Tracer diffusion of some alkali,alkaline-earth and transition element ions in a basaltic and an andesitic melt,and the implications concerning melt structure

The diffusion properties of Na, Cs, Sr, Ba, Co, Mn, Fe and Sc ions in a basaltic and an andesitic melt have been determined experimentally using the radiotracer residual-activity method, and narrow platinum capillaries, over the temperature range 1,300–1,400° C. Diffusion of all cations follows an Arrhenius relationship; the values of the activation energies range from 24 kcal mol^–1 for Na to 67 kcal mol^–1 for Co in the andesitic melt, and from 39 kcal mol^–1 for Na to 65 kcal mol^–1 for Cs in the basaltic melt. Relative diffusivities in the basaltic melt, but not in the andesitic melt, correlate with assumed ionic radii values. Each cation, except Na⁺, diffuses faster in the basaltic melt than in the andesitic melt over the studied temperature range. Sodium shows similar diffusivity in the two melts.Compensation diagrams incorporating new and some previously-published data indicate that Cs probably diffuses by different mechanisms in different silicate glass and melt systems. Iron has a relatively high activation energy which is consistent with its part occupancy of tetrahedral co-ordination polyhedra.     

Sinks of iron and manganese in underground coal mine workings

The sources and sinks of manganese in underground coal mine workings are poorly understood compared to those of iron. The geochemical system in the secondary egress drift of Caphouse Colliery near Horbury, UK, is an ideal system for studying these processes. Five locations along the drift and four secondary inflows to the drift were sampled 24 times through the year commencing May 2005. During the sampling period, the pH in the main channel varied from 6.73 to 7.93 and increased along the flow path. The secondary inflows to the drift from the strata were of higher alkalinity (mean = 385 mg/L as CaCO₃) than the main flow (mean = 330 mg/L as CaCO₃); the affects of mixing between the less alkaline main channel and the more alkaline secondary inflows and of carbon dioxide exsolution are evident in the form of carbonate and hydroxide precipitates. SEM and XRD analysis of precipitates collected from the drift confirm the presence of calcium and manganese carbonates and ferric hydroxide. PHREEQC speciation and solubility modelling confirms supersaturation of the water in the main channel with respect to ferric oxy-hydroxides; iron, manganese, magnesium and calcium carbonates; and manganese oxides. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Numerical aspects of time elements

Numerical results have shown that the use of time elements with time transformations provides increased accuracy in the numerical solution of gravitational systems.To gain additional accuracy improvements, it appears that the time and the time element should be calculated from quantities that have been adjusted so as to satisfy the energy integral exactly.We also have found that by reducing the growth of the time element to being nearly linear rather than quadratic causes an increase in the magnitude of the local truncation error in the solution but with a decrease in the rate of growth of the truncation error.     

Sea ice algae in the White and Barents seas: composition and origin

To examine algae populations, three expeditions (in March 2001, April 2002 and February 2003) were conducted in the Guba Chupa (Chupa Estuary; north-western White Sea), and one cruise was carried out in the open part of the White Sea in April 2003 and in the northern part of the Barents Sea in July 2001. Sea ice algae and phytoplankton composition and abundance and the content of sediment traps under the land-fast ice in the White Sea and annual and multi-year pack ice in the Barents Sea were investigated. The community in land-fast sea ice was dominated by pennate diatoms and its composition was more closely related to that of the underlying sediments than was the community of the pack ice, which was dominated by flagellates, dinoflagellates and centric diatoms. Algae were far more abundant in land-fast ice: motile benthic and ice-benthic species found favourable conditions in the ice. The pack ice community was more closely related to that of the surrounding water. It originated from plankton incorporation during sea ice formation and during seawater flood events. An additional source for ice colonization may be multi-year ice. Algae may be released from the ice during brine drainage or sea ice melting. Many sea ice algae developed spores before the ice melt. These algae were observed in the above-bottom sediment traps all year around. Three possible fates of ice algae can be distinguished: 1) suspension in the water column, 2) sinking to the bottom and 3) ingestion by herbivores in the ice, at the ice-water interface or in the water column.     

Performance of the Nuclear Compton Telescope

On 1 June 2005, the prototype Nuclear Compton Telescope (NCT) flew on a high altitude balloon from Fort Sumner, New Mexico. NCT is a balloon-borne soft γ-ray (0.2–10 MeV) telescope for studying astrophysical sources of nuclear line emission and γ-ray polarization. Our program is designed to develop and test technologies and analysis techniques crucial for the Advanced Compton Telescope; however, our detector design and configuration is also well matched to the focal plane requirements for focusing Laue lenses. The NCT prototype utilizes two, 3D imaging germanium detectors (GeDs) in a novel, ultra-compact design optimized for nuclear line emission in the 0.5–2 MeV range. Our prototype flight provides a critical test of the novel detector technologies, analysis techniques, and background rejection procedures developed for high resolution Compton telescopes.     

Observations of cosmic gamma-ray bursts with the main detector of the SIGMA telescope onboard the Granat Observatory

We present the observations of cosmic gamma-ray bursts (GRBs) with the main detector of the SIGMA telescope onboard the Granat Observatory from January 1990 through September 1994. The observations were carried out in the energy range 35–1300 keV. We detected 36 GRBs and 31 high-energy solar flares during this period. No GRB fell within the main field of view; they were all recorded by the “secondary optics” of the telescope. The SIGMA telescope recorded relatively bright bursts with peak fluxes of 10^?6–10^?4 erg s^?1 cm^?2 in the 100–500-keV energy band. Stable detector background allows the long-term variability of GRB sources on a time scale of ～1000 s to be studied. The results of our search for early afterglows of GRBs are presented. The flux averaged over all bursts in the interval 100–800 s after the main event is 0.36±0.14 counts s^?(35–300 keV), suggesting that there is soft gamma-ray emission on this time scale after a considerable number of GRBs.     

Comparison of Ocean Surface Wind Stress Computed with Different Parameterization Functions of the Drag Coefficient

Depending on the choice of reference wind speed, the quantitative and qualitative properties of the drag coefficient may vary. On the ocean surface, surface waves are the physical roughness at the air-sea interface, and they play an important role in controlling the air-sea exchange processes. The degree of dynamic influence of surface waves scales with wavelength. Drag coefficient computed with the reference wind speed at an elevation proportional to the wavelength (for example, U _λ/2) is fundamentally different from the drag coefficient computed with the wind speed at fixed 10 m elevation (U ₁₀). A comparison has been carried out to quantify the difference in wind stress computation using several different parameterization functions of the drag coefficient. The result indicates that the wind stress computed from U ₁₀ input using a drag coefficient referenced to U _λ/2 is more accurate than that computed with drag coefficient functions referenced to U ₁₀.     

Radar facies of paraglacial barrier systems: coastal New England, USA

Analysis of a large data base of ground-penetrating-radar (GPR) profiles from both natural and developed paraglacial barriers along the coast of New England has allowed identification of eight reflection configurations that characterize this type of mid- to high-latitude coastal environment. Bedrock anchor points yield primarily hyperbolic configurations, whereas glacial anchor points and sediment-source areas are characterized by chaotic, parallel, and tangential-oblique configurations. Beaches and dunes produce predominantly sigmoidal oblique, hummocky, reflection-free, and bounding-surface configurations. Back-barrier sediments may yield basin-fill configurations, but generally include abundant signal-attenuating units.
The GPR data, calibrated with information from cores, were collected across swash-aligned and drift-aligned barriers in a variety of wave- and tidal-energy settings. Application of a 120-MHz antenna, as used in this study, enables portrayal of a range of sedimentary units, from individual bedforms (on single records) to entire barrier elements (using large numbers of intersecting GPR sections), at maximum vertical resolutions that vary between 0·2 m and 0·7 m.
The most important drawback of GPR in the coastal environment is attenuation of the electromagnetic (EM) signal by layers of salt-marsh peat or by brackish or salty groundwater, primarily along barrier edges. This disadvantage is offset by many benefits. Data can be collected at rates of several km per day, making GPR an excellent reconnaissance tool. A core that is used in the calibration of GPR data can be matched with great accuracy to its position on the complementary GPR record, allowing detailed correlation between lithostratigraphy and reflection configuration.     

Polycyclic musks in green-lipped mussels (Perna viridis) from Hong Kong

Six polycyclic musk compounds [Cashmeran (DPMI), Celestolide (ADBI), Phantolide (AHMI), Traseolide (ATII), Tonalide (AHTN), and Galaxolide (HHCB)] were analysed in marine green-lipped mussels (Perna viridis) from Hong Kong. ADBI, HHCB and AHTN were detected in almost all samples, while AHMI, ATII and DPMI were not detected. Concentrations of ADBI, HHCB and AHTN in mussels ranged from below detection limit-0.0743 (mean: 0.0246), 0.247-6.08 (mean: 1.15) and 0.0591-0.738 (mean: 0.190)mg/kg lipid weight, respectively. Mussels from two sampling sites in central Victoria Harbour contained the highest total polycyclic musk levels, suggesting that these waters are heavily influenced by domestic sewage. Concentrations of HHCB and AHTN detected in the mussel samples were the second highest and the highest levels, respectively, compared to global concentrations. A preliminary risk assessment indicated that HHCB and AHTN in mussels pose little or no threat to the health of shellfish consumers. Nevertheless, more comprehensive studies are required to further assess the ecological and human health risks associated with polycyclic musks.