Crustal reworking and orogenic styles inferred from zircon Hf isotopes:Proterozoic examples from the North Atlantic region

Zircon Hf evolutionary patterns are powerful tools to investiage magma petrogenesis and crustal evolution. The ~(176)Hf/~(177)Hf isotopic signature of a rock is particularly informative and can be used to derive an estimation of the time when mantle extraction and diagnose closed system reworking where successive samples through time define an Hf evolution array dependant on the source Lu/Hf ratio. However, many magmatic events require new mantle addition as the thermal impetus for melting pre-existing crust. In this situation, rather than simply reflecting reworking, the isotopic signature indicates mixing with contributions from both reworked crust and new radiogenic input. Different geodynamic settings have different propensities for either reworking or addition of new mantle-derived magma. Hence, Hf-time trends carry within them a record, albeit cryptic, of the evolving geodynamic environment as different tectonic configurations recycle and add new crust at different rates, magnitudes, and from different sources. As an example of the difference in apparent Hf evolution slopes, we present Hf-time compilations from three geographically distinct Meso-to Neoproterozoic orogenic belts in the North Atlantic Region whose geodynamic configurations remain a subject of debate. We use the εHf/Ma trajectory to assist in understanding their evolution. The εHf/Ma trajectory of the Sveconorwegian Orogen corresponds to a ~(176)Lu/~(177) Hf ratio of 0.012, which implies a process driven primarily by reworking of preexisting crust that is balanced with input from the depleted mantle resulting in a relatively shallowεHf/Ma slope. The Valhalla Orogen reveals a similar comparatively shallow εHf/Ma path. In stark contrast to these patterns is the steep εHf/Ma trajectory of the Grenville Orogen that requires a mixing process involving a greater contribution of old crust of at least ～ 1.8 Ga age. The degree of reworking required to produce the εHf/Ma trend of the Grenville Orogen is consistent with a continent-continent collisional orogeny whereas both Sveconorwegian and Valhalla orogens appear more consistent with accretionary margins.     

Natural-abundance radiocarbon as a tracer of assimilation of petroleum carbon by bacteria in salt marsh sediments

The natural abundance of radiocarbon (¹⁴C) provides unique insight into the source and cycling of sedimentary organic matter. Radiocarbon analysis of bacterial phospholipid lipid fatty acids (PLFAs) in salt-marsh sediments of southeast Georgia (USA)—one heavily contaminated by petroleum residues—was used to assess the fate of petroleum-derived carbon in sediments and incorporation of fossil carbon into microbial biomass. PLFAs that are common components of eubacterial cell membranes (e.g., branched C₁₅ and C₁₇, 10-methyl-C₁₆) were depleted in ¹⁴C in the contaminated sediment (mean Δ¹⁴C value of +25 ± 19‰ for bacterial PLFAs) relative to PLFAs in uncontaminated “control” sediment (Δ¹⁴C = +101 ± 12‰). We suggest that the ¹⁴C-depletion in bacterial PLFAs at the contaminated site results from microbial metabolism of petroleum and subsequent incorporation of petroleum-derived carbon into bacterial membrane lipids. A mass balance calculation indicates that 6-10% of the carbon in bacterial PLFAs at the oiled site could derive from petroleum residues. These results demonstrate that even weathered petroleum may contain components of sufficient lability to be a carbon source for biomass production by marsh sediment microorganisms. Furthermore, a small but significant fraction of fossil carbon is assimilated even in the presence of a much larger pool of presumably more-labile and faster-cycling carbon substrates.     

Modelling alluvial fan morphology

A mathematical model which estimates the scale-independent sediment surface profile of alluvial fans has been developed. This model utilizes a diffusive sediment transport model and an unsteady, radial flow, conservation relationship. These equations are approximately solved assuming a quasi-steady-state closure with appropriate modelling assumptions for two end member fan types: (1) fans where most of the fan surface is depositionally active (denoted here as ‘homogeneous’) and (2) fans characterized by channelling and sediment sorting processes. The fundamental result for these two fan types is a dimensionless sediment profile relationship which approximates most fan surfaces. The model suggests that the overall dimensionless morphology of alluvial fans is governed more by fundamental diffusion principles in sediment deposition than by individual environmental or basin characteristics. Additionally, this work potentially can be extended to model temporal variation in fan development. Preliminary comparison with alluvial fan profiles is reasonable, indicating that this model provides useful qualitative and quantitative information relating to alluvial fan process and morphology. Copyright © 1999 John Wiley & Sons, Ltd.     

Vertical Profiles of Major Organic Geochemical Constituents and Extracellular Enzymatic Activities in Sandy Sediments of Aransas and Copano Bays, TX

Vertical distribution patterns of organic geochemical constituents and the enzymes aminopeptidase and β-glucosidase provide insights about the nature and reactivity of sediment organic matter in the sandy sediments of two shallow “South Texas” estuaries. Sediment total organic carbon (TOC) δ¹³C values indicated that the organic matter (OM) was derived more from a mixture of seagrass and phytoplankton than from terrigenous OM. Down-core amounts of TOC and total nitrogen (TN) were <0.2% of dry weight, respectively. Enzyme activities were highest near surface and ranged from 25 to 1 μM/h for aminopeptidase as compared to 5 to 0.2 μM/h for glucosidase. In Aransas Bay, aminopeptidase activity correlated with sediment TN content (r _s = 0.30) and β-glucosidase with TOC content (r _s = 0.27). In Copano Bay, aminopeptidase correlated with TOC, TN, and carbohydrate content (r _s = 0.89, 0.90, and 0.83, respectively). Variations of glucosidase activity also related positively to TOC, TN, and total carbohydrate content (r _s = 0.68, 0.77, and 0.48, respectively). Overall, enzyme activities in these low OM, sandy sediments resembled those for other benthic marine environments.     

Heavy metal concentrations in sediment deposits on the Tar River floodplain following Hurricane Floyd

The relation between the magnitude of a flood event and the resulting environmental impacts remains unclear. This study examines the impact of the flood of record on heavy metal deposition on the Tar River floodplain in eastern North Carolina, USA. Samples of sediment deposited on the floodplain following Hurricane Floyd were collected from 85 sites along the lower Tar River basin and analyzed for heavy metal concentration. The Hurricane Floyd event is the flood of record for the Tar River basin. Despite the magnitude of the flood, little suspended sediment was deposited on the floodplain. In almost all cases the deposition was less than 0.2 cm. There was variability in heavy metal content from site to site, but the overall concentrations were lower than might be expected for a flood of the magnitude of Floyd. To aid in comparison of contamination levels, the heavy metal concentrations were normalized to two environmental standards; the EPA preliminary remediation goals for residential soil and the general background concentrations of stream sediments throughout the Tar River basin. Most samples were highly enriched in heavy metals relative to the background concentration of stream sediments. However, samples were generally not contaminated relative to EPA PRG regulations. Arsenic, which was significantly elevated in nearly all samples, was the only exception. This contradiction makes it clear that the standard to which contaminants are compared must be considered carefully. The overall low concentration of heavy metals was likely the result of smaller flooding from Hurricane Dennis, 10 days prior to Hurricane Floyd, moving most of the stored sediment out of the basin prior to wide-spread overtopping of the banks. The implication is that event sequencing is as important as flood magnitude when examining environmental impacts.     

Theoretical constraints and chronological evidence of Holocene coastal development in central and southern New South Wales, Australia

Holocene coastal evolution in New South Wales has been interpreted essentially as the unfolding of the impact of marine transgression. Sea level on this coast supposedly reached its present height at 6–6.5 ka, and varied < 1 m since then. The early Holocene rise of the sea has been considered the key factor (“forcing function”) in dune migration, coastal sand barrier development, and the evolution of estuaries. Episodic storminess during the late Holocene has been seen as an important, though secondary, factor in beach erosion and dune mobilisation. An alternate interpretation presented here challenges the concept of the marine transgression as the primary “forcing function”. It (a) attributes early Holocene dune mobilisation to climate rather than the rising sea; (b) shows that the sea reached its present level by 7 ka and rose to at least + 2 m until 1.5 ka; (c) links late Holocene dune activity to local disruption of vegetation rather than to regional episodic storminess; (d) demonstrates a fall of 2°C in sea surface temperature after 3 ka that coincides with the onset of barrier erosion; (e) recognises the imprint of at least three tsunamis in the coastal sedimentary record.     

Diphytanyl glycerol ether distributions in sediments of the Orca Basin

Archaebacterially produced diphytanyl glycerol ether (DPGE) was examined in core sediments from the Orca Basin, an anoxic hypersaline basin in the northwestern Gulf of Mexico, to observe its spatial variability and potential origin. A differential extraction protocol was employed to quantify the isopranyl glycerol ethers associated with unbound, intermediate-bound, and kerogen-bound lipid fractions. Archaebacterial lipids were evident at all depths for the unbound and intermediate-bound fractions. Concentrations of DPGE ranged from 0.51 to 2.91 micrograms/g dry sediment at the surface and showed secondary maxima deeper in basin sediments. Intermediate-bound DPGE concentrations exhibited an inverse relationship to unbound DPGE concentrations. Kerogen-bound DPGE concentrations were normally below detection limits. Earlier studies describing the general homogeneity of lipid components within the overlying brine and at the brine/seawater interface suggest that the large-scale sedimentary DPGE variations observed in this study result from spatial and temporal variations in in situ production by methanogenic or extremely halophilic archaebacteria.     

THE IMPACT OF TSUNAMI ON THE COASTLINE OF JERVIS BAY,SOUTHEASTERN AUSTRALIA

The Jervis Bay area offers a diversity of landforms that do not fit within contemporary views of coastal evolution. Field evidence indicates that catastrophic tsunami have had a significant impact on the coast and its hinterland both within and outside the embayment. Runup has overtopped cliffs 80 m above sea level and deposited chevron-shaped ridges to elevations of 130 m on the southern headland. Boulders, up to 6 m in diameter, have been deposited in an imbricated fashion against cliffs, on clifftops, and along shoreline ramps. Bed-form features and the size of transported material indicate flow depths up to 10 m and velocities around 8 m s^-1. While significant Pleistocene material has been swept onto the coastline, mainly in the form of barriers, radiocarbon dating indicates that tsunami have occurred repetitively throughout the Holocene. The most recent event occurred just before European settlement over 200 years ago. [Key words: barrier beaches, coastal geomorphology, tsunami, Jervis Bay, Australia.]