Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes. 相似文献
Land use based on landscape ecological security pattern provides a scientific basis for alleviating conflicts between land conservation and human use, ensuring concomitant economic development and ecological integrity. The majority of studies by Chinese researchers have been focused on the carrying capacity and land development intensity, and less attention has been paid to the ecological security pattern of the landscape in Mianzhu in the transitional zone between the Chengdu Plain region and the Longmen Mountains, western China. However, land resources are undergoing significant changes resulting from land use associated with rapid economic development and demographic growth. In this study, we constructed a minimum cumulative resistance model in Mianzhu in the transitional zone, and the land space was divided into optimized development areas, key development areas, restricted development areas, and prohibited development areas according to the landscape ecological security pattern based on the model surface. These land use types covered 7218.39 ha, 17,974.75 ha, 21,545.39 ha, and 77,791.46 ha, respectively. We also examined land use changes over the last 20 years and quantitatively analyzed the relationships between land use changes and geographic factors based on remote sensing and geographic information system. The information obtained from this research ultimately impacts future policies and plans regarding land resources and can be used to promote the sustainable use of land resources in the region.