Early diagenetic influences on iron transformations in a freshwater lake sediment

Iron transformations in a calcium carbonate rich fresh-water sediment were studied by analyzing the relevant constituents of both interstitial water and solid matter. Analysis of interstitial water shows that the observed redox sequence NO⁻₃/NH⁺₄, MnO₂/Mn(II), FeOOH/Fe(II), SO²⁻₄/S(−II) is roughly in agreement with that predicted by the Gibbs Free Energy for the corresponding reactions. In contrast to marine sediments, these redox transitions occur in the uppermost sediments, i.e., at depths of 0–4 cm.

Deeper in the sedimentary sequence, the depth profile for dissolved iron exhibits a steady non-linear increase up to 400 μmol dm⁻³. In this anoxic zone, according to thermodynamic predictions, iron (II)-minerals such as iron sulfide, siderite, and vivianite should precipitate while Fe(III) oxides should be completely dissolved. However, microscopic analysis showed that Fe(III) oxides were present throughout the studied sediment. Furthermore, scanning electron microscope/energy dispersive spectroscopy analysis suggests the presence of iron sulfide could be verified but not that of siderite or vivianite. These observations indicate kinetic control of iron transformations.

We have investigated the importance of kinetic control of iron distribution in anoxic sediments using a diagenetic model for dissolved iron(II). A rough estimate of time scales for dissolution and precipitation rates was made by imposing limiting boundary conditions. Using the calculated rate constant, we established that more than 1000 years would be required for the complete dissolution of Fe(III) oxides, which is agreement with our observations and experimental data from the literature. Calculated precipitation rates of Fe(II) for a given mineral phase such as siderite yield a maximum value of 3 μg_(FeCO3) g⁻¹_{(dry sediment)} yr⁻¹. Such low rates would explain the absence of siderite and vivianite.

Finally, it can be inferred from the Mn_T/Fe_T ratio in the sediments that this ratio depends on the redox conditions of the sediment-water interface at the time of deposition. Thus, this ratio can be used as “paleo-redox indicator” in lacustrine sediments.     

Habitat use by small mammals in coastal marshes of Southwestern Louisiana

A short-term study based on snap-trap capture rates of small mammals in the marsh and levee system in southwestern Louisiana was conducted in the winter-spring period. Marsh rice rats (Oryzomys palustris) dominated marsh habitats and rice rats and fulvous harvest mice (Reithrodontomys fulvescens) were co-dominants on levees. Least shrews (Cryptotis parva) and house mice (Mus musculus) were also taken. Although rice rat capture rate in marshes was twice that from levees, the difference was not significant (p=0.1428). When found on levees, rice rats preferred portions of levees adjacent to marshes and canals (p<0.0001). We found few differences in rice rat capture rates from marsh and levee habitats, although capture rates from fresh marsh and adjacent levees were select levee ridges over the marsh and canal edges (0.1≥p≥0.05). The abundance of harvest mice on levees adjacent to intermediate marshes exceeded all other levee habitats. For reasons as yet unexplained, intermediate marshes and adjacent levees had the highest small mammal abundance and species richness. Conversely, fresh marshes and their adjacent levees had the lowest abundance and variety of small mammals.     

Relationship between aboveground and belowground biomass ofSpartina alterniflora (Smooth Cordgrass)

Aboveground and belowground biomass ofSpartina alterniflora were harvested during the period of peak aerial biomass from six sites along a latitudinal gradient ranging from Georgia to Nova Scotia. An equation relating live aboveground to live belowground biomass for short-form plants was formulated, using data collected in Delaware marshes. When data from the other sites were substituted into the equation, the mean live belowground biomass it predicted was within 15% of the value determined by harvesting at four of the five sites. At all sites, short-form plant live belowground biomass was concentrated in the upper 10 cm. Dead belowground biomass was located mostly in the top 15 cm in southern marshes, but was more evenly distributed with depth in northern marshes. Results were more ambiguous for tall-form plants, probably because of greater spatial variability in biomass distribution, and greater seasonal biomass dynamics.     

Composition of widespread volcanic glass in deep-sea sediments of the Southern Pacific Ocean: an Antarctic source inferred

Widespread Plio-Pleistocene (2.43-0.06 Ma) tephra zones recognised in deep-sea cores from high latitudes (>60°) in the Southern Pacific Ocean were thought to have originated from calc-alkaline rhyolitic eruptions in New Zealand, some 5000 km distant. Electron microprobe analyses of the glasses reveal a wide diversity of alkalic felsic compositions, as well as minor components of basic and intermediate glasses, incompatible with a New Zealand Neogene source but similar to contemporaneous eruptives from the Antarctic region. Most tephra zones are trachytic; seven zones are peralkaline rhyolite. The rhyolitic zones represent a deep-sea record of widespread silicic eruptions from continental Antarctica, possibly Marie Byrd Land. The extent of these rhyolitic zones suggest a greater frequency of large explosive eruptions in Antarctica than previously documented. The coarse grain size of some of the shards (up to 3 mm), their great distance from the closest sources (>1600 km for some cores), and the presence of nonvolcanic ice-rafted debris indicate some of the glasses, especially the more basic compositions, may have been ice-rafted, contrary to previous suggestions of a fallout origin.     

The influence of rock mass strength on glacial valley cross-profile morphometry: A case study from the Southern Alps,New Zealand

The erosional morphology in the vicinity of the Main Divide of the Southern Alps, and Fiordland, New Zealand, appears to be a product of the interaction between Alpine Fault-induced tectonic processes, rock mass strength of the uplifted and eroded bedrock, and the processes acting to denude the developing mountain landscape. The magnitude of the effects of glacial erosion on the landscape is directly controlled by the size and physical properties of the glaciers, whilst the form of the trough is a direct consequence of the rock mass strength (RMS) properties of the slope rock. Realistic models of development of the cross-profile shape of glacial valleys must take into consideration the RMS properties of the eroded substrate.     

Denudational isostatic rebound of intraplate highlands: The lachlan river valley,Australia

A range of evidence from the Lachlan valley in the southeast Australian highlands is consistent with Neogene isostatic rebound in response to denudational unloading. This evidence is found along the inland edge of the highlands in the transition zone between the highlands proper and the Lachlan's inland alluviated valley and the intracratonic Murray Basin. The amounts and rates of uplift indicated by offsets of suballuvium bedrock profiles and the long profiles of Tertiary valley-filling basalts are consistent with modelling of denudational rebound using known rates of highland denudation and basinal sedimentation, and reasonable crustal properties. The modelling shows that weak to moderately strong strong lithosphere (effective elastic thickness, T_e = 1-25 km) and strong lithosphere (T_e = 100 km) are all consistent with the observed amounts of rebound. Strong lithosphere must be broken, however, to be consistent with the field data. Even in the Australian setting, which is characterized by very low rates of denudation, isostatic rebound in response to denudational unloading must be a significant factor in maintaining highland elevation and must be incorporated in models of long-term landscape evolution. It would be expected that denudational isostatic rebound would be an even more significant component of long-term landscape evolution in areas of higher denudation rates.     

Two dynamical models for solar spicules

Solar spicules are luminous jets that erupt up to 10 000 km from the surface of the Sun and have diameters, all along their length, of only about 150–200 km. We first review some recent observations made at the H wavelength. According to our models, a solar spicule is a self-channelled proton beam emitted by a magnetic element and surrounded by a cold sheath. The beam originates in a self-excited dynamo that exploits a v × B field and that could be situated either below or above the element, where v is the local plasma velocity and B is the local magnetic flux density. In falling back, the sheath provides a return current of protons that cancels the outgoing current. We discuss the channelling of charged-particle beams of very large cross-section and propose velocity channelling, which is apparently a new concept. We assume a steady state and a hydrogen plasma.     

Integrating agriculture and energy to assess GHG emissions reduction: a methodological approach

Agriculture is responsible for approximately 25% of anthropogenic global GHG emissions. This significant share highlights the fundamental importance of the agricultural sector in the global GHG emissions reduction challenge. This article develops and tests a methodology for the integration of agricultural and energy systems modelling. The goal of the research is to extend an energy systems modelling approach to agriculture in order to provide richer insights into the dynamics and interactions between the two (e.g. in competition for land-use). We build Agri-TIMES, an agricultural systems module using the TIMES energy systems modelling framework, to model the effect of livestock emissions and explore emissions reduction options. The research focuses on Ireland, which is an interesting test case for two reasons: first, agriculture currently accounts for about 30% of Ireland's GHG emissions, significantly higher than other industrialized countries yet comparable with global levels (here including emissions associated with other land-use change and forestation); second, Ireland is both a complete and reasonably sized agricultural system to act as a test case for this new approach. This article describes the methodology used, the data requirements, and technical assumptions made to facilitate the modelling. It also presents results to illustrate the approach and provide associated initial insights.

Policy relevance

Most of the policy focus with regard to climate mitigation targets has been on reducing energy-related CO₂ emissions, which is understandable as they represent by far the largest source of emissions. Non-energy-related GHG emissions – largely from agriculture, industrial processes, and waste – have received significantly less attention in policy discourse. Going forward, however, if significant cuts are made in energy-related CO₂ emissions, the role of non-energy-related GHG emissions will grow in importance. It is therefore crucial that climate mitigation analyses and strategies are not limited to the energy system. This article shows the value of using integrated energy and agriculture techno-economic modelling techniques to draw evidence for new comprehensive climate policy strategies able to discern between the full range of technical solutions available. It enables the production of economy-wide least-cost climate mitigation pathways.