Ecotoxicological Assessment of After-Effects of the Volga River Water Contamination

Comprehensive assessment of ecotoxicological situation in the Volga River basin is presented. Concentrations of organic and inorganic toxic substances are cited. Basic clinic and postmortem symptoms of intoxication in fish are described; changes in the cellular structure of their organs and tissues, as well as disturbances in hemogenesis, developing under the effect of toxic agents, are characterized. Based on the dose-effect dependences, calculated according to the values of the total concentration of toxic substances, standardized to MPC, and criteria of the physiological state of fish, cases of exceedance of the critical concentrations of pollutants are demonstrated for the investigated river sections.__________Translated from Vodnye Resursy, Vol. 32, No. 4, 2005, pp. 410–424.Original Russian Text Copyright © 2005 by Moiseenko, Gashkina, Sharova, Pokoeva.     

Survival of the thinnest: rediscovery of Bauer’s (1898) ichthyosaur tooth sections from Upper Jurassic lithographic limestone quarries,south Germany

During the late Early Cretaceous, the shallow-water domains of the western Tethys are characterized by the widespread deposition of Urgonian-type carbonates rich in rudists, corals and other oligotrophic, shallow-marine organisms. In the Helvetic Alps, the Urgonian occurrences have been dated by ammonite biostratigraphy as Late Barremian and Early Aptian. For the more proximal occurrences in the western Swiss Jura, a recent age model based on bio-, chemo- and sequence stratigraphy has been proposed, which allows for an improved correlation with the Helvetic counterparts. In order to corroborate the recently proposed age model for the Jura, a set of well-preserved rhynchonellids collected from five different lithostratigraphical formations and members (“Marnes bleues d’Hauterive”, “Marnes d’Uttins”, basal marly layers within the “Urgonien Jaune”, “Marnes de la Russille”, “Urgonien Blanc”) has been analysed for its strontium–isotope ratios (⁸⁷Sr/⁸⁶Sr). In addition, K–Ar dating was performed on well-preserved glauconite grains from two different levels (“Marnes d’Uttins” and a basal layer within the “Urgonien Jaune”). The correlation of the Sr–isotope data set with a belemnite-based, ammonite-calibrated reference curve provides an age model which is coherent with recently published ages based on calcareous nannofossil biostratigraphy and the correlation of trends in chemo- and sequence stratigraphy. K–Ar dating on well-preserved glauconite grains from the “Marnes d’Uttins” and lowermost part of the “Urgonien Jaune” delivered ages of 127.5 ± 2.3 and 130.7 ± 2.6 Ma, respectively. Whereas the age of the glauconitic level near the base of the “Urgonien Jaune” is chronostratigraphically meaningful, the K–Ar age of the “Marnes d’Uttins” appears too young relative to the presently used time scale. This may be related to rejuvenation of the K–Ar chronometer due to post-depositional Ar loss, most likely during hardground formation. The ages obtained here confirm the Late Barremian age for the onset of the Urgonian platform, an age which is conform with ages obtained in the Helvetic Alps and elsewhere along the northern Tethyan margin.     

Heavy minerals of the Barakar Formation,Talchir Gondwana Basin,Orissa

Heavy mineral analysis has been carried out in the Barakar Formation of the Talchir Gondwana Bbasin, Orissa. The characteristic heavy minerals are garnet, zircon, tourmaline, rutile, biotite, chlorite, pyroxenes, hornblende, staurolite, sillimanite, apatite, epidote, sphene, spinel and siderite including opaques and leucoxene. These heavy minerals are divisible into four groups on the basis of principal component analysis and suggest derivation of Barakar sediments from pegmatite, acid and basic igneous as well as low- and high-rank metamorphic rocks lying to the south of the Talchir Gondwana Basin. Though the heavy mineral suites of all the sandstone samples are by and large similar, differences have been noticed in the frequencies of many heavy minerals in vertical succession. Cyclic nature and vertical fluctuation of heavy mineral frequencies can be ascribed to variation of the relief of the source area, sudden release of some of the minerals in the source region and/or existence of favourable geochemical condition to escape partial dissolution.     

Geology and geochemistry of the Bingdaban ophiolitic mélange in the boundary fault zone on the northern Central Tianshan Belt,and its tectonic implications

The properties and tectonic significance of the fault bound zone on the northern margin of the Central Tianshan belt are key issues to understand the tectonic framework and evolutionary history of the Tianshan Orogenic Belt. Based on the geological and geochemical studies in the Tianshan orogenic belt, it is suggested that the ophiolitic slices found in the Bingdaban area represent the remaining oceanic crust of the Early Paleozoic ocean between the Hazakstan and Zhungaer blocks. Mainly composed of basalts, gabbros and diabases, the ophiolites were overthrust onto the boundary fault between the Northern Tianshan and Central Tianshan belts. The major element geochemistry is characterized by high TiO₂ (1.50%–2.25%) and MgO (6.64%–9.35%), low K₂O (0.06%–0.41%) and P₂O₅ (0.1%–0.2%), and Na₂O>K₂O as well. Low ΣREE and depletion in LREE indicate that the original magma was derived from a depleted mantle source. Compared with a primitive mantle, the geochemistry of the basalts from the Bingdaban area is featureded by depletion in Th, U, Nb, La, Ce and Pr, and unfractionated in HFS elements. The ratios of Zr/Nb, Nb/La, Hf/Ta, Th/Yb and Hf/Th are similar to those of the typical N-MORB. It can be interpreted that the basalts in the Bingdaban area were derived from a depleted mantle source, and formed in a matured mid-oceanic ridge setting during the matured evolutionary stage of the Northern Tianshan ocean. In comparison with the basalts, the diabases from the Bingdaban area show higher contents of Al₂O₃, ΣREE and HFS elements as well as unfractionated incompatible elements except Cs, Rb and Ba, and about 10 times the values of the primitive mantle. Thus, the diabases are thought to be derived from a primitive mantle and similar to the typical E-MORB. The diabases also have slight Nb depletion accompanying no apparent Th enrichment compared with N-MORB. From studies of the regional geology and all above evidence, it can be suggested that the diabases from the Bingdaban area were formed in the mid-oceanic ridge of the Northern Tianshan ocean during the initial spreading stage. Supported by the Major State Research Program of PRC (Grant No. 2001CB409801), the National Natural Science Foundation of China (Grant Nos. 40472115 and 40234041) and the State Research Program of China Geological Survey (Grant No. 2001130000-22)     

Phases of the Fe–C–N system as hosts of mantle carbon and nitrogen: Experimental studies at 7.8 GPa and 1350°C

Parts of the Fe–C–N system were studied in experiments at 7.8 GPa and 1350°C. It was shown that the admixture of nitrogen extends considerably the domain of melt stability in the system at temperatures close to the Fe–Fe₃C eutectic temperatures. Nitrogen solubility in cementite in equilibrium with the nitrogen- rich melt is below the detection limit of the EMPA technique applied. The metal melt is the only nitrogen concentrator (up to 4 wt % of N) in the range of compositions considered. The data obtained permit the conclusion that, in the case of complete dissolution of carbon and nitrogen, which might occur in the enriched mantle, native iron at ~250 km depth should either be completely molten or consist of a melt and carbide of iron.     

The anisotropy of kinetic and current helicity

A three-dimensional model for thermal convection with a dynamo in a rotating planar layer heated from below is used to investigate the behavior of the mean kinetic and current helicities. In spite of the presence of gravity and rotation, which introduce anisotropy into the system, the components of the helicity determined from the field components in the directions tangent and normal to the boundary have similar values. The existence of a separation by scale, when the current helicity has different signs on different spatial scales, is demonstrated. The number of regions where the sign of the helicity does not coincide with the sign of its mean value in that region is estimated (～43?45% of the total number of regions). The estimates presented are relevant for interpretations of observations of solar activity and analysis of the properties of rotating magnetohydrodynamical turbulence.     

Improving conveyance of uncertainties in the findings of the IPCC

Authors of the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) received guidance on reporting understanding, certainty and/or confidence in findings using a common language, to better communicate with decision makers. However, a review of the IPCC conducted by the InterAcademy Council (2010) found that “the guidance was not consistently followed in AR4, leading to unnecessary errors . . . the guidance was often applied to statements that are so vague they cannot be falsified. In these cases the impression was often left, quite incorrectly, that a substantive finding was being presented.” Our comprehensive and quantitative analysis of findings and associated uncertainty in the AR4 supports the IAC findings and suggests opportunities for improvement in future assessments.     

Effects of degree of saturation on shallow landslides triggered by rainfall

The empirical rainfall threshold concept and the physical-based model are two commonly used approaches for the assessment of shallow landslides triggered by rainfall. To investigate in detail the rainfall-triggered shallow landslides, many physical-based models coupling the infinite slope stability analysis with the rainfall infiltration modeling in variably saturated soil were developed. However, in those physical-based shallow landslide models, the unit weight and the unsaturated shear strength were assumed constant rather than depending on the degree of saturation. In this study, the effects of the unit weight and the unsaturated shear strength as function of degree of saturation on rainfall-triggered shallow landslides are examined. Several designed scenarios and a real case scenario are used to conduct the examinations. The results show that not only the occurrence of shallow landslides but also the failure depth and the time to failure could be misassessed if the influences of degree of saturation on the unit weight and the unsaturated shear strength are neglected.     

EM and GPR investigations of contaminant spread around the Hoc Mon waste site,Vietnam

This paper is presenting the results from near-surface geophysical surveys near the waste site of Hoc Mon in southern Vietnam where leachate contamination has been recognized at the surface. Using EM and GPR surveys, we were able to determine the lateral extent of a contaminated area of high electrical conductivity and have identified channels that concentrate the contaminant flow. The simple relationship between the electrical resistivity and the leachate concentration is suggested and estimated the in situ leachate concentration from the inversion of the EM data; values are as high as 40%. Thanks to a permeability barrier leachate flow is confined to the shallow subsurface, making it easier to apply possible site remediation projects.