Carbonatites from Eastern Paraguay and genetic relationships with potassic magmatism: C, O, Sr and Nd Isotopes

Summary Geochemical characteristics were systematically determined for Early Cretaceous samples of carbonatitic rocks from Eastern Paraguay (Rio Apa, Amambay and Central Provinces). The data show that all the occurrences have an enriched isotopic signature and that the carbonatites have negligible or absent crustal signature. A petrogenetic model (parent liquids, fractional crystallization, hydrothermal interactions and weathering) is proposed as a function of incompatible trace element, stable (O-C) and radiogenic (Sr-Nd) isotope variations with the aim to test the significance of carbonatitic complexes as a marker of the metasomatized subcontinental lithospheric mantle. The results indicate that the carbonatites and primary carbonates from eastern Paraguay, and those from the north eastern Paraná Basin (SE Brazil), were affected by metasomatic events distinct in time and composition.

---

Karbonatite aus Ost-Paraguay und ihre genetische Beziehung zu Kalium-Magmatismus: C O, Sr und Nd isotope

Zusammenfassung Die geochemischen Charakteristika von frühkretazischen Karbonatitproben aus Ostparaguay (Rio Alpa, Amambay und Zentrale Provinzen) wurden untersucht. Die Daten belegen, daß alle Vorkommen eine isotopische Anreicherungssignatur zeigen und daß ihnen eine entsprechende Krustensignatur fehlt. Ein Petrologisches Modell (Ausgangsschmelze, fraktionierte Kristallisation, hydrothermale Interaktion und Verwitterung) wird auf Grund der Verteilung der inkompatiblen Spurenelemente, der stabilen (C-O) und radiogenen (Sr-Nd) Isotope vorgeschlagen. Es versucht die Bedeutung der Karbonatitkomplexe als Markerhorizonte des metasomatischen subkontinentalen Mantels zu überprüfen. Die Ergebnisse zeigen, daß die Karbonatite und die primären Karbonate in Ostparaguay, und jene aus dem Paraná Becken SüdostBrasiliens durch zeitlich und zusammensetzungsmäßig unterschiedliche metasomatische Prozesse erfaßt wurden.

---

---

With 10 Figures     

Tunneling and interference of Alfvén waves

The propagation and interference of Alfvén waves in magnetic regions is studied. A multilayer approximation of the standard models of the solar atmosphere is used. In each layer, there is a linear law of temperature variation and a power law of Alfvén velocity variation. The analytical solutions of a wave equation are stitched at the layer boundaries. The low-frequency Alfvén waves (P > 1 s) are able to transfer the energy from sunspots into the corona by tunneling only. The chromosphere is not a resonance filter for the Alfvén waves. The interference and resonance of Alfvén waves are found to be important to wave propagation through the magnetic coronal arches. The transmission coefficient of Alfvén waves into the corona increases sharply on the resonance frequences. To take into account the wave absorption in the corona, a method of equivalent schemes is developed. The heating of a coronal arch by Alfvén waves is discussed.     

Rb/Sr dating of the Upper Proterozoic basement of Zambesia,Mozambique

The Proterozoic basement of the Province of Zambezia (Mozambique) is located near the southern end of the so called Mozambique Belt. Rb-Sr data derived from the analyses of 66 whole rocks and a few mineral samples bear witness of a magmatic and metamorphic episode referable to the Kibaran (ca. 1000 Ma) and helped to model the late-Proterozoic evolution as follows. At 1100–1050 Ma a pre-orogenic, calc-alkaline magmatism was responsible for the emplacement of now deformed granite and granodiorite. This phase was accompanied by rhyolitic volcanism. A subsequent peak of deformation and metamorphism occurred at 1000-950 Ma and was associated with a second generation of substantially post-tectonic granites. A thermal event resulting in the emplacement of a final generation of granites and pegmatites can be dated to around 500-450 Ma.The metamorphic basement has not preserved its protolith age, probably as a result of extensive isotopic homogeneization of Sr in Kibaran times. Its maximum time of differentiation from the mantle should be around 1600 Ma.The very low values of initial Sr isotopic ratios suggest the absence of Archean crustal precursors and support the rather young, yet pre-Pan-African evolution of the southernmost Mozambique Belt.

---

Zusammenfassung Das proterozoische Grundgebirge der Provinz Zambesi (Mosambique) befindet sich in der Nähe des südlichen Endes des sogenannten Mozambique Belt. Rb/Sr Daten aus 66 Ganzgesteins- und einigen Mineralanalysen zeugen von einer magmatischen und metamorphen Episode die sich dem Kibaran (ca. 1000 Ma) zuordnen läßt, und wie sich im folgenden zeigt, hilfreich bei der Modellisierung der spätproterozoischen Entwicklung ist. Um 1100 bis 1050 Ma erfolgte ein präorogener kalkalkalischer Magmatismus, bestehend aus Graniten und Granodioriten, die heute deformiert vorliegen. Diese Phase wurde von rhyolithischem Vulkanismus begleitet. Von 1000 bis 950 Ma folgte der Höhepunkt der Deformation und Metamorphose, begleitet von einer bedeutenden 2. Generation posttektonischer Granite. Bedingt durch ein weiteres thermales Ereignis intrudierte die letzte Granit- und Pegmatitgeneration vor 500 bis 450 Ma.Im metamorphen Grundgebirge ist das Eduktalter vermutlich aufgrund der starken isotopischen Homogenisierung von Sr während der Kibara-Zeit nicht erhalten. Seine maximale Differentiationszeit vom Mantel muß vor 1600 Ma gewesen sein.Die sehr niedrigen Gehalte der initialen Sr-Isotopenverhältnisse lassen die Abwesenheit von archaischen Krustenvorläufern vermuten, und unterstützen die sehr junge, bis jetzt Prä-Pan-Afrikanische Entwicklung des südlichsten Mozambique Belts.

---

Résumé Le socle protérozoïque de la province du Zambèze, au Mozambique, se trouve à proximité de l'extrémité sud du «Mozambique Belt». Des mesures Rb/Sr effectuées sur 66 roches totales et sur quelques minéraux témoignent d'un épisode magmatique et métamorphique attribuable au Kibarien (environ 1.000 Ma), ce qui permet de se représenter comme suit l'histoire de cette région au Protérozoïque supérieur. Il y a 1.100 à 1.050 Ma, la région a connu une phase de magmatisme calco-alcalin qui s'est traduite par la mise en place de granites et granodiorites, aujord'hui déformés. Cette phase s'est accompagnée d'un volcanisme rhyolitique. Elle a été suivie, entre 1.000 et 950 Ma, d'une activité tectono-métamorphique majeure, à laquelle est associée une deuxième et importante génération de granites, post-tectoniques. Ultérieurement, la région a connu encore un épisode thermique, daté à 500-450 Ma, responsable de la mise en place d'une dernière génération de granite et de pegmatite.Le socle métamorphique n'a pas gardé de témoins de l'âge de son protolithe, en raison probablement de la forte homogénisation isotopique du Sr à l'époque kibarienne. Lâge maximal de sa différenciation à partir du manteau doit se situer autour de 1.600 Ma.La valeur très basse des rapports isotopiques initiaux du Sr suggère l'absence de précurseurs crustaux archéens et incite à admettre une évolution relativement jeune — bien que pré-panafricaine — du «Mozambique Belt» méridional.

---

() .. . , Rb/Sr 66 , , Kibara, 1000 , , , . 1100 1050 - - , , . . 1000 950 , - . , 500 450 . , , , Kibara. , , 1600 my . - .

     

A new model for X-ray emission from NGC 4151

We present an analysis of the reported spectral features of NGC 4151 in X-rays. It is shown that the origin of X-rays from the source is inconsistent with a single production mechanism. We suggest a new two-component model in which soft X-rays arise from the black-body emission of a tiny hot nucleus withT2×10⁷ K and the hard X-ray photons are generated in an extended region by inverse Compton scattering of electrons with the infrared photons.     

Holocene record of productivity in the NW Iberian continental shelf

A multiproxy approach (textural characteristics, heavy metal concentrations and benthic foraminifera data) was adopted to study the OMEX core KSGX 40, collected at the Galicia Mud Deposit (NW Iberian outer continental shelf) and recording the last ca. 4.8 ka cal BP. Geochemical profiles of Fe, Mn, Zn, Co, Cr, Cu, Ni, Pb, Al and Ca show significant temporal variations. Benthic foraminifera productivity proxy suggests that the recorded muddy events were contemporaneous of a higher C_org flux to the marine benthic environment. The higher flux of organic matter, following a long-term intensification of the upwelling and coinciding with a finer sedimentation, led to depressed levels of oxygen beneath the water-sediments interface and to early diagenetic processes of several redox-sensitive elements.     

HP–LT Variscan metamorphism in the Cubito-Moura schists (Ossa-Morena Zone, southern Iberia)

Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S₁) in these rocks. The main foliation in the schists is a crenulation cleavage (S₂), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe³⁺ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S₁ chlorites down to 0.1 in syn-S₂ chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006).     

Zircon geochronology and Sm–Nd isotopic study: Further constraints for the Archean and Paleoproterozoic geodynamical evolution of the southeastern Guiana Shield, north of Amazonian Craton, Brazil

The eastern part of the Guiana Shield, northern Amazonian Craton, in South America, represents a large orogenic belt developed during the Transamazonian orogenic cycle (2.26–1.95 Ga), which consists of extensive areas of Paleoproterozoic crust and two major Archean terranes: the Imataca Block, in Venezuela, and the here defined Amapá Block, in the north of Brazil.

Pb-evaporation on zircon and Sm–Nd on whole rock dating were provided on magmatic and metamorphic units from southwestern Amapá Block, in the Jari Domain, defining its long-lived evolution, marked by several stages of crustal accretion and crustal reworking. Magmatic activity occurred mainly at the Meso-Neoarchean transition (2.80–2.79 Ga) and during the Neoarchean (2.66–2.60 Ga). The main period of crust formation occurred during a protracted episode at the end of Paleoarchean and along the whole Mesoarchean (3.26–2.83 Ga). Conversely, crustal reworking processes have dominated in Neoarchean times. During the Transamazonian orogenic cycle, the main geodynamic processes were related to reworking of older Archean crust, with minor juvenile accretion at about 2.3 Ga, during an early orogenic phase. Transamazonian magmatism consisted of syn- to late-orogenic granitic pulses, which were dated at 2.22 Ga, 2.18 Ga and 2.05–2.03 Ga. Most of the ε_Nd values and T_DM model ages (2.52–2.45 Ga) indicate an origin of the Paleoproterozoic granites by mixing of juvenile Paleoproterozoic magmas with Archean components.

The Archean Amapá Block is limited in at southwest by the Carecuru Domain, a granitoid-greenstone terrane that had a geodynamic evolution mainly during the Paleoproterozoic, related to the Transamazonian orogenic cycle. In this latter domain, a widespread calc-alkaline magmatism occurred at 2.19–2.18 Ga and at 2.15–2.14 Ga, and granitic magmatism was dated at 2.10 Ga. Crustal accretion was recognized at about 2.28 Ga, in agreement with the predominantly Rhyacian crust-forming pattern of the eastern Guiana Shield. Nevertheless, T_DM model ages (2.50–2.38 Ga), preferentially interpreted as mixed ages, and ε_Nd < 0, point to some participation of Archean components in the source of the Paleoproterozoic rocks. In addition, the Carecuru Domain contains an oval-shaped Archean granulitic nucleus, named Paru Domain. In this domain, Neoarchean magmatism at about 2.60 Ga was produced by reworking of Mesoarchean crust, as registered in the Amapá Block. Crustal accretion events and calc-alkaline magmatism are recognized at 2.32 Ga and at 2.15 Ga, respectively, as well as charnockitic magmatism at 2.07 Ga.

The lithological association and the available isotopic data registered in the Carecuru Domain suggests a geodynamic evolution model based on the development of a magmatic arc system during the Transamazonian orogenic cycle, which was accreted to the southwestern border of the Archean Amapá Block.     

The effect of thermal treatment on the 57Fe Mössbauer spectrum of beryl

Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be₃Al₂Si₆O₁₈) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe²⁺ doublet (ΔE _Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe³⁺ (ΔE _Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe²⁺ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites.     

Aerosol characterization and optical thickness retrievalsusing GOME and METEOSAT satellite data

Summary ?Retrievals of atmospheric aerosol optical thickness are highly dependent on the choice of the class describing the aerosol properties leading to significant errors while using classes available in the literature. High spectral resolution measurements from GOME (Global Ozone Monitoring Experiment) between the ultraviolet and the near infrared can be used for an accurate characterization of the aerosol optical properties. The radiometer MVIRI (METEOSAT Visible and Infrared Imager) on board the geostationary satellite METEOSAT, while being equipped only with broadband VIS channel, ensures an adequate half-hourly monitoring of the atmospheric conditions over a large portion of the Earth. The present algorithm is based on a combination of data from both sensors for the retrieval of the aerosol optical thickness at the reference wavelength of 0.55 μm (AOT). A case of a desert dust outbreak from the African continent over the Atlantic Ocean is examined. AOT values obtained using a priori fixed classes taken from the literature are compared with those retrieved with this algorithm using the GOME-derived classes. Systematic differences of the order of a few tenths on average are found which remain significant also after considering the measurement errors. This represents a novelty introduced by the synergetic use of both sensors. Received March 13, 2002