Phytoliths as indicators of pedogenesis and paleoenvironmental changes in the Brazilian cerrado

This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Variable vegetation cover and episodic sand movement on longitudinal desert sand dunes

Longitudinal (linear) sand dunes of the Simpson and Strzelecki dunefields in eastern central Australia present a paradox. Low levels of activity today stand in contrast to luminescence dating which has repeatedly shown deep deposits of sand on dune crests dating to within the late Holocene. In order to investigate the nature of dune activity in the Simpson–Strzelecki dunefield, vegetation and sand mobility were investigated by detailed vegetation survey and measurement of rippled area and loose sand depth of dunes at three sites along a climatic gradient. The response of both vegetation and sand movement to inter-annual climate variability was examined by repeat surveys of two sites in drought and non-drought conditions. Projected plant cover and plant + crust cover were found to have inverse linear relationships with rippled area and the area of deep loose sand. No relationship was found between these measures of sand movement and the plant frontal area index. A negative exponential relationship between equivalent mobile sand depth on dune surfaces and both vascular plant cover and vascular + crust cover was also found. There is no simple threshold of vegetation cover below which sand transport begins. Dunes with low perennial plant cover may form small dunes with slip faces leading to a positive feedback inhibiting ephemeral plant growth in wet years and accelerating sand transport rates. The linear dunefields are largely within the zone in which plant cover is sufficient to enforce low sand transport rates, and in which there is a strong response of vegetation and sand transport to inter-annual variation in rainfall. Both ephemeral plants (mostly forbs) and crust were found to respond rapidly to large (> 20 mm/month) rainfall events. On millennial time-scales, the level of dune activity is controlled by vegetation cover and probably not by fluctuations of wind strength. Land use or extreme, decadal time-scale, drought may destabilise dunes by removing perennial plant cover, accelerating wind erosion.     

Biological and Geochemical Record of Anthropogenic Impacts in Recent Sediments from Lake Pupuke, Auckland City, New Zealand

Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS ¹⁴C and ²¹⁰Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO₄ addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the ²¹⁰Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.     

A geochronological approach to understanding the role of solar activity on Holocene glacier length variability in the Swiss Alps

We present a radiocarbon data set of 71 samples of wood and peat material that melted out or sheared out from underneath eight presentday mid‐latitude glaciers in the Central Swiss Alps. Results indicated that in the past several glaciers have been repeatedly less extensive than they were in the 1990s. The periods when glaciers had a smaller volume and shorter length persisted between 320 and 2500 years. This data set provides greater insight into glacier variability than previously possible, especially for the early and middle Holocene. The radiocarbon‐dated periods defined with less extensive glaciers coincide with periods of reduced radio‐production, pointing to a connection between solar activity and glacier melting processes. Measured long‐term series of glacier length variations show significant correlation with the total solar irradiance. Incoming solar irradiance and changing albedo can account for a direct forcing of the glacier mass balances. Long‐term investigations of atmospheric processes that are in interaction with changing solar activity are needed in order to understand the feedback mechanisms with glacier mass balances.     

Lead, zinc, and antimony contamination of the Rio Chilco-Rio Tupiza drainage system, Southern Bolivia

An intense, but localized rainfall event in February 2003, led to the severe erosion and failure of a tailings disposal impoundment at the Abarόa Antimony Mine in southern Bolivia. The failure released approximately 5,500 m³ of contaminated tailings into the Rio Chilco-Rio Tupiza drainage system. The impacts of the event on sediment quality are examined and compared to contamination resulting from historic mining operations in the headwaters of the basin. Of primary concern are contaminated floodplain soils located along downstream reaches of the Rio Tupiza which were found to contain lead (Pb), zinc (Zn), and antimony (Sb) concentrations that locally exceed Canadian, German, and Dutch guidelines for agricultural use. Spatial patterns in sediment-borne trace metal concentrations, combined with Pb isotopic data, indicate that Pb, Zn, and Sb are derived from three tributary basins draining the Abarόa, Chilcobija, and Tatasi-Portugalete mining districts. Downstream of each tributary, geographical patterns in trace metal concentrations reflect local geomorphic changes throughout the drainage system. Trace metal concentrations within the Rio Chilco decrease rapidly downstream as a result of dilution by uncontaminated sediments and storage of metal enriched particles (e.g., sulfide minerals) in the channel bed as a result of ongoing aggradation. Storage in the floodplains is limited. These processes significantly reduced the dispersal and, thus, the relative environmental affects of tailings eroded from the Abarόa Mine during the 2003 flood. In contrast, storage of Pb, Zn, and Sb in floodplains along the Rio Tupiza is significant, the majority of which is derived from historic mining operations, particularly mining within the Tatasi-Portugalete district.