不透明矿物流体包裹体红外显微测温研究：进展、存在问题与解决方案

流体包裹体是古地质流体的唯一直接记录,为反演地质过程涉及的物理化学条件等提供了最为重要的证据。流体包裹体是研究热液矿床成矿流体最有利手段,常规的测试对象为透明的脉石矿物,而矿石矿物中的流体包裹体更为直接、准确地记录了成矿流体信息。大多数矿石矿物在显微镜透射光下不透明,其捕获的流体包裹体研究需要使用配备有红外成像系统的显微镜进行。近20 年来,不透明矿物流体包裹体红外显微测温研究获得了长足的进展,但其中仍有一些问题尚未解决,制约了该方法的应用;同时,国内该研究领域正处在起步阶段,多个实验室已安装了红外测试仪器,但尚未开展系统的研究工作。因此,需要对该研究领域进行综述,探讨存在的问题,以促进该研究方法的发展。本文首先介绍了红外显微镜仪器工作原理及样品制备注意事项,阐述了影响不透明矿物红外透明度的因素,讨论了红外显微测温研究中的主要问题和难点,并针对测温过程中相变观察困难、红外光可能影响测温结果等问题提出可行的解决方案,最后论述了红外显微测温系统在矿床学领域的应用前景。     

地下立体交通箱涵管幕双重置换自动导向技术研究

为适应地下立体交通工程箱涵顶进置换管幕施工的新方法,研究开发了一套以自动全站仪为主的智能导向系统。介绍了该智能导向系统的原理及关键技术,并结合该系统在上海金山既有铁路下顶进公路箱涵工程的顺利完成和成功应用,表明了该系统在实际施工中的优越性与实用性,具有自动化程度高、可靠性强、测量精度高的特点,可以为纠偏提供实时偏差信息,达到信息化施工的目标。     

安徽宣城红土微生物GDGTs分布特征及其古环境意义

中国南方更新世红土是古气候环境变化研究非常重要的载体之一,红土微生物类脂分子是其古气候环境研究的有效指标,但其在红土中的古气候意义需要更进一步的挖掘和明确.选取处于气候变化敏感地带并且已有很好年代学基础的安徽宣城红土剖面进行详细的野外调查和系统的样品采集,利用改善后的碱式水解法提取红土微生物类脂分子,通过对比分析、比较印证等方法对其中的甘油二烷基链甘油四醚(glycerol dialkyl glycerol tetraethers,简称GDGTs)进行系统研究.宣城剖面GDGTs分布特征显示:剖面下部各指标呈旋回性变化、而上部相对稳定,表明形成初期环境比较动荡,而后期成土环境相对稳定;土壤pH为7.0~8.0,推测其物源主要来源于北方干旱区或长江中下游干涸河滩沉积;BIT指标反映宣城地区在130 ka BP左右气候极为干旱.结果表明,红土中微生物类脂物GDGTs能够定量、高分辨率地重建安徽宣城的古气候环境,具有重要的研究意义.      

Geoinformatics education in China

The paper gives an overview of the current status of education in geoinformatics in China. First, the paper provides a brief introduction to the history of geoinformatics education in China and a general review of the scientific and technological development. It then presents how the development affects the education and training in China. In the paper, universities and institutes in China that can award academic degrees related to geoinformatics are summarized, and undergraduate majors are briefly introduced. Next, the paper reports the work having been done by the national expert group on Surveying and Mapping, including the revision of discipline catalog and guide for graduate education and requirements. A list of typical curricula in geoinformatics education is suggested. Activities on promoting the graduate student exchange platform are presented. Finally, a case study of geoinformatics education in Wuhan University is discussed.     

Building a model-based personalised recommendation approach for tourist attractions from geotagged social media data

When travelling, people are accustomed to taking and uploading photos on social media websites, which has led to the accumulation of huge numbers of geotagged photos. Combined with multisource information (e.g. weather, transportation, or textual information), these geotagged photos could help us in constructing user preference profiles at a high level of detail. Therefore, using these geotagged photos, we built a personalised recommendation system to provide attraction recommendations that match a user's preferences. Specifically, we retrieved a geotagged photo collection from the public API for Flickr (Flickr.com) and fetched a large amount of other contextual information to rebuild a user's travel history. We then created a model-based recommendation method with a two-stage architecture that consists of candidate generation (the matching process) and candidate ranking. In the matching process, we used a support vector machine model that was modified for multiclass classification to generate the candidate list. In addition, we used a gradient boosting regression tree to score each candidate and rerank the list. Finally, we evaluated our recommendation results with respect to accuracy and ranking ability. Compared with widely used memory-based methods, our proposed method performs significantly better in the cold-start situation and when mining ‘long-tail’ data.     

断裂带的韧-脆性转化与成矿

根据河南西部绿岩型脉状金矿的一些地质现象,探讨了韧性剪切带转化为脆性断裂的机制.韧性剪切过程岩石的面理化为矿液参与断裂作用,增加流体压力创造了条件.流体压力的增加一方面可以改变断裂的力学性质;另一方面可以压裂围岩,促进断裂韧-脆性转化,为脉状矿床的形成创造了条件.     

A double-differenced cycle slip detection and repair method for GNSS CORS network

The difficulty to detect and repair cycle slip of carrier phase measurements is a key limit for continuously high accuracy of GNSS positioning and navigation services. We propose an automated cycle slip detection and repair method for data preprocessing of a CORS network. The method jointly uses double-differenced (DD) geometry-free (GF) combination and ionospheric-free observation corrected for the computed geometrical distance (IF-OMC) to estimate the cycle slips in dual-frequency observations. The DD GF combination, which is only affected by the ionospheric residual, can be used to detect cycle slips with high reliability except for special pairs such as (77, 60) on GPS L1/L2 frequencies. The detection principle of the IF-OMC observable is such that there is a large discontinuity related to the previous epoch when cycle slips occur at the present epoch. The disadvantages of these two combinations can be overcome employing the proposed detection method. The cycle slip pair (77, 60) has no effect on the GF combination, while a change of 14.65 m is derived from GPS L1/L2 observations using the IF-OMC algorithm. Using pre-determined station coordinates as precise values, we found that the accuracy of the DD IF-OMC combination was 18 mm for a 200-km CORS baseline. Therefore, cycle slips in dual-frequency observations can be correctly and uniquely determined using DD GF and IF-OMC equations. The proposed method was verified by adding simulated cycle slips in observations collected from the CORS network under a quiet ionosphere and shown to be effective. Moreover, the method was assessed with observations made during intense ionospheric activity, which generated extensive cycle slips. The results show that the algorithm can detect and repair all cycle slips apart from two exceptions relating to long data gaps.     

SH波入射下圆弧状沉积盆地地震反应瞬态解析解计算

地震波散射问题的解析解是研究局部场地、地形、盆地等不规则地层结构对地震动参数放大效应影响的重要理论工具。现有解析解大部分在频域内给出,无法直接用于研究不规则地层结构对地震动峰值、反应谱等参数的放大效应。本文基于平面SH波入射下圆弧状沉积盆地动力响应宽频带稳态解析解,通过Fourier变换,获取瞬态响应解析解。基于此,研究El Centro波入射下,沉积盆地对地震动峰值加速度、峰值速度、峰值位移及不同周期反应谱的放大效应。研究结果表明,盆地宽度和深度、沉积介质波速、入射波角度等对盆地放大效应具有显著影响,地震动反应谱谱比最大值超过2.0,且宽度达10 km的较大型盆地对长周期地震动参数具有显著放大效应,对于位于该类盆地的超高层建筑、大型储液罐、大跨度桥梁等长周期结构,应充分考虑盆地对抗震设防参数的影响。     

Distribution and significance of novel low molecular weight sterenes in an immature evaporitic sediment from the Jinxian Sag,North China

An unusual series of C₂₂–C₂₇ monounsaturated sterenes and C₂₄–C₃₀ tetracyclic terpanes (17,21-secohopanes) were detected in relatively high concentrations in an immature evaporitic marl sediment of the Jinxian Sag, Bohai Bay Basin, North China. The site of unsaturation in these novel sterenes is assigned tentatively to the D ring on the basis of mass spectral interpretation, which also distinguishes them from reported unsaturated sterenes. Other hydrocarbon biomarker or stable isotope characteristics are indicative of microbial (e.g. methyl hopanes), phytoplankton or higher plant (depleted δ¹³C values of isoprenoids and hopanes) inputs and an anoxic carbonate depositional environment (hexacyclic hopanes; tetracyclic terpanes). The hydrocarbon composition showed no obvious biodegradation and the relatively high concentration of unsaturated terpenoids (e.g. gammacerene) and low values of other established maturity parameters (T_s/T_m = 0.23; R_o = 0.44%; T_max = 417 °C), are consistent with sediments of low maturity. The novel, low molecular weight sterenes and the tetracyclic terpanes may be early diagenetic products of microbial sources in a carbonate environment.     

1,4-蒽醌衍生物的合成

通过高酞酸酐与2-氯-5-甲基-1,4-苯醌反应,经过最长线性步骤6步和3步反应,分别以16%和47%的总产率合成了2个1,4-蒽醌衍生物12和14。其中,化合物14的合成为首次报道。所有合成的化合物均采用核磁共振波谱和质谱方法对其进行了表征和确证,并对高酞酸酐与苯醌反应生成1,4-蒽醌的反应机理进行了探讨。