Neogene-Quaternary tectonic evolution of the Leeward Antilles islands (Aruba, Bonaire, Curaçao) from fault kinematic analysis

Aruba, Bonaire, and Curaçao are islands aligned along the crest of a 200-km-long segment of the east-west-trending Leeward Antilles ridge within the broad Caribbean-South America plate boundary zone presently characterized by east-west, right-lateral strike-slip motion. The crust of the Leeward Antilles ridge represents the western segment of the Cretaceous-early Cenozoic Great Arc of the Caribbean, which obliquely collided, with the continental margin of northern South America in early Cenozoic time. Following the collision, the ridge was affected by folding and was segmented by oblique, northwest-striking normal faults that have produced steep-sided, northwest-trending, elongate islands and narrow shelves separated by deepwater, sediment-filled and fault-controlled basins. In this paper, we present the first fault slip observations on the Neogene carbonate rocks that cover large areas of all three islands. Our main objective is to quantify the timing and nature of Neogene to Quaternary phases of faulting and folding that have affected the structure and topography of this area including offshore sedimentary basins that are being explored for their petroleum potential. These data constrain three fault phases that have affected Aruba, Bonaire, and Curaçao and likely the adjacent offshore areas: 1) NW-SE-directed late Paleogene compression; 2) middle Miocene syndepositional NNW-SSE to NNE-SSW extension that produced deep rift basins transverse to the east-west-trending Leeward Antilles ridge; and 3) Pliocene-Quaternary NNE-trending compression that produced NW-SE-trending anticlines present on Aruba, Curaçao and Bonaire islands. Our new observations - that include detailed relationships between striated fault planes, paleostress tensors, and bedding planes - show that prominent bedding dips of Neogene limestone on Aruba, Bonaire and Curaçao were produced by regional tectonic shortening across the entire Leeward Antilles ridge rather than by localized, syndepositional effects as proposed by previous workers. We interpret Pliocene-Quaternary NNE-directed shortening effects on the Leeward Antilles ridge as the result of northeastward extrusion or “tectonic escape” of continental areas of western Venezuela combined with southeastward shallow subduction of the Caribbean plate beneath the ridge.     

Industry participation in stock assessment: the New Zealand SNA1 snapper (Pagrus auratus) fishery

We describe industry funded contributions to the assessment of the SNA1 snapper (Pagrus auratus) fishery during the 1990s and discuss the advantages and disadvantages of industry funded research. We also provide background on the history of fisheries management in New Zealand, on the current assessment and management processes, and on the SNA1 snapper fishery. In the SNA1 fishery, the contributions of industry and the cooperation with Government scientists has resulted in high quality assessments. In our opinion, the advantages of industry funded research out weigh the disadvantages and suggest that industry funded assessments are highly desirable and should be an integral part of any management system.     

Measurement and modeling of bed shear stress under solitary waves

Direct measurements of bed shear stresses (using a shear cell apparatus) generated by non-breaking solitary waves are presented. The measurements were carried out over a smooth bed in laminar and transitional flow regimes (~ 10⁴ < R_e < ~ 10⁵). Measurements were carried out where the wave height to water depth (h/d) ratio varied between 0.12 and 0.68; maximum near bed velocity varied between 0.16 m/s and 0.51 m/s and the maximum total shear stress (sum of skin shear stress and Froude–Krylov force) varied between 0.386 Pa and 2.06 Pa. The total stress is important in determining the stability of submarine sediment and in sheet flow regimes. Analytical modeling was carried out to predict total and skin shear stresses using convolution integration methods forced with the free stream velocity and incorporating a range of eddy viscosity models. Wave friction factors were estimated from skin shear stress at different instances over the wave (viz., time of maximum positive total shear stress, maximum skin shear stress and at the time of maximum velocity) using both the maximum velocity and the instantaneous velocity at that phase of the wave cycle. Similarly, force coefficients obtained from total stress were estimated at time of maximum positive and negative total stress and at maximum velocity. Maximum positive total shear stress was approximately 1.5 times larger than minimum negative total stress. Modeled and measured positive bed shear stresses are well correlated using the best convolution model, but the model underestimates the data by about 4%. Friction factors are dependent on the choice of normalizing using the maximum velocity, as is conventional, or the instantaneous velocity. These differ because the stress is not in phase with the velocity in general. Friction factors are consistent with previous data for monochromatic waves, and vary inversely with the square-root of the Reynolds number. The total shear stress leads the free stream fluid velocity by approximately 50°, whereas the skin friction shear stress leads by about 30°, which is similar to that reported by earlier researchers.     

Dissolved carbon and 33-133-133-1anomalies in the water column caused by hydrocarbon seeps on the northwestern Gulf of Mexico slope

Alkalinity, dissolved inorganic carbon (DIC), and ¹³C profiles from seep sites on the northwestern Gulf of Mexico upper slope show anomalously negative ¹³C values of up to –4.5 PDB, increased levels of DIC of up to 2.45 mmole/liter, and slight alkalinity rises of up to 2.54 meq/liter, relative to water column profiles from a seep-free site (0.63, 2.04 mmole/liter, and 2.39 meq/liter). The observed DIC enrichments coupled with the¹³C-depletions are attributed to the release of CO₂ by microbial oxidation of crude oil in the seep environment, and its migration into the water column. The ¹³C composition of the migrating CO₂ is estimated to be –26.0 on the basis of dissolved carbon inventory. Manifestation of DIC and ¹³C anomalies in the water column caused by hydrocarbon seepage holds promise to be useful for hydrocarbon reconnaissance surveys over large offshore tracts on account of the simplicity of sampling acquisition, and rapidity of analytical techniques in the laboratory.     

Geochemistry of suspended matter from the Baltic Sea 2. Results of bulk trace metal analysis by AAS

In 1984, on a transect covering the whole Baltic Sea and parts of the adjacent North Sea, 160 water samples were taken and analysed for their concentrations of particulate and dissolved metals. In addition, the suspended materials were investigated for their elemental bulk composition.The particulate fractions represented from about 5% (Cd, Cu and Ni) to 50% (Fe and Pb) of the total (particulate plus dissolved) concentrations. For some elements (Ba, Cd, Cu, Pb and Zn), the particulate matter from the surface microlayer was enriched with respect to those suspended materials taken from 0.2 m depth. This could reflect the atmospheric input of metal-rich aerosols. In anoxic deep waters, maximum contents of Zn (6400 μg g⁻¹), Cu (1330 μg g⁻¹) and Cd (12 μg g⁻¹) were observed in the particulate matter, indicating sulphidic forms. On the other hand, under oxic conditions the distribution coefficients (K_d) decreased with the water depth (Cd, Fe and Pb).Relative to global background levels, the particulate matter contained metal “excesses” amounting to more than 90% of the total contents (Cd, Mn, Pb and Zn). Automated electron probe X-ray microanalysis (EPXMA) revealed that the elemental composition of sediments is mainly governed by post-depositional processes of early diagenesis and is only weakly related to the composition of suspended matter in the overlying water body. For instance, in relation to surface mud sediments of the central Baltic net-sedimentation basins, Zn, Cd, Cu and Mn had 30–100% higher levels in the suspended materials. The general pattern of metal contents of particulate matter taken from 10 m depth on a transect between the Bothnian Bay and the North Sea were—possibly as a result of anthropogenic inputs—rather similar for Pb, Zn and Cu. For Fe and Mn, the distribution patterns along the transect were probably governed by the natural loading characteristics and by the biogeochemistry of those elements.     

Carbon balance in a salt marsh: Interactions of diffusive export, tidal deposition and rainfall-caused erosion

Studies of the concentrations of particulate and dissolved organic carbon in the Duplin River, of the tidal exchange of POC and DOC in the marsh, of the standing stock and movement of Spartina alterniflora wrack in the Duplin, and of the removal of carbon from the surface of the marsh by rain were conducted at Sapelo Island, Georgia in order to test three hypotheses about export of carbon from the Duplin River watershed. We found that the gradients in POC and DOC concentrations are such that carbon is being transported down the Duplin River throughout the year, although in smaller quantities than previously believed. In contrast, almost all tidal exchanges within the marsh result in deposition of carbon. Most of this deposited carbon is subsequently eroded as a result of rain falling on the exposed marsh surface, and is washed back into the tidal creeks. This cycle of deposition and erosion is a possible mechanism keeping POC in the thin aerobic surface layer of the marsh, thus increasing its availability to detritivores and aerobic microbes. The standing stock of wrack is only a fraction of the S. alterniflora produced each year, and its export is a negligible term in the carbon balance equation.