Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

On the Occurrence of Zellia from the Maping Limestone of Chengkung, Central Yunnan

INTRODUCTIONThe specimens described in the present paper were collected in 1939 by the late Mr. T. Y. Hsu and Mr. C. S. Pien from the Maping limestone exposed E of Tuikoshan, Chengkung district, Central Yunnan. All specimens belong to Zellia, a subgenus of Pseudoschwagerina; three forms may be referred to known subspecies while two are new.     

Contribution of electrical tomography methods in geotechnical investigations at Mavropigi lignite open pit mine,Northern Greece

In this paper, the application of 2D and 3D electrical resistivity methods in geotechnical investigations is explored through a case study in Northern Greece. These two methods were employed at a lignite surface mining operation where fracture zones and discontinuities have been recently observed close to the pit boundaries. The main aim of the geophysical survey was to estimate the inclination of the contact between the Neogene and Schist/Carbonate formations near the southern limits of the pit, as well as to estimate the thickness of the carbonate rocks on top of the Schist formations to evaluate the stability of the southern slopes. Synthetic data were initially generated to help plan an efficient electrical tomography survey, in a region with complex geology and irregular terrain. Three configurations (Wenner–Schlumberger and dipole–dipole or pole–dipole) proved essential in such conditions and helped improving the resolution of the resistivity section. The sections were then calibrated by boreholes. Finally, the geophysical survey provided invaluable data regarding the geometry of the bedrock and possible faults, which was essential for the slope stability calculations.     

Sedimentological analysis of two drill cores through the crater moat‐filling breccia,Flynn Creek impact structure,Tennessee

Sedimentological (line‐logging) analysis of two drill cores, FC77‐3 and FC67‐3, situated, respectively, in the northwestern and southeastern quadrants of the Flynn Creek impact structure's crater‐moat area reveals that the ~27 m thick crater moat‐filling breccia consists of three subequal parts. These parts, which were deposited during early modification stage of this marine‐target impact structure, are distinguished on the basis of vertical trends in sorting, grain size, and counts of clasts per meter in comparison with other well‐known marine‐target impact structures, namely Lockne, Tvären, and Chesapeake Bay. The lower part is interpreted to represent mainly slump deposits, and the middle part is interpreted to represent a stage intermediate between slump and marine resurge, that is, a traction flow driven by overriding suspension flow. The upper part (size graded, and relatively well sorted and fine grained) is interpreted to represent marine resurge flow only. The upper part is capped by a relatively thin and relatively fine‐grained calcarenite to calcisiltite deposit.     

Oxygen and hydrogen isotope fractionation in serpentine-water and talc-water systems from 250 to 450 °C, 50 MPa

Oxygen and hydrogen isotope fractionation factors in the talc-water and serpentine-water systems have been determined by laboratory experiment from 250 to 450 °C at 50 MPa using the partial exchange technique. Talc was synthesized from brucite + quartz, resulting in nearly 100% exchange during reaction at 350 and 450 °C. For serpentine, D-H exchange was much more rapid than ¹⁸O-¹⁶O exchange when natural chrysotile fibers were employed in the initial charge. In experiments with lizardite as the starting charge, recrystallization to chrysotile enhanced the rate of ¹⁸O-¹⁶O exchange with the coexisting aqueous phase. Oxygen isotope fractionation factors in both the talc-water and serpentine-water systems decrease with increasing temperature and can be described from 250 to 450 °C by the relationships: 1000 ln  = 11.70 × 10⁶/T² − 25.49 × 10³/T + 12.48 and 1000 ln  = 3.49 × 10⁶/T² − 9.48 where T is temperature in Kelvin. Over the same temperature interval at 50 MPa, talc-water D-H fractionation is only weakly dependent on temperature, similar to brucite and chlorite, and can be described by the equation: 1000 ln = 10.88 × 10⁶/T² − 41.52 × 10³/T + 5.61 where T is temperature in Kelvin. Our D-H serpentine-water fractionation factors calibrated by experiment decrease with temperature and form a consistent trend with fractionation factors derived from lower temperature field calibrations. By regression of these data, we have refined and extended the D-H fractionation curve from 25 to 450 °C, 50 MPa as follows: 1000 ln  = 3.436 × 10⁶/T² − 34.736 × 10³/T + 21.67 where T is temperature in Kelvin. These new data should improve the application of D-H and ¹⁸O-¹⁶O isotopes to constrain the temperature and origin of hydrothermal fluids responsible for serpentine formation in a variety of geologic settings.     

N and O isotope effects during nitrate assimilation by unicellular prokaryotic and eukaryotic plankton cultures

In order to provide biological systematics from which to interpret nitrogen (N) and oxygen (O) isotope ratios of nitrate (¹⁵N/¹⁴N, ¹⁸O/¹⁶O, respectively) in the environment, we previously investigated the isotopic fractionation of nitrate during its assimilation by mono-cultures of eukaryotic algae (Granger et al., 2004). In this study, we extended our analysis to investigate nitrate assimilation by strains of prokaryotic plankton. We measured the N and O isotope effects, ¹⁵ε and ¹⁸ε, during nitrate consumption by cultures of prokaryotic strains and by additional eukaryotic phytoplankton strains (where ε is the ratio of reaction rate constants of the light vs. heavy isotopologues, ^lightk and ^heavyk; ε = ^lightk/^heavyk − 1 × 1000, expressed in per mil). The observed ¹⁵ε ranged from 5‰ to 8‰ among eukaryotes, whereas it did not exceed 5‰ for three cyanobacterial strains, and was as low as 0.4‰ for a heterotrophic α-protoeobacterium. Eukaryotic phytoplankton fractionated the N and O isotopes of nitrate to the same extent (i.e., ¹⁸ε ∼ ¹⁵ε). The ¹⁸ε:¹⁵ε among the cyanobacteria was also ∼1, whereas the heterotrophic α-proteobacterial strain, which showed the lowest ¹⁵ε, between 0.4‰ and 1‰, had a distinct ¹⁸ε:¹⁵ε of ∼2, unlike any plankton strain observed previously. Equivalent N vs. O isotope discrimination is thought to occur during internal nitrate reduction by nitrate reductase, such that the cellular efflux of the fractionated nitrate into the medium drives the typically observed ¹⁸ε:¹⁵ε of ∼1. We hypothesize that the higher in the ¹⁸ε:¹⁵ε of the α-proteobacterium may result from isotope discrimination by nitrate transport, which is evident only at low amplitude of ε. These observations warrant investigating whether heterotrophic bacterial assimilation of nitrate decreases the community isotope effects at the surface ocean.     

Tsunamis as geological agents

When a tsunami wave series approaches and interacts with a coast, the consequent passage shorewards of great volumes of water and their invasion of the land, especially within bays and up river valleys, results in the disturbance of existing sediment and the removal seawards of land debris and coastal and shallow‐water marine sediments. Tsunami action builds up sequences of peculiar sediments in shallow water; it at least assists in the formation and maintenance of submarine canyons and, through them, produces turbidity currents of a particularly powerful kind. Tsunami action may explain many puzzling sedimentary phenomena, for example, sudden and drastic changes in near‐shore bathymetry; the formation of chaotic sediments such as some paraconglomerates and edgewise conglomerates. It offers solutions to problems arising from the study of turbiditic sequences, both modern and ancient.