Core Jamming in Unconsolidated Formations

Geotechnical and Geological Engineering - In coring operations, core jamming is a permanent concern, taking place when the rock core sample becomes stuck within the inner core barrel, thus...     

Brain acetylcholinesterase as a marine pesticide biomarker using Brazilian fishes

Brain acetylcholinesterase (AChE) of some fishes from the coast of Rio de Janeiro State was studied as a possible pesticide biomarker in marine environmental monitoring. AChE specific activity in brain varied from 145 to 530 U/g of proteins and the Michaelis-Menten constant (K(M)) for acetylthiocholine varied from 104 to 291 microM among the 20 species studied. The enzyme sensitivity to methyl paraoxon, evaluated by the inhibition kinetic constants, shows that some species (Paralonchurus brasiliensis and Genidens genidens) are more sensitive (IC50-30 min=455 and 468 nM, respectively). The less sensitive Merluccius hubbsi and Percophis brasiliensis (IC50-30 min=3339 and 3259 nM, respectively) belong to the super-order Paracanthopterygii, which includes the more ancient species. On the other hand, more susceptible species belong to the super-order Acanthopterygii, which includes more recent species. These results suggest a possible evolutionary linkage for AChE sensitivity to methyl paraoxon. The application of inhibition kinetic constants for fish brain AChE in phylogenetic studies is still being investigated. The results have shown that a fish sentinel species should have the highest brain AChE level among the more sensitive ones.     

C-, Sr-isotope and Hg chemostratigraphy of Neoproterozoic cap carbonates of the Sergipano Belt,Northeastern Brazil

Two cap carbonates overlying glaciogenic diamictites crop out extensively in the eastern Vaza Barris Domain of the Sergipano Belt, northeastern Brazil. They are represented by carbonates of the Jacoca Formation, resting on top of diamictite of the Ribeiropolis Formation, and by the Olhos D’Agua Formation (carbonates, organic-rich towards the top), which overlies diamictite of the Palestina Formation. These two sequences were deformed and metamorphosed at sub-greenschist facies-conditions during the Brasiliano cycle (650–600 Ma).     

Using helicopter electromagnetic data to predict groundwater quality in fractured crystalline bedrock in a semi-arid region, Northeast Brazil

Geostatistical modeling, using airborne and borehole electromagnetic data, was used to estimate electrical conductivity in groundwater within fractured paragneisses and migmatites in a semi-arid climate in northeastern Brazil. Despite the geologic heterogeneity of crystalline aquifers, the use of high resolution helicopter electromagnetic (HEM) data enabled the characterization of groundwater electrical conductivity where data from drilled wells were insufficient. The tacit assumption is that HEM measurements can be used to relate rock electrical conductivity to groundwater electrical conductivity. In this study, the HEM data were used as an external drift variable in non-stationary estimation and stochastic simulation to identify the variability of groundwater electrical conductivity. Validation tests, comparing predicted values for groundwater conductivity with measurements in new wells, confirmed the success of these models in locating fresh groundwater sources in crystalline bedrock.     

Spectral analysis of climatological series in Duero Basin

Summary General harmonic analysis (FFT) and maximum entropy spectral analysis (MEM) are used in order to study annual and monthly values of air temperature, precipitation and insolation in a number of weather stations in Duero Hydrographic Basin. The corresponding spectra estimates were prepared and compared. MEM estimates show better power resolution and a better spectral definition than FFT estimates. Based on the similarity behavior of the spectra, four main climatic zones were clearly defined. Finally, physical interpretation of the main features of the most representative spectra for the four regions was attempted.With 9 Figures     

Harmonic analysis of the mean northern hemisphere water vapor distribution for the year 1950

Summary Harmonic analyses along latitudes 30°, 45° and 60° of the mean northern hemisphere water vapor field are presented. The seasonal variations of these spectra are investigated and the relative contributions of the various scales of mean eddies to the meridional transport of water vapor are calculated. Of special interest is the finding that perturbations of wave number 2, corresponding to the great continents and oceans, are dominant at all three latitudes and of primary importance in effecting the northward transport of water vapor.The research reported in this article was sponsored by the Geophysics Research Directorate, Air Force Cambridge Research Center, under Contract No. AF 19 (604)-2242.     

Sediment hosted lead–zinc deposits of the Neoproterozoic Bambuí Group and correlative sequences, São Francisco Craton, Brazil: A review and a possible metallogenic evolution model

The Proterozoic sediment-hosted Zn–(Pb) sulfide and non-sulfide deposits of the São Francisco Craton, Brazil, are partially syn-diagenetic and epigenetic and were probably formed during extensional events. The majority of the deposits occur within shallow water dolomites. The Pb isotopic data of sulfides are relatively homogeneous for individual deposits and plot above the upper crust evolution curve of the Plumbotectonic model. Some of the deposits are characterized by highly radiogenic lead (²⁰⁶Pb/²⁰⁴Pb ≥ 21) originating from the highly radioactive crust of the São Francisco Craton. Pb and S isotopic data suggest the sources of metal and sulfur for the deposits to be the basement rocks and seawater sulfates in the sediments, respectively. The relatively high temperatures of formation (100 to 250 °C) and moderate salinity (3% to 20% NaCl equiv.) of the primary fluid inclusions in the sphalerite crystals suggest the participation of basinal mineralizing fluids in ore formation. The steep paleo-geothermal gradient generated by the radioactively enriched basement rocks probably assisted in heating up the circulating mineralizing fluids.     

Isotope measurements and ground water flow modeling using MODFLOW for understanding environmental changes caused by a well field in semiarid Brazil

Measurements of the environmental isotopes carbon-14 and oxygen-18 and of the electrical conductivity in ground water, together with MODFLOW-88 (DOS) simulations of pumping tests, were used to achieve a detailed understanding of the functioning of an aquifer in the area of a well field. The methodology was applied in the sedimentary basin of the Cariri region, in the south of Ceará State in Brazil. Localized hydraulic connections between adjacent aquifer units could be detected, and mixing ratios for the contributions from the units involved were determined. Cone of depression simulations for a three-year drought period revealed well interference and a drastic lowering of the piezometric level, thereby explaining the hydrogeologic changes and transformations in vegetation that were observed in the area of the well field. The combined use of the modeling tools and the geochemical field observations is shown to provide more detailed insight into the conceptual model of the groundwater flow system.     

Correlated humidity and temperature measurements in the urban atmospheric boundary layer

Summary To investigate the effect of atmospheric turbulence on microwave communication links, temperature and water vapor pressure have been measured and radio refractivity has been computed, during different meteorological conditions, in the atmospheric boundary layer of an urban site. The cospectra between temperature (T) and water vapor pressure (e) have been found to be either negative over the whole range of frequencies, or the low-frequency end of the cospectrum is of opposite sign relative to higher frequency end. In both cases cospectra follow a–5/3 law in the inertial subrange, in agreement with the theoretical predictions. The coherence spectra clearly show that the temperature and humidity fluctuations are highly coherent within the inertial subrange under both convective and stable conditions. The relative contribution ofC _T ² ,C _eT andC _e ² to the real refractive index structure parameterC _n ² is examined and discussed.With 4 Figures