Problem of the Relationship between Phosphorites and Evaporites (Critical Comments to the Work by A.S. Sokolov “Paragenetic Interrelations between Phosphoritic and Saliferous Basins,” Lithology and Mineral Resources, 1999, no. 2)

Lithology and Mineral Resources -     

Exploring the effects of data quality,data worth,and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST inversion

This study examined the impacts of reservoir properties on carbon dioxide (CO₂) migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO₂ monitoring data such as spatial–temporal distributions of gas pressure, which can be reasonably monitored in practice. The injection reservoir was assumed to be located 1,400–1,500 m below the ground surface such that CO₂ remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO₂ injection simulation used a cylindrical grid setting in which the injection well was situated at the center of the domain, which extended out 8,000 m from the injection well. The CO₂ migration was simulated using the latest version of the simulator, subsurface transport over multiple phases (the water–salt–CO₂–energy module), developed by Pacific Northwest National Laboratory. A nonlinear parameter estimation and optimization modeling software package, Parameter ESTimation (PEST), is adopted for automated reservoir parameter estimation. The effects of data quality, data worth, and data redundancy were explored regarding the detectability of reservoir parameters using gas pressure monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO₂ monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy. The feasibility of using CO₂ saturation data for improving reservoir characterization was also discussed.     

Hydrologic and geomorphic processes in the Colville River delta, Alaska

The Colville basin drains the North Slope of Alaska and is one of several large Arctic river systems located within permafrost. The timing and style of fluvial processes in the earth's permafrost regions differ from those occurring in midlatitude settings. Moreover, in comparison to temperate-zone systems, rivers located entirely within permafrost perform most of their work during relatively short periods of time. This paper examines river ice hydrology and the resulting geomorphic processes that occur within the Colville delta, Alaska. Fluvial processes and landform development within the Colville delta occur after the flood-pulse is initiated by the breakup of river ice. During this 4-month period, the geomorphic processes are largely influenced by the movement of ice. The flood-pulse and accompanying river ice influences erosional and depositional processes and results in unique styles of sediment transport, deposition, and riverbank erosion.     

Geochemistry and Metallogeny of Phosphorus in the Russian Platform during the Jurassic–Cretaceous

The composition and metallogeny of igneous rocks and relevant weathering crusts of Jurassic–Cretaceous provenances of the Russian Platform are considered. It is shown that the association of metals that accumulated in the process of weathering and erosion of ancient substratum includes P, Fe, Ti, V, and Cr. This process is reflected in the formation of nodular phosphorites, Ti and Zr placers, and iron ore deposits in the Jurassic–Cretaceous seas of the platform.     

Short-term and interannual variability of redox-sensitive chemical parameters in hypoxic/anoxic bottom waters of the Chesapeake Bay

A combination of CTD casts, discrete bottle sampling and in situ voltammetric microelectrode profiling was used to examine changing redox conditions in the water column at a single station south of the Bay Bridge in the upper Chesapeake Bay in late July/early August, 2002–2005. Short-term (2–4 h) fluctuations in the oxic/suboxic/anoxic interface were documented using in situ voltammetric solid-state electrodes. Profiles of dissolved oxygen and sulfide revealed tidally-driven vertical fluctuations of several meters in the depth and thickness of the suboxic zone. Bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ also varied over the tidal cycle by approximately an order of magnitude. These data indicate that redox species concentrations at this site varied more due to physical processes than biogeochemical processes. Based on analysis of ADCP data, tidal currents at this station were strongly polarized, with the principal axis of tidal currents aligned with the mainstem channel. Together with the chemical data, the ADCP analysis suggests tidal flushing of anoxic bottom waters with suboxic water from north of the site. The present study is thus unique because while most previous studies have focused on processes across relatively stable redox interfaces, our data clearly demonstrate the influence of rapidly changing physical mixing processes on water column redox chemistry.Also noted during the study were interannual differences in maximum bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺. In 2003, for example, heavy spring rains resulted in severe hypoxia/anoxia in June and early July. While reported storm-induced mixing in late July/early August 2003 partially alleviated the low-oxygen conditions, bottom water concentrations of sulfide, Mn²⁺ and Fe²⁺ were still much higher than in the previous year. The latter implies that the response time of the microbial community inhabiting the suboxic/anoxic bottom waters to changing redox conditions is slow compared to the time scale of episodic mixing events. Bottom water concentrations of the redox-sensitive chemical species should thus be useful as a tracer to infer prior hypoxic/anoxic conditions not apparent from ambient oxygen levels at the time of sampling.