The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

Imaging the ramp–décollement geometry of the Chelungpu fault using coseismic GPS displacements from the 1999 Chi-Chi, Taiwan earthquake

We use coseismic GPS data from the 1999 Chi-Chi, Taiwan earthquake to estimate the subsurface shape of the Chelungpu fault that ruptured during the earthquake. Studies prior to the earthquake suggest a ramp–décollement geometry for the Chelungpu fault, yet many finite source inversions using GPS and seismic data assume slip occurred on the down-dip extension of the Chelungpu ramp, rather than on a sub-horizontal décollement. We test whether slip occurred on the décollement or the down-dip extension of the ramp using well-established methods of inverting GPS data for geometry and slip on faults represented as elastic dislocations. We find that a significant portion of the coseismic slip did indeed occur on a sub-horizontal décollement located at 8 km depth. The slip on the décollement contributes 21% of the total modeled moment release. We estimate the fault geometry assuming several different models for the distribution of elastic properties in the earth: homogeneous, layered, and layered with lateral material contrast across the fault. It is shown, however, that heterogeneity has little influence on our estimated fault geometry. We also investigate several competing interpretations of deformation within the E/W trending rupture zone at the northern end of the 1999 ground ruptures. We demonstrate that the GPS data require a 22- to 35-km-long lateral ramp at the northern end, contradicting other investigations that propose deformation is concentrated within 10 km of the Chelungpu fault. Lastly, we propose a simple tectonic model for the development of the lateral ramp.     

Formation of the regular satellites of giant planets in an extended gaseous nebula I: subnebula model and accretion of satellites

We model the subnebulae of Jupiter and Saturn wherein satellite accretion took place. We expect each giant planet subnebula to be composed of an optically thick (given gaseous opacity) inner region inside of the planet’s centrifugal radius (where the specific angular momentum of the collapsing giant planet gaseous envelope achieves centrifugal balance, located at rCJ ∼ 15R_J for Jupiter and rCS ∼ 22R_S for Saturn) and an optically thin, extended outer disk out to a fraction of the planet’s Roche-lobe (R_H), which we choose to be ∼R_H/5 (located at ∼150 R_J near the inner irregular satellites for Jupiter, and ∼200R_S near Phoebe for Saturn). This places Titan and Ganymede in the inner disk, Callisto and Iapetus in the outer disk, and Hyperion in the transition region. The inner disk is the leftover of the gas accreted by the protoplanet. The outer disk may result from the nebula gas flowing into the protoplanet during the time of giant planet gap-opening (or cessation of gas accretion). For the sake of specificity, we use a solar composition “minimum mass” model to constrain the gas densities of the inner and outer disks of Jupiter and Saturn (and also Uranus). Our model has Ganymede at a subnebula temperature of ∼250 K and Titan at ∼100 K. The outer disks of Jupiter and Saturn have constant temperatures of 130 and 90 K, respectively.Our model has Callisto forming in a time scale ∼10⁶ years, Iapetus in 10⁶-10⁷ years, Ganymede in 10³-10⁴ years, and Titan in 10⁴-10⁵ years. Callisto takes much longer to form than Ganymede because it draws materials from the extended, low density portion of the disk; its accretion time scale is set by the inward drift times of satellitesimals with sizes 300-500 km from distances ∼100R_J. This accretion history may be consistent with a partially differentiated Callisto with a ∼300-km clean ice outer shell overlying a mixed ice and rock-metal interior as suggested by Anderson et al. (2001), which may explain the Ganymede-Callisto dichotomy without resorting to fine-tuning poorly known model parameters. It is also possible that particulate matter coupled to the high specific angular momentum gas flowing through the gap after giant planet gap-opening, capture of heliocentric planetesimals by the extended gas disk, or ablation of planetesimals passing through the disk contributes to the solid content of the disk and lengthens the time scale for Callisto’s formation. Furthermore, this model has Hyperion forming just outside Saturn’s centrifugal radius, captured into resonance by proto-Titan in the presence of a strong gas density gradient as proposed by Lee and Peale (2000). While Titan may have taken significantly longer to form than Ganymede, it still formed fast enough that we would expect it to be fully differentiated. In this sense, it is more like Ganymede than like Callisto (Saturn’s analog of Callisto, we expect, is Iapetus). An alternative starved disk model whose satellite accretion time scale for all the regular satellites is set by the feeding of planetesimals or gas from the planet’s Roche-lobe after gap-opening is likely to imply a long accretion time scale for Titan with small quantities of NH₃ present, leading to a partially differentiated (Callisto-like) Titan. The Cassini mission may resolve this issue conclusively. We briefly discuss the retention of elements more volatile than H₂O as well as other issues that may help to test our model.     

Variable vegetation cover and episodic sand movement on longitudinal desert sand dunes

Longitudinal (linear) sand dunes of the Simpson and Strzelecki dunefields in eastern central Australia present a paradox. Low levels of activity today stand in contrast to luminescence dating which has repeatedly shown deep deposits of sand on dune crests dating to within the late Holocene. In order to investigate the nature of dune activity in the Simpson–Strzelecki dunefield, vegetation and sand mobility were investigated by detailed vegetation survey and measurement of rippled area and loose sand depth of dunes at three sites along a climatic gradient. The response of both vegetation and sand movement to inter-annual climate variability was examined by repeat surveys of two sites in drought and non-drought conditions. Projected plant cover and plant + crust cover were found to have inverse linear relationships with rippled area and the area of deep loose sand. No relationship was found between these measures of sand movement and the plant frontal area index. A negative exponential relationship between equivalent mobile sand depth on dune surfaces and both vascular plant cover and vascular + crust cover was also found. There is no simple threshold of vegetation cover below which sand transport begins. Dunes with low perennial plant cover may form small dunes with slip faces leading to a positive feedback inhibiting ephemeral plant growth in wet years and accelerating sand transport rates. The linear dunefields are largely within the zone in which plant cover is sufficient to enforce low sand transport rates, and in which there is a strong response of vegetation and sand transport to inter-annual variation in rainfall. Both ephemeral plants (mostly forbs) and crust were found to respond rapidly to large (> 20 mm/month) rainfall events. On millennial time-scales, the level of dune activity is controlled by vegetation cover and probably not by fluctuations of wind strength. Land use or extreme, decadal time-scale, drought may destabilise dunes by removing perennial plant cover, accelerating wind erosion.     

Multiscale characterization of a heterogeneous aquifer using an ASR operation

Heterogeneity in the physical properties of an aquifer can significantly affect the viability of aquifer storage and recovery (ASR) by reducing the recoverable proportion of low-salinity water where the ambient ground water is brackish or saline. This study investigated the relationship between knowledge of heterogeneity and predictions of solute transport and recovery efficiency by combining permeability and ASR-based tracer testing with modeling. Multiscale permeability testing of a sandy limestone aquifer at an ASR trial site showed that small-scale core data give lower-bound estimates of aquifer hydraulic conductivity (K), intermediate-scale downhole flowmeter data offer valuable information on variations in K with depth, and large-scale pumping test data provide an integrated measure of the effective K that is useful to constrain ground water models. Chloride breakthrough and thermal profiling data measured during two cycles of ASR showed that the movement of injected water is predominantly within two stratigraphic layers identified from the flowmeter data. The behavior of the injectant was reasonably well simulated with a four-layer numerical model that required minimal calibration. Verification in the second cycle achieved acceptable results given the model's simplicity. Without accounting for the aquifer's layered structure, high precision could be achieved on either piezometer breakthrough or recovered water quality, but not both. This study demonstrates the merit of an integrated approach to characterizing aquifers targeted for ASR.     

Geochemistry of suspended matter from the Baltic Sea 2. Results of bulk trace metal analysis by AAS

In 1984, on a transect covering the whole Baltic Sea and parts of the adjacent North Sea, 160 water samples were taken and analysed for their concentrations of particulate and dissolved metals. In addition, the suspended materials were investigated for their elemental bulk composition.The particulate fractions represented from about 5% (Cd, Cu and Ni) to 50% (Fe and Pb) of the total (particulate plus dissolved) concentrations. For some elements (Ba, Cd, Cu, Pb and Zn), the particulate matter from the surface microlayer was enriched with respect to those suspended materials taken from 0.2 m depth. This could reflect the atmospheric input of metal-rich aerosols. In anoxic deep waters, maximum contents of Zn (6400 μg g⁻¹), Cu (1330 μg g⁻¹) and Cd (12 μg g⁻¹) were observed in the particulate matter, indicating sulphidic forms. On the other hand, under oxic conditions the distribution coefficients (K_d) decreased with the water depth (Cd, Fe and Pb).Relative to global background levels, the particulate matter contained metal “excesses” amounting to more than 90% of the total contents (Cd, Mn, Pb and Zn). Automated electron probe X-ray microanalysis (EPXMA) revealed that the elemental composition of sediments is mainly governed by post-depositional processes of early diagenesis and is only weakly related to the composition of suspended matter in the overlying water body. For instance, in relation to surface mud sediments of the central Baltic net-sedimentation basins, Zn, Cd, Cu and Mn had 30–100% higher levels in the suspended materials. The general pattern of metal contents of particulate matter taken from 10 m depth on a transect between the Bothnian Bay and the North Sea were—possibly as a result of anthropogenic inputs—rather similar for Pb, Zn and Cu. For Fe and Mn, the distribution patterns along the transect were probably governed by the natural loading characteristics and by the biogeochemistry of those elements.     

Towards Real‐Time Geodemographics: Clustering Algorithm Performance for Large Multidimensional Spatial Databases

Geodemographic classifications provide discrete indicators of the social, economic and demographic characteristics of people living within small geographic areas. They have hitherto been regarded as products, which are the final “best” outcome that can be achieved using available data and algorithms. However, reduction in computational cost, increased network bandwidths and increasingly accessible spatial data infrastructures have together created the potential for the creation of classifications in near real time within distributed online environments. Yet paramount to the creation of truly real time geodemographic classifications is the ability for software to process and efficiency cluster large multidimensional spatial databases within a timescale that is consistent with online user interaction. To this end, this article evaluates the computational efficiency of a number of clustering algorithms with a view to creating geodemographic classifications “on the fly” at a range of different geographic scales.