Improved Platinum-Group Element Extraction by NiS Fire Assay from Chromitite Ore Samples Using a Flux Containing Sodium Metaphosphate

Many chromite-rich rocks contain relatively high concentrations of the platinum-group elements (PGE). In many cases, the phases carrying PGE occur as either platinum-group minerals (PGM) or as base metal sulfides in solid solution in sulfides. In some cases, such as the UG-2 unit of the Bushveld Complex, the PGM are occluded inside chromite grains. Chromites are notably difficult to dissolve in most fluxes and if the chromite contains some PGM the possibility exists that not all the PGE will be recovered during fusion. In this work, shortcomings in published methods of analysis based on the nickel sulfide fire assay procedure were investigated and a new procedure developed based on the addition of sodium metaphosphate to the fusion mixture. Optimum composition of the fusion mixture was found to be 10 g sodium metaphosphate and 9 g silica to 10 g sample, 15 g sodium carbonate, 30 g lithium tetraborate, 7.5 g nickel and 4.5 g sulfur to achieve complete dissolution of chromite grains. The new flux mixture was evaluated by the analysis of reference material CHR-Pt+ (which is known to contain PGM inside chromite grains) and no undissolved chromite grains were found in the glassy slag. Analysis of the nickel sulfide beads from this fire assay using neutron activation analysis showed similar results for Rh and Ru when compared with published conventional true (or accepted) values, while Au, Ir, Os, Pd and Pt values determined here were 10 to 30% higher than the corresponding published conventional true values. It was concluded that the addition of sodium metaphosphate improved chromite dissolution in the flux and appears to improve PGE recovery.     

利用树轮资料重建青海都兰地区过去1835年的气候变化

根据青海都兰地区树木年轮样本,建立了上前我国最长的年轮年表序列（１８３５a）,系 统地与所在地区气候资料进行了综合分析。通过响应函数计算得出,该年表对温度因子的反映更为第三一些。在响应面分析中发现,温度、降水与年轮宽度的关系呈现出随温度和降水的不同而不同。在温度低而降水量少的情况下,其线性相关性明显;但在温度较高和降水量较多时,树轮与两要素间的关系就显得不明显。另外,还对该年表玮秋季平均温度的关系进     

Raman spectroscopic studies of carbonates part I: High-pressure and high-temperature behaviour of calcite,magnesite, dolomite and aragonite

The room-temperature Raman spectra of aragonite, magnesite and dolomite have been recorded up to 30 GPa and 25 GPa, respectively and no phase changes were observed during compression, unlike calcite. The effect of temperature on the room-pressure Raman spectra of calcite, aragonite, magnesite and dolomite is reported up to 800–1100 K. The measured relative pressure and temperature-shifts of the Raman lines are greater for the lattice modes than for the internal modes of the CO₃ groups. These shifts are used to calculate the mode anharmonic parameters of the observed Raman modes; they are negative and their absolute values are smaller (close to 0) for the internal CO₃ modes than for the lattice modes (4–17 10^?5 K^?1). The temperature shifts of the lattice modes in calcite are considerably larger than those for dolomite and magnesite, and a marked non-linear increase in linewidth is observed above 400° C for calcite. This is consistent with an increasing relaxational component to the libration of the CO₃ groups about their threefold axes, premonitory to the rotational order-disorder transition at higher temperature. This behaviour is not observed for the other calcite structured minerals in this study. We examine systematic variations in the lattice mode frequencies and linewidths with composition, to begin to understand these differences in their anharmonic behaviour. Finally, we have used a simple Debye-Waller model to calculate atomic displacements in calcite, magnesite and dolomite with increasing temperature from the vibrational frequency data, to provide a direct comparison with atomic positional data from high-temperature structure refinements.     

Geology of the Victor Kimberlite, Attawapiskat, Northern Ontario, Canada: cross-cutting and nested craters

The pipe shapes, infill and emplacement processes of the Attawapiskat kimberlites, including Victor, contrast with most of the southern African kimberlite pipes. The Attawapiskat kimberlite pipes are formed by an overall two-stage process of (1) pipe excavation without the development of a diatreme (sensu stricto) and (2) subsequent pipe infilling. The Victor kimberlite comprises two adjacent but separate pipes, Victor South and Victor North. The pipes are infilled with two contrasting textural types of kimberlite: pyroclastic and hypabyssal-like kimberlite. Victor South and much of Victor North are composed of pyroclastic spinel carbonate kimberlites, the main features of which are similar: clast-supported, discrete macrocrystal and phenocrystal olivine grains, pyroclastic juvenile lapilli, mantle-derived xenocrysts and minor country rock xenoliths are set in serpentine and carbonate matrices. These partly bedded, juvenile lapilli-bearing olivine tuffs appear to have been formed by subaerial fire-fountaining airfall processes.

The Victor South pipe has a simple bowl-like shape that flares from just below the basal sandstone of the sediments that overlie the basement. The sandstone is a known aquifer, suggesting that the crater excavation process was possibly phreatomagmatic. In contrast, the pipe shape and internal geology of Victor North are more complex. The northwestern part of the pipe is dominated by dark competent rocks, which resemble fresh hypabyssal kimberlite, but have unusual textures and are closely associated with pyroclastic juvenile lapilli tuffs and country rock breccias±volcaniclastic kimberlite. Current evidence suggests that the hypabyssal-like kimberlite is, in fact, not intrusive and that the northwestern part of Victor North represents an early-formed crater infilled with contrasting extrusive kimberlites and associated breccias. The remaining, main part of Victor North consists of two macroscopically similar, but petrographically distinct, pyroclastic kimberlites that have contrasting macrodiamond sample grades. The juvenile lapilli of each pyroclastic kimberlite can be distinguished only microscopically. The nature and relative modal proportion of primary olivine phenocrysts in the juvenile lapilli are different, indicating that they derive from different magma pulses, or phases of kimberlite, and thus represent separate eruptions. The initial excavation of a crater cross-cutting the earlier northwestern crater was followed by emplacement of phase (i), a low-grade olivine phenocryst-rich pyroclastic kimberlite, and the subsequent eruption of phase (ii), a high-grade olivine phenocryst-poor pyroclastic kimberlite, as two separate vents nested within the original phase (i) crater. The second eruption was accompanied by the formation of an intermediate mixed zone with moderate grade. Thus, the final pyroclastic pipe infill of the main part of the Victor North pipe appears to consist of at least three geological/macrodiamond grade zones.

In conclusion, the Victor kimberlite was formed by several eruptive events resulting in adjacent and cross-cutting craters that were infilled with either pyroclastic kimberlite or hypabyssal-like kimberlite, which is now interpreted to be of probable extrusive origin. Within the pyroclastic kimberlites of Victor North, there are two nested vents, a feature seldom documented in kimberlites elsewhere. This study highlights the meaningful role of kimberlite petrography in the evaluation of diamond deposits and provides further insight into kimberlite emplacement and volcanism.     

Fingerprinting of the Atlantic meridional overturning circulation in climate models to aid in the design of proxy investigations

It is desirable to design proxy investigations that target regions where properties reconstructed from calibrated parameters potentially carry high-fidelity information concerning changes in large-scale climate systems. Numerical climate models can play an important role in this task, producing simulations that can be analyzed to produce spatial “fingerprints” of the expected response of various properties under a variety of different scenarios. We will introduce a new method of fingerprinting the Atlantic meridional overturning circulation (AMOC) that not only provides information concerning the sensitivity of the response at a given location to changes in the large-scale system, but also quantifies the linearity, monotonicity and symmetry of the response. In this way, locations that show high sensitivities to changes in the AMOC, but that exhibit, for example, strongly nonlinear behavior can be avoided during proxy investigations. To demonstrate the proposed approach we will use the example of the response of seawater temperatures to changes in the strength of the AMOC. We present results from an earth-system climate model which has been perturbed with an idealized freshwater forcing scenario in order to reduce the strength of the AMOC in a systematic manner. The seawater temperature anomalies that result from the freshwater forcing are quantified in terms of their sensitivity to the AMOC strength in addition to the linearity and monotonicity of their response. A first-order reversal curve (FORC) approach is employed to investigate and quantify the irreversibility of the temperature response to a slowing and recovering AMOC. Thus, FORCs allow the identification of areas that are unsuitable for proxy reconstructions because their temperature versus AMOC relationship lacks symmetry.     

Sorption behaviour of pentachlorophenol in sub-Saharan tropical soils: soil types sorption dynamics

In order to predict exposure risks as well as appropriate remediation strategies for pesticides in soils, knowledge of pesticides sorption processes onto various representative soils is vital. Hence, laboratory batch experiments were carried out to study sorption of a pesticide, pentachlorophenol (PCP), on five soils obtained from different sub-Saharan agro-ecological zones (AEZs) in order to understand sorption equilibrium, kinetics, and thermodynamics. Experimental data showed that sorption equilibrium was attained within 24 h. The fitting of kinetic results and equilibrium data to different models suggested partly surface adsorption and partly partitioning of PCP within voids of the various soil components. Sorption was mainly attributed to sharing or exchange of valence electrons between negatively charged PCP molecules and positively charged soil sorption sites. The sorption process was spontaneous and accompanied by decreased entropy, but was pH and temperature dependent, reducing with increase in pH and temperature. The various soils’ PCP sorption capacities were directly proportional to their cation exchange capacities. The low PCP sorption observed in these soils suggested high risk of PCP being present in soil water solution, especially at higher temperatures, which can lead to contamination of the aquifer. This risk may be higher for soils obtained from AEZs with warmer natural temperatures.     

Class distribution and locality in rural areas: an example from Gloucestershire

The analysis of rural social change has reached a point of somewhat saturated orthodoxy. Numerous studies over the last 20 years have served to reinforce a standard view that it is the ‘newcomer vs local’ conflict which lies at the heart of social and cultural changes in rural communities. Moreover, these broad categorisations have often been translated into class terms without due regard for the detailed circumstances of locality or intra-class fractions. This paper presents some evidence from an intensive study of 10 parishes in rural Gloucestershire, and seeks to provide a detailed background to the distribution of selected indicators of social change in that area. It focuses on the diversions and needs experienced by different social groups and suggests additional complexities to those recognised in traditional treatments of rural conflict.