers and exposed periphery. Pelagic sediments are difficult to form at the northeastern portion and edge area of Caiwei Guyot due to the strong bottom current environment, which makes these areas suitable for crust growth. This paper delineated three cobalt-rich crust prospective areas at the Caiwei Guyot with of significant implications for exploration and mining-lease-block selections at Caiwei Guyot.     

鄂尔多斯盆地中央古隆起的地质结构与成因机制

克拉通盆地内古隆起是了解板内变形机制的重要窗口,也是油气、煤、盐、铀等矿产勘查的主要对象,一直是盆地分析的热点领域。本文以鄂尔多斯盆地中央古隆起为例,利用新的高精度反射地震剖面与深探井资料,解剖古隆起的地质结构,刻画构造演化过程,探讨其形成机制。研究表明,鄂尔多斯盆地古生代隆起带发育在华北克拉通地块中西部,自伊盟—杭锦旗、乌审旗—定边,南延至镇原—正宁一带,呈“工”字形,面积达7.5×104 km2以上;伊盟凸起为基底隆起,镇原隆起为多阶段、间隙性发育的剥蚀与沉积型隆起,定边凸起为沉积型隆起。它是基底分异构造格局与周缘板块构造事件共同控制的产物,为在中元古代裂陷基础上早古生代被动大陆边缘背景下发育演化的古隆起;古生代早期,邻接周缘洋盆表现为台缘隆起;石炭纪晚期—二叠纪早期,因差异升降而具陆缘隆起性质;印支晚期—燕山期以来,隐伏于天环坳陷之下埋藏沉没。鄂尔多斯盆地中央隆起带为多机制复合成因,伊盟凸起为基底强烈伸展、长期剥露剥蚀型隆起;镇原凸起为西缘断阶迁移、南缘前缘隆起叠加的复合隆起;定边凸起为断阶迁移、挤压叠加的继承性隆起。鄂尔多斯盆地中央隆起带对盆地内部的构造—沉积分异施加了重要影响,其两翼斜坡带是油气聚集的有利区带。     

阿尔泰南缘东段变形岩石磁组构分析

磁组构是指岩石磁化率的各向异性,磁组构方法已经被广泛应用于构造变形分析。阿尔泰南缘东段地区岩石磁组构特征是磁各向异性度P值大,反映本区总体韧性剪切变形强烈。萨尔布拉克—科克萨依脆性劈理化带和玛因鄂博韧性剪压构造带的E>0占优势,磁面理发育,部分样品磁线理发育,反映变形以压扁变形为主,主压应力方向为NE(NEE)向,伴随弱的左行剪切;达拉维孜—阿热勒托别韧性流变构造带和锡泊渡—富蕴深层次变晶糜棱岩带E>0和E<0均存在,磁面理和磁线理均发育,反映以剪切变形为主;其中达拉维孜—阿热勒托别构造带主压应力方向为NE(NEE)向,为左行剪切,而锡泊渡—富蕴构造带主压应力方向为SN向,为右行剪切。在达拉维孜—阿热勒托别构造带中的哈腊苏铜矿和卡拉先格尔—老山口一带一些叠加蚀变矿化的强变形岩石的P值明显减小,说明在韧性变形之后发生过矿化热液作用导致磁化率各向异性发生了均一化。结合区域构造分析,可以认为萨尔布拉克—科克萨依构造带、达拉维孜—阿热勒托别构造带和玛因鄂博构造带构成一个完整的板块碰撞聚合带,而锡泊渡—富蕴构造带可能为在古生代期间被强烈改造的具有前震旦纪结晶基底的微大陆的残留(或断片)。     

车载LiDAR点云路灯提取方法

道路场景中路灯数量大、类型多,大场景中路灯详细信息获取是一项繁重的工作。本文提出先验样本集辅助的、基于骨架线缓冲区判别的路灯点云提取及种类识别算法:先根据路灯在车载LiDAR点云中的表达特征,构建路灯模型,并构建路灯先验样本集;再依据数学形态学的理论和方法,提取车载LiDAR点云场景中的杆状地物,在路灯模型及语义规则约束下,得到候选路灯;然后根据候选路灯的参数信息,及已获取路灯的统计信息,从样本集中筛选候选样本;最后基于最小二乘理论的匹配算法,对路灯先验样本与候选路灯点云进行匹配筛选,并基于路灯骨架线信息构建的双重缓冲区,对候选路灯进行判别分析,实现路灯的提取和种类识别。试验表明,该算法对于遮挡少、数据相对完整的路灯提取准确度为95.2%,对于遮挡严重、点云密度低、数据完整性差的路灯提取准确度为78.0%,验证了该算法对大场景中路灯详细信息提取的稳健性。     

柳珊瑚分子系统发育学的研究进展

珊瑚分子系统发育学研究始于90年代初,用于柳珊瑚分子系统学研究的主要分子标记是线粒体DNA和核糖体RNA。本文在重点介绍了柳珊瑚种群遗传多样性和柳珊瑚种上阶元系统发育学两方面的研究进展和所取得研究成果的同时,也讨论了珊瑚虫纲的系统发生关系。最后在简单引述了柳珊瑚分子系统发育学同传统形态分类学方法之间关系的同时,也对柳珊瑚分子系统发育学今后的重点研究方向做了预测。