S-wave Velocity Models in the Scotia Sea Region, Antarctica, from Nonlinear Inversion of Rayleigh Waves Dispersion

—More than 60 events recorded by four recently deployed seismic broadband stations around Scotia Sea, Antarctica, have been collected and processed to obtain a general overview of the crust and upper mantle seismic velocities.¶Group velocity of the fundamental mode of Rayleigh waves in the period between 10 s to 30–40 s is used to obtain the S-wave velocity versus depth along ten different paths crossing the Scotia Sea region. Data recorded by two IRIS (Incorporated Research Institutions for Seismology) stations (PMSA, EFI) and the two stations of the OGS-IAA (Osservatorio Geofisico Sperimentale—Instituto Antarctico Argentino) network (ESPZ, USHU) are used.¶The Frequency-Time Analysis (FTAN) technique is applied to the data set to measure the dispersion properties. A nonlinear inversion procedure, "Hedgehog," is performed to retrieve the S-wave velocity models consistent with the dispersion data.¶The average Moho depth variation on a section North to South is consistent with the topography, geological observations and Scotia Sea tectonic models.¶North Scotia Ridge and South Scotia Ridge models are characterised by similar S-wave velocities ranging between 2.0 km/s at the surface to 3.2 km/s to depths of 8 km/s. In the lower crust the S-wave velocity increases slowly to reach a value of 3.8 km/s. The average Moho depth is estimated between 17 km to 20 km and 16 km to 19 km, respectively, for the North Scotia Ridge and South Scotia Ridge, while the Scotia Sea, bounded by the two ridges, has a faster and thinner crust, with an average Moho depth between 9 km and 12 km.¶On other paths crossing from east to west the southern part of the Scotia plate and the Antarctic plate south of South Scotia Ridge, we observe an average Moho depth between 14 km and 18 km and a very fast upper crust, compared to that of the ridge. The S-wave velocity ranges between 3.0 and 3.6 km/s in the thin (9–13 km) and fast crust of the Drake Passage channel. In contrast the models for the tip of the Antarctic Peninsula consist of two layers with a large velocity gradient (2.3–3.0 km/s) in the upper crust (6-km thick) and a small velocity gradient (3.0–4.0) in the lower crust (14-km thick).     

A methodology to estimate renewal time scales in estuaries: the Tagus Estuary case

High-resolution hydrodynamic models are a common tool to simulate water dynamics in estuaries. Results from these models are, however, difficult to interpret without the aid of additional parameters to integrate the information. In this paper a methodology to understand the transport patterns in the Tagus Estuary is proposed. It is based on the computation of two renewal time scales: residence time and integrated water fraction. This last parameter is used to build a dependency matrix that gives the integrated influence of each region of the estuary at a selected point. The parameters are computed using a Lagrangian transport model coupled to the hydrodynamic model. Results show that Tagus Estuary has two different types of regions: the central part of the estuary, with low renewal efficiency, and three regions with higher renewal efficiency. Renewal mechanisms are, however, different for each region as shown by the dependency matrix. Comparison of renewal time scales with results from a water-quality model revealed that residence time is not a limiting parameter for primary production in the Tagus Estuary.Responsible Editor: Hans Burchard     

Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais,Brazil

Eight samples of the beryl variety aquamarine were selected from four pegmatites in the Governador Valadares and Araçuaí regions in northeastern Minas Gerais State, Brazil. These samples were fully characterized by chemical analysis, infrared and UV-visible spectroscopy, thermal analyses, and high-temperature X-ray diffraction (from room temperature up to 800 °C). Several physical and chemical properties of beryl were found to depend on the amount of water and ions residing in the structural channels. The thermal expansion coefficients from room temperature to about 800 °C are temperature-independent, with αa ? ?3.2 × 10^?6 ° C^?1 and αc ? ?8.7 × 10^?6 ° C^?1. The contraction of both a and c unit-cell parameters with increasing temperature and the shift of the infrared band centered at about 1200 cm^?1 were tentatively ascribed to interactions between channel water and the silicate rings.The color of beryl seems to be dictated by the relative proportions of Fe³⁺ in the octahedralsites and of fe²⁺ in the channels. Thus, deep-blue samples have little Fe³⁺, whereas greener samples have more Fe³⁺ or less channel Fe²⁺.     

Total and methylmercury in a Brazilian estuary,Rio de Janeiro

Guanabara Bay, in Rio de Janeiro state, is impacted by organic matter, oil and heavy metals. The present study evaluated the total mercury (THg) and methylmercury (MeHg) concentrations and the MeHg to THg ratio (%MeHg) in water samples from different points of the bay and in 245 organisms of three different trophic levels sampled between 1990 and 2000. Dissolved mercury concentration in estuarine water samples ranged from 0.72 to 5.23 ngl(-1). THg and MeHg in mussel, ranging from 11.6 to 53.5 microg THg kg(-1) wet wt. and 4.5-21.0 microg MeHg kg(-1) wet wt., varied according to sampling point and water quality. Planktivorous fish and mussel presented similar MeHg concentrations, meanwhile THg in planktivorous fish were lower than in mussel. Carnivorous fish showed higher THg and MeHg concentrations (199.5 +/- 119.3, 194.7 +/- 112.7 microg kg(-1) wet wt. respectively) than organisms from other feeding habits and lower trophic levels. There was a significant difference in the %MeHg among trophic levels: mussel presented lower MeHg percentage (33%) than planktivorous fish (54%) and carnivorous fish (98%).     

"三联式"资源定量预测与评价--数字找矿理论与实践探讨

随着信息技术的发展,矿产勘查已步入数字化,定量化研究的新阶段。“三联式”成矿预测及资源评价途径正是“数字找矿”的创新探索。“三联式”成矿预测以地质异常分析为基础,以成矿多样性分析与矿床谱系研究为指导,将地质异常,成矿多样性及矿床谱系三方面定量化研究紧密结合形成矿产预测及定量评价的有机切入点,是实现全面数字找矿的必由之路,也是矿产勘查评价领域应用信息技术的基础和前提。     

Sediment contamination in floodplains and alluvial terraces as an historical record of gold exploitation in the Carmo River basin,Southeast Quadrilátero Ferrífero,Minas Gerais,Brazil

This paper describes the geochemistry of sediment samples placed in floodplains and alluvial terraces downstream from gold mines in the Carmo River basin, Quadrilátero Ferrífero, Minas Gerais, Brazil. The geochemistry signature Na₂O, K₂O, SiO₂, CaO, MgO, Al₂O₃, Fe₂O₃, TiO₂, P₂O₅, Mn, As, Cu, Zn, Ba, Ni, Cr, S, Co were analyzed in different facies from stratigraphic profiles. As, Cu, Zn, and Mn anomalies are mainly associated with the clayed facies deposited in floodplains and oxbow lakes, and with coarse‐sediment facies deposited in the channel. The facies were accumulated by the gold exploitation activity in the region. The contamination of As, Cu, and Zn was controlled by minerals such as iron oxides and hydroxides (hematite, magnetite, and mainly goethite), manganese oxides, and sulfide‐rich minerals. The As‐bearing sediments of the region characterize one of the most As contaminated area of Brazil. Their main source is associated with gold exploration in the last three centuries.     

Observational study of the seasonality of the submonthly and intraseasonal signal over the tropics

Summary Atmospheric variability in outgoing long-wave radiation (OLR) and tropospheric relative vorticity (VOR) over the South American region was studied from 1979 to 1996 using the complex Morlet wavelet function. The analyses focus on spatial variation in intraseasonal and submonthly scales. Scalograms were used to measure submonthly intraseasonal oscillations in convection, which were found to be predominant in the tropical regions. However, 7-day and 15-day oscillations were observed at tropical and extratropical latitudes in spring and winter, indicating that transient disturbances play a more prominent role. Regarding VOR, tropical energy intensities were highest in the spring and summer, whereas subtropical and extratropical energy intensities were highest in the autumn and winter. The dynamics of the 25-day and 45-day VOR oscillations indicates a possible correlation with Rossby waves over the eastern tropical Pacific Ocean, mainly during the summer. During winter, the 7-day and 15-day VOR oscillations are more frequent at higher latitudes and are enhanced along storm tracks. It was also observed that convection amplitudes in the regions of maximum intensity change appreciably from year to year and from season to season, showing that the behavior of the submonthly and intraseasonal oscillations is nonperiodic and correlates strongly with El Ni?o/Southern Oscillation years. These results confirm the efficiency of wavelet analysis for time-scale studies of atmospheric variability.     

Occurrence and Resistance of Pathogenic Bacteria Along the Tietê River Downstream of São Paulo in Brazil

The load of pathogenic bacteria, their fate and their dangerousness in the Tietê River were assessed along 100 km starting from the city of São Paulo, Brazil. The data were compared with those from two German rivers. High loads of pathogens were found in the Tietê River near the city of São Paulo (Escherichia coli O157:H7, Shigella flexneri, and Shigella boydii), which were absent 30 km downstream of São Paulo. The antibiotic resistances observed in the Tietê river were rather low and decreased after the major input in São Paulo to significantly lower levels about 30 km downstream. While the Brazilian isolates were more susceptible for ampicillin than the German ones, the reverse was observed for gentamycin. For optimal control of infections in humans critical areas where these bacteria survived longer and their elimination mechanisms should be identified as well as the extent and the origin of antibiotic resistance should be determined.     

Non-Linear Gravitational Clustering Using the Zel'dovich Approximation

As an alternative to computationally expensive N-body simulations for gravitional clustering, the Zel'dovich approximation (ZA) was studied in 3D, 2D and 1D. Plots of the density contrast were compared against linear theory and the exact solution. The ZA was found to perform very well in the linear regime, better than linear theory, and to give a good approximation well into the non-linear regime. This revised version was published online in July 2006 with corrections to the Cover Date.