Modelling mechanical behaviour of limestone under reservoir conditions

High porosity and low permeability limestone has presented pore collapse. As fluid is withdrawn from these reservoirs, the effective stresses acting on the rock increase. If the strength of the rock is overcome, pore collapse may occur, leading to irreversible compaction of porous media with permeability and porosity reduction. It impacts on fluid withdrawal. Most of reservoirs have been discovered in weak formations, which are susceptible to this phenomenon. This work presents a study on the mechanical behaviour of a porous limestone from a reservoir located in Campos Basin, offshore Brazil. An experimental program was undergone in order to define its elastic plastic behaviour. The tests reproduced the loading path conditions expected in a reservoir under production. Parameters of the cap model were fitted to these tests and numerical simulations were run. The numerical simulations presented a good agreement with the experimental tests. Copyright © 2006 John Wiley & Sons, Ltd.     

K–Ar and Ar/Ar ages of dikes emplaced in the onshore basement of the Santos Basin, Resende area, SE Brazil: implications for the south Atlantic opening and Tertiary reactivation

New K–Ar and ⁴⁰Ar/³⁹Ar data of tholeiitic and alkaline dike swarms from the onshore basement of the Santos Basin (SE Brazil) reveal Mesozoic and Tertiary magmatic pulses. The tholeiitic rocks (basalt, dolerite, and microgabbro) display high TiO₂ contents (average 3.65 wt%) and comprise two magmatic groups. The NW-oriented samples of Group A have (La/Yb)_N ratios between 15 and 32.3 and range in age from 192.9±2.2 to 160.9±1.9 Ma. The NNW-NNE Group B samples, with (La/Yb)_N ratios between 7 and 16, range from 148.3±3 to 133.9±0.5 Ma. The alkaline rocks (syenite, trachyte, phonolite, alkaline basalts, and lamprophyre) display intermediate–K contents and comprise dikes, plugs, and stocks. Ages of approximately 82 Ma were obtained for the lamprophyre dikes, 70 Ma for the syenite plutons, and 64–59 Ma for felsic dikes. Because Jurassic–Early Cretaceous basic dikes have not been reported in SE Brazil, we might speculate that, during the emplacement of Group A dikes, extensional stresses were active in the region before the opening of the south Atlantic Ocean and coeval with the Karoo magmatism described in South Africa. Group B dikes yield ages compatible with those obtained for Serra Geral and Ponta Grossa magmatism in the Paraná Basin and are directly related to the breakup of western Gondwana. Alkaline magmatism is associated with several tectonic episodes that postdate the opening of the Atlantic Ocean and related to the upwelling of the Trindade plume and the generation of Tertiary basins southeast of Brazil. In the studied region, alkaline magmatism can be subdivided in two episodes: the first one represented by lamprophyre dykes of approximately 82 Ma and the second comprised of felsic alkaline stocks of approximately 70 Ma and associated dikes ranging from 64 to 59 Ma.

Resumo

Novos dados K–Ar e ⁴⁰Ar/³⁹Ar de enxames de diques toleíticos e alcalinos localizados no embasamento onshore da Bacia de Santos (SE Brasil) apontam para diferentes pulsos magmáticos ocorridos entre o Jurássico e o Terciário. Os diques de rochas toleíticas (basalto, diabásio e microgabro), são mais velhos, exibem altos teores de TiO₂ (3,65% peso na média) e podem ser subdivididos em dois grupos magmáticos. O Grupo A aflora a norte da Bacia de Resende, compreende diques orientados na direção NW, com razões (La/Yb)_N entre 15 e 32,3, e idades entre 192.9±2.2 e 160.9±1.9 Ma. O Grupo B aflora a sul e a leste da Bacia de Resende, engloba diques orientados na direção NNW e NNE, com razões (La/Yb)_N entre 7 e 16, e idades obtidas entre 148.3±3 e 133.9±0.5 Ma. As rochas alcalinas (sienito, traquito, fonolito, basalto alcalino e lamprófiro) possuem teores médios de K, e afloram como diques, plugs e stocks.. As idades obtidas são de ca. 82 Ma para os diques lamprofíricos, de ca. 70 Ma para os plugs sieníticos, e entre 64 e 59 Ma para os diques félsicos. Como estas idades Jurássicas para diques toleíticos ainda não foram descritas para a região sudeste do Brasil, pode-se especular que durante o emplacement dos diques do GrupoA o cenário tectônico indicaria esforços extensionais anteriores à abertura do Oceano atlântico Sul, e contemporânea ao derrame basáltico do Karoo na África do Sul. Já os diques do Grupo B são contemporâneos ao magmatismo Serra Geral e ao enxame de diques de Ponta Grossa, e portanto este episódio está diretamente relacionado à separação entre o Brasil e África no Cretáceo. O magmatismo alcalino está associado a diversos episódios tectônicos que sucedem à abertura do Oceano Atlântico Sul e que resultaram no desenvolvimento das Bacias terciárias do sudeste brasileiro. Está provavelmente relacionado à chegada da Pluma de Trindade e as idades obtidas para a região em estudo indicam que o magmatismo lamprofírico é mais antigo (ca. 82 Ma), seguido pelos plútons sieníticos (ca. 70 Ma) e diques associados (64 a 59 Ma.)     

Positive solution of two-dimensional solute transport in heterogeneous aquifers

The transport of contaminants in aquifers is usually represented by a convection-dispersion equation. There are several well-known problems of oscillation and artificial dispersion that affect the numerical solution of this equation. For example, several studies have shown that standard treatment of the cross-dispersion terms always leads to a negative concentration. It is also well known that the numerical solution of the convective term is affected by spurious oscillations or substantial numerical dispersion. These difficulties are especially significant for solute transport in nonuniform flow in heterogeneous aquifers. For the case of coupled reactive-transport models, even small negative concentration values can become amplified through nonlinear reaction source/sink terms and thus result in physically erroneous and unstable results. This paper includes a brief discussion about how nonpositive concentrations arise from numerical solution of the convection and cross-dispersion terms. We demonstrate the effectiveness of directional splitting with one-dimensional flux limiters for the convection term. Also, a new numerical scheme for the dispersion term that preserves positivity is presented. The results of the proposed convection scheme and the solution given by the new method to compute dispersion are compared with standard numerical methods as used in MT3DMS.     

Ideal width of transects for monitoring source-related categories of plastics on beaches

Although there is a consensus on the necessity of monitoring solid wastes pollution on beaches, the methods applied vary widely. Therefore, creating, testing and recommending a method that not only allows comparisons of places and periods, but also the detection of source signals, will be important to reach the objectives of the source-prevention principle. This will also allow the optimisation of time, resources, and processing of samples and data. A classification of the items found into specific categories was made according to their most probable source/use (fisheries, food packaging, hazardous, sewage/personal hygiene, beach user, general home). This study tested different widths of sampling transects to be used in the detection of plastics contamination on beaches, until all the categories were significantly represented. Each transect had its total width (50m) sub-divided into eight intervals of 0-2.5m; 2.5-5m; 5-10m; 10-15m; 15-20m; 20-30m; 30-40m; and 40-50m. The accumulated number of categories in the 50m (up to 2.5m; up to 5m and so on) was used to determine the minimal width necessary to qualitatively characterize the area regarding plastics contamination. The diversity of the categories was directly related to the area of the sampling transect. These results indicate that a significant increase in the number of categories in the first intervals tend to stabilize from 15-20m onwards.     

The use of the marine biotic index AMBI in the assessment of the ecological status of the Obidos lagoon (Portugal)

This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.     

Foraminiferal responses to polluted sediments in the Montevideo coastal zone, Uruguay

A study of foraminiferal assemblages was carried out in 24 sediment samples collected from the Montevideo coastal zone (south-eastern coastal region of South America) to assess the response of the benthic foraminifera to the polluted sediments. The area is affected by different pollutants such as sewage, hydrocarbons and heavy metals derived from different sources. Biological data were analyzed with multivariate techniques of cluster analysis and a principal component analysis (PCA) was performed for abiotic factors. The results allowed the recognition of different species assemblages corresponding to different sub-environments, which reflected the prevalent ecological conditions. The Montevideo Bay, particularly, its inner part showed an extremely poor foraminiferal fauna-including a totally azoic station-and high percentages of abnormal tests, when compared with the adjacent Punta Carretas and Punta Yeguas zones. Mean faunal density showed a strong relationship with organic matter, oxygen and heavy metal concentrations, as well as redox potential and pH values of each sub-environment. Although the adjacent zones presented a moderate pollution degree, it was noticed that a positive effect on the foraminiferal density specially on Ammonia tepida, caused by the sewage pipe located in Punta Carretas, a pure organic contamination. Differences among foraminiferal assemblages seemed to be related to the combined action of the several kinds of pollutants and the natural abiotic variables, like the rapid salinity changes that occurred in this area.     

An exotic Cretaceous kimberlite linked to metasomatized lithospheric mantle beneath the southwestern margin of the Francisco Craton,Brazil

We present major and trace element compositions of mineral concentrates comprising garnet xenocrysts,ilmenite,phlogopite,spinel,zircon,and uncommon minerals (ti...     

Coral reef ecosystems protect shore from high-energy waves under climate change scenarios

Coral reefs and other coastal ecosystems such as seagrasses and mangroves are widely recognized to provide protection against the devastating effects of strong waves associated with tsunamis and storms. The predicted warming climate brings to fore the role of these ecosystems in providing protection against stronger typhoons that can result in more devastating waves of greater amplitude. We performed a model simulation of storm generated waves on a Philippine reef, which is located along the path of tropical storms, i.e., at least 10 typhoons on the average pass through the study site yearly. A model to simulate wave propagation was developed using Simulating Waves Nearshore (SWAN) and DELFT3D-WAVE computer simulation software. Scenarios involving local monsoonal wind forcing and storm conditions were simulated. In addition, as climate change may also result to increased relative sea level, a 0.3 m and 1 m rise in sea level scenarios were also used in the wave model simulations. Results showed that the extensive reef system in the site helped dissipate wave energy that in turn reduced wave run-up on land. A significant reduction in wave energy was observed in both climate change, i.e., stronger wind and higher sea level, and non-climate change scenarios. This present study was conducted in a reef whose coral cover is in excellent condition (i.e., 50 to 80% coral cover). Estimates of coral reef growth are in the same order of magnitude as estimates of relative sea level rise based on tide gauge and satellite altimeter data, thus it is possible that the role of reefs in attenuating wave energy may be maintained if coral reef growth can keep up with the change in sea level. Nonetheless, to maintain reef growth, it is imperative to manage coral reef ecosystems sustainably and to eliminate the stressors that are within human control. Minimizing activities such as illegal and destructive blast and poison fishing methods, pollution and siltation, is crucial to minimize the impacts of high-energy waves that may increase with climate change.     

An upgraded version of the Eta model

Upgrades implemented over a number of years in an open source version of the Eta model, posted at the CPTEC web site http://etamodel.cptec.inpe.br/, are summarized and examples of benefits are shown. The version originates from the NCEP’s Workstation Eta code posted on the NCEP web site http://www.emc.ncep.noaa.gov/mmb/wrkstn_eta, which differs from the NCEP’s latest operational Eta by having the WRF-NMM nonhydrostatic option included. Most of the upgrades made resulted from attention paid to less than satisfactory performance noted in several Eta results, and identification of the reasons for the problem. Others came from simple expectation that including a feature that is physically justified but is missing in the code should help. The most notable of the upgrades are the introduction of the so-called sloping steps, or discretized shaved cells topography; piecewise-linear finite-volume vertical advection of dynamic variables; vapor and hydrometeor loading in the hydrostatic equation, and changes aimed at refining the convection schemes available in the Eta. Several other modifications have to do with the calculation of exchange coefficients, conservation in the vertical diffusion, and diagnostic calculation of 10-m winds. Several examples showing improved performance resulting from the dynamics changes are given. One includes a case of unrealistically low temperatures in several mountain basins generated by a centered vertical advection difference scheme’s unphysical advection from below ground, removed by its replacement with a finite-volume scheme. Another is that of increased katabatic winds in the Terra Nova Bay Antarctica region. Successful forecast of the severe downslope zonda wind case in the lee of the highest peaks of the Andes is also shown, and some of the recent successful verification results of the use of the upgraded model are pointed out. The code is used at numerous places, and along with setup information it is available for outside users at the CPTEC Eta web site given above.     

Extreme climatic events in the Amazon basin

During 2009 the Amazon basin was hit by a heavy flooding with a magnitude and duration few times observed in several decades. Torrential rain in northern and eastern Amazonia during the austral summer of 2008–2009 swelled the Amazon River and its tributaries. By July 2009, water levels of the Rio Negro, a major Amazon tributary, reached at Manaus harbor a new record, the highest mark of the last 107?years. During the 2008–2009 hydrological year, the rainy season on northern and northwestern Amazonia started prematurely, and was followed by a longer-than-normal rainy season. An anomalously southward migration of the ITCZ during May–June 2009, due to the warmer than normal surface waters in the tropical South Atlantic, was responsible for abundant rainfall in large regions of eastern Amazonia and Northeast Brazil from May to July 2009. We also compared the flood of 2009 with other major events recorded in 1989 and 1999. The hydrological consequences of this pattern were earlier than normal floods in Amazon northern tributaries, which peak discharges at their confluences with the main stem almost coincided with the peaks of southern tributaries. Since the time displacement of the contribution to the main stem of northern and southern Amazon tributaries is fundamental for damping flood waves in the main stem, the simultaneous combinations of peak discharges of tributaries resulted in an extreme flood.