Provenance of Pleistocene Rhine River Middle Terrace sands between the Swiss–German border and Cologne based on U–Pb detrital zircon ages

Detrital zircon U–Pb age distributions derived from samples representing ancient or relatively young large-scale continental drainage networks are commonly taken to reflect the geochronological evolution of the tapped continental area. Here, we present detrital zircon U–Pb ages and associated heavy mineral data from Pleistocene Rhine River Middle Terrace sands and equivalents between the Swiss–German border and Cologne in order to test the commonly assumed Alpine provenance of the material. Samples from eight localities were analyzed for their heavy mineral assemblages. Detrital zircon U–Pb ages were determined by laser ablation inductively coupled mass spectrometry on selected samples from five locations along the Rhine River. The zircon age populations of all samples show a similar distribution, their main peaks being between 300 and 500 Ma. Minor age populations are recognized at 570 and 1,070 Ma. The 300–400 Ma maximum reflects the Variscan basement drained by or recycled into the Rhine River and its tributaries. The 400–500 Ma peak with predominantly Early Silurian ages points to Baltica or to the mid-German crystalline rise as original sources. One distinct peak at c. 570 Ma probably represents input from Cadomian terranes. The Precambrian U–Pb ages are compatible with derivation from sources in Baltica and in northern Gondwana. The heavy mineral populations of Middle Terrace sands and equivalents are characterized to a variable extend by garnet, epidote, and green hornblende. This association is often referred to as the Alpine spectrum and is considered to be indicative of an Alpine provenance. However, hornblende, epidote, and garnet are dominant heavy minerals of collisional orogens in general and may also be derived from Variscan and Caledonian units or from intermittent storage units. A remarkable feature of the detrital zircon age distribution in the Rhine River sediments from the Swiss–German border to Cologne is the absence of ages younger than 200 Ma and in particular of any ages reflecting the Alpine orogeny between c. 100 and 35 Ma. Sediments from rivers draining the equally collisional Himalaya orogen contain detrital zircons as young as 20 Ma. Our results question the assumption that Pleistocene Rhine River sediments were directly derived from the Alps. The lag time between the formation and deposition age of the youngest zircon in the studied Pleistocene Rhine River deposits is 200 Ma. Together with the absence of Alpine zircon ages, this stresses that detrital zircon age data from ancient sedimentary units found in poorly understood tectonic or paleogeographic settings need to be interpreted with great care, one could miss an entire orogenic cycle.     

CFD modeling of high-pressurized CO2 released from onshore pipeline leakages

Safe pipeline transportation of carbon dioxide is a critical issue in the developing field of carbon capture and storage technology. Inadequate fluid thermo- and regimes for on- and offshore transport through high-pressurized pipelines can induce pipe material obsolescence or even pipeline rupture. In such cases, CO₂ (Carbon dioxide) will be released and dispersed in the ambient medium. The dispersion is influenced by the total amount of released fluid, jet pressure and direction, the released concentrations, leakage hole size, ambient material properties and is also affected by the dynamical conditions of the environmental medium. The goal of this study is the hydrodynamical characterization of carbon dioxide jet expansion and dispersion in the ambient atmosphere in case of onshore pipeline accidental leaks. Numerical simulations were carried out by means of a 3D turbulent CFD (computational fluid dynamics) code which includes multi-component flow treatment. The influence of the jet release pressure and size of the leakage hole on harmful CO₂ concentration distances will be analyzed.     

Évolution géodynamique messino-pliocène en Languedoc central : le paléo-réseau hydrographique de l’Orb et de l’Hérault (Sud de la France)

Résumé

En Languedoc central, la cartographie des sédiments formés lors de la crise messinienne et de ceux de la séquence pliocène, ainsi que les données patées paléontologiques nouvelles (Aigues-Vives et Servian) permettent de proposer une reconstitution du tracé messimeli des rivières actuelles (Orb et Hérault) transformées en rias à la suite du relèvement eustatique pliocène. L’Hérault messinien se singularise par une incision beaucoup plus faible que celle des autres rivères. En effet, la nature karstique de l’arinère-pays immédiat permet un enfouissement des eaux météoriques au profit d’aquifères profonds sous-jacents au drainage aérien du réseau hydrographique messinien. Le Languedoc central illustre, entre Roussillon et Rhône, le modèle géodynamique messino-pliocène de Clauzon. © Elsevier, Paris     

Seawater nutrient and carbonate ion concentrations recorded as P/Ca, Ba/Ca, and U/Ca in the deep-sea coral Desmophyllum dianthus

As paleoceanographic archives, deep sea coral skeletons offer the potential for high temporal resolution and precise absolute dating, but have not been fully investigated for geochemical reconstructions of past ocean conditions. Here we assess the utility of skeletal P/Ca, Ba/Ca and U/Ca in the deep sea coral D. dianthus as proxies of dissolved phosphate (remineralized at shallow depths), dissolved barium (trace element with silicate-type distribution) and carbonate ion concentrations, respectively. Measurements of these proxies in globally distributed D. dianthus specimens show clear dependence on corresponding seawater properties. Linear regression fits of mean coral Element/Ca ratios against seawater properties yield the equations: P/Ca_coral (μmol/mol) = (0.6 ± 0.1) P/Ca_sw(μmol/mol) - (23 ± 18), R² = 0.6, n = 16 and Ba/Ca_coral(μmol/mol) = (1.4 ± 0.3) Ba/Ca_sw(μmol/mol) + (0 ± 2), R² = 0.6, n = 17; no significant relationship is observed between the residuals of each regression and seawater temperature, salinity, pressure, pH or carbonate ion concentrations, suggesting that these variables were not significant secondary dependencies of these proxies. Four D. dianthus specimens growing at locations with Ω_arag ? 0.6 displayed markedly depleted P/Ca compared to the regression based on the remaining samples, a behavior attributed to an undersaturation effect. These corals were excluded from the calibration. Coral U/Ca correlates with seawater carbonate ion: U/Ca_coral(μmol/mol) = (−0.016 ± 0.003) (μmol/kg) + (3.2 ± 0.3), R² = 0.6, n = 17. The residuals of the U/Ca calibration are not significantly related to temperature, salinity, or pressure. Scatter about the linear calibration lines is attributed to imperfect spatial-temporal matches between the selected globally distributed specimens and available water column chemical data, and potentially to unresolved additional effects. The uncertainties of these initial proxy calibration regressions predict that dissolved phosphate could be reconstructed to ±0.4 μmol/kg (for 1.3-1.9 μmol/kg phosphate), and dissolved Ba to ±19 nmol/kg (for 41-82 nmol/kg Ba_sw). Carbonate ion concentration derived from U/Ca has an uncertainty of ±31μmol/kg (for ). The effect of microskeletal variability on P/Ca, Ba/Ca, and U/Ca was also assessed, with emphasis on centers of calcification, Fe-Mn phases, and external contaminants. Overall, the results show strong potential for reconstructing aspects of water mass mixing and biogeochemical processes in intermediate and deep waters using fossil deep-sea corals.     

Evaluation of Subsurface Oxygen Sensors for Remediation Monitoring

Continuous remediation monitoring using sensors is potentially a more effective and inexpensive alternative to current methods of sample collection and analysis. Gaseous components of a system are the most mobile and easiest to monitor. Continuous monitoring of soil gases such as oxygen, carbon dioxide, and contaminant vapors can provide important quantitative information regarding the progress of bioremediation efforts and the area of influence of air sparging or soil venting. Laboratory and field tests of a commercially available oxygen sensor show that the subsurface oxygen sensor provides rapid and accurate data on vapor phase oxygen concentrations. The sensor is well suited for monitoring gas flow and oxygen consumption in the vadose zone during air sparging and bioventing. The sensor performs well in permeable, unsaturated soil environments and recovers completely after being submerged during temporary saturated conditions. Calibrations of the in situ oxygen sensors were found to be stable after one year of continuous subsurface operation. However, application of the sensor in saturated soil conditions is limited. The three major advantages of this sensor for in situ monitoring arc as follows: (1) it allows data acquisition at any specified time interval; (2) it provides potentially more accurate data by minimizing disturbance of subsurface conditions; and (3) it minimizes the cost of field and laboratory procedures involved in sample retrieval and analysis.     

Thermal history of the Rio Muni (West Africa)–NE Brazil margins during continental breakup

We document the thermal record of breakup of the conjugate Rio Muni (West Africa) and NE Brazil margins using apatite fission track analysis, vitrinite reflectance data and stratigraphic observations from both margins. These results permit determination of the timing of four cooling episodes, and the temperature of samples at the onset of each episode. All samples are interpreted to have experienced higher temperatures in the geological past due to i) elevated basal heatflow (palaeogeothermal gradient in Rio Muni-1 well decaying from 58 °C/km during the Mid Cretaceous to 21.5 °C/km in the Late Cenozoic) and ii) progressive exhumation from formerly greater burial depth. A well constrained history of changing palaeogeothermal gradient allows for much more precise quantification of the thickness of eroded section (exhumation) than if a constant heatflow is assumed. Cooling episodes identified from the palaeotemperature data at 110–95 Ma (both margins) and 85–70 Ma (Rio Muni only) coincide with major unconformities signifying, respectively, the cessation of rifting (breakup) and compressional shortening that affected the African continent following the establishment of post-rift sedimentation (drift). The interval between these separate unconformities is occupied by allochthonous rafts of shallow-water carbonates recording gravitational collapse of a marginal platform. The rift shoulder uplift that triggered this collapse was enhanced by local transpression associated with the obliquely divergent Ascension Fracture Zone, and thermal doming due to the coeval St Helena and Ascension Plumes. The data also reveal a c.45–35 Ma cooling episode, attributed to deep sea erosion at the onset of Eo-Oligocene ice growth, and a c.15–10 Ma episode interpreted as the record of Miocene exhumation of the West African continental margin related to continent-wide plume development. Integration of thermal history methods with traditional seismic- and stratigraphy-based observations yields a dynamic picture of kilometre-scale fluctuations in base level through the breakup and early drift phases of development of these margins. Major unconformities at ocean margins are likely to represent composite surfaces recording not only eustasy, but also regional plate margin-generated deformation, local ‘intra-basinal’ reorganization, and the amplifying effect of negative feedbacks between these processes.