Histogram and variogram inference in the multigaussian model

Several iterative algorithms are proposed to improve the histogram and variogram inference in the framework of the multigaussian model. The starting point is the variogram obtained after a traditional normal score transform. The subsequent step consists in simulating many sets of gaussian values with this variogram at the data locations, so that the ranking of the original values is honored. The expected gaussian transformation and the expected variogram are computed by an averaging operation over the simulated datasets. The variogram model is then updated and the procedure is repeated until convergence. Such an iterative algorithm can adapt to the case of tied data and despike the histogram. Two additional issues are also examined, referred to the modeling of the empirical transformation function and to the optimal pair weighting when computing the sample variogram.     

Hydrothermal bitumen generated from sedimentary organic matter of rift lakes – Lake Chapala, Citala Rift, western Mexico

Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition (δ¹³C = −21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka (¹⁴C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200–250 °C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions.     

Geochemical characteristics of mineral air particles emitted inside a clay atomisation plant which introduces waste recycling processes

The objective of this work is to assess the concentrations of three factions of air particles (settable particles, TSP and PM10) and the levels of several toxic elements in a clay atomisation industry through aerosol sampling at several points inside an industrial plant. Mechanical activities, which produce diffuse emissions, are the main process of discharge of particles in both indoor and outdoor workplace environments in the atomisation plant. The levels of As, Cd, Pb, Zn, Ba and Ni increase in the zones with higher concentrations of particles and lower ventilation. The concentrations of As and F are not influenced by the recycling processes. The levels of Cd and Pb do not show great enrichment in air particles collected inside the atomisation plant although the content of both elements is associated with ceramic muck recycling. Finally, the content of B in waste water is mainly transferred in gaseous phase to the atmosphere during the process of drying by atomisation.     

Age, distribution, tectonics, and eustatic controls of the Paranense and Caribbean marine transgressions in southern Bolivia and Argentina

Marine transgression onto the South American continent took place at least twice in the Miocene along distinct paleogeographic corridors. The first event occurred between 15 and 13 Ma and the second between 10 and 5? Ma. Each event has particular dominant variables (tectonism, eustacy, sediment accumulation rate) that permitted the preservation of the record and development of the sea on the continent. The 15–13 Ma transgression was tectonically and eustatically controlled, flooding older sedimentary accommodation zones on the South American plate during a global high sea level, whereas the 105? Ma event was predominantly tectonically controlled, generated by tectonic loading created in the Cordillera Oriental fold-and-thrust belt. A new 7.72±0.31 Ma ⁴⁰Ar/³⁹Ar date from the Río Parapetí in Bolivia suggests that the 15–13 Ma transgression registered in Argentina produced no continental connection to the Caribbean transgression, registered in Bolivia, because of temporal constraints.     

Long-term deforestation in NW Spain: linking the Holocene fire history to vegetation change and human activities

The Holocene fire regime is thought to have had a key role in deforestation and shrubland expansion in Galicia (NW Spain) but the contribution of past societies to vegetation burning remains poorly understood. This may be, in part, due to the fact that detailed fire records from areas in close proximity to archaeological sites are scarce. To fill this gap, we performed charcoal analysis in five colluvial soils from an archaeological area (Campo Lameiro) and compared the results to earlier studies from this area and palaeo-ecological literature from NW Spain. This analysis allowed for the reconstruction of the vegetation and fire dynamics in the area during the last ca 11 000 yrs. In the Early Holocene, Fabaceae and Betula sp. were dominant in the charcoal record. Quercus sp. started to replace these species around 10 000 cal BP, forming a deciduous forest that prevailed during the Holocene Thermal Maximum until ～5500 cal BP. Following that, several cycles of potentially fire-induced forest regression with subsequent incomplete recovery eventually led to the formation of an open landscape dominated by shrubs (Erica sp. and Fabaceae). Major episodes of forest regression were (1) ～5500–5000 cal BP, which marks the mid-Holocene cooling after the Holocene Thermal Maximum, but also the period during which agropastoral activities in NW Spain became widespread, and (2) ～2000–1500 cal BP, which corresponds roughly to the end of the Roman Warm Period and the transition from the Roman to the Germanic period. The low degree of chronological precision, which is inherent in fire history reconstructions from colluvial soils, made it impossible to distinguish climatic from human-induced fires. Nonetheless, the abundance of synanthropic pollen indicators (e.g. Plantago lanceolata and Urtica dioica) since at least ～6000 cal BP strongly suggests that humans used fire to generate and maintain pasture.     

Low-order stabilized finite element for the full Biot formulation in soil mechanics at finite strain

This article presents a novel finite element formulation for the Biot equation using low-order elements. Additionally, an extra degree of freedom is introduced to treat the volumetric locking steaming from the effective response of the medium; its balance equation is also stabilized. The accuracy of the proposed formulation is demonstrated by means of numerical analyses.     

Geophysical evidence for a large impact structure on the Falkland (Malvinas) Plateau

A large, roughly circular structural basin is recognised on the Falkland (Malvinas) Plateau to the NW of West Falkland (Gran Malvina) Island (S 51°00′, W 62°00′). The basin, seen in seismic‐reflection profiles and evident as a large negative gravity anomaly, has a diameter of ~250 km. The age of the basin is estimated to be Late Palaeozoic. It is completely buried by younger sediments and has no topographic expression on the sea floor. We propose that the basin and geophysical anomalies, especially the combination of a large circular negative gravity anomaly with a rim of positive anomalies, and a marked circular series of positive magnetic anomalies in the same area, may be best explained by the presence of a large buried impact structure.     

Pre‐Alpine discordant granitic dikes in the metamorphic core of the Betic Cordillera: tectonic implications

Pegmatite dikes bearing andalusite crosscut foliation S₂ in Alpujarride gneisses and schists. Post‐S₂ andalusite is transposed by a foliation S₃, defined by fibrolite, which affects the dikes. The dikes represent highly differentiated granitic magmas with low REE and Zr contents and a positive Eu anomaly. U‐Pb SHRIMP dating of magmatic zircons provided Pan‐African ages (cores) and late Variscan ages (rims). However, U‐rich rims also provided metamorphic Alpine ages, supporting a polyorogenic tectonometamorphic history for pre‐Mesozoic Alpujarride rocks.