Seasonal acceleration of the rate of total ozone decreases over Central Europe: impact of tropopause height changes

Total ozone data from some European stations have been analyzed to detect the ozone decrease in different seasons from 1979 to 1995. The differences between the winter–spring (December–March) and summer (May–August) total ozone means have decreased distinctly during the last three decades, by 10 Dobson Units per decade, showing that the winter–spring decrease is significantly stronger than the summer one. Applying a multiple regression model to the monthly means of tropopause height, positive trends in the summer and winter–spring seasons have been found, especially since 1979. This corresponds to the accelerating ozone decrease then. The possibility of using tropopause height variations as an indicator of dynamical variability in the total ozone trend model is discussed. The total ozone response to the changes of tropopause height seems to be independent of timescale over which the tropopause-total ozone relationship has been examined (month-to-month, interannual). The total ozone trends, as well as the accelerated rate of ozone decrease since 1979 in the winter–spring and summer seasons, respectively, are reduced by about 0.5–1% per decade after inclusion of the tropopause height effect on the ozone model.     

Configuring Detection Wells Near Landfills

A graphical method was devised for designing contaminant detection monitoring networks in aquifers. The approach eliminates bias in detection efficiency among well pairs, thereby improving the overall efficiency of a ground water monitoring network. In the equidistant configurations derived by the graphical approach, all wells are located the same distance from a landfill, but the distance is measured parallel to ground water flow, Measured perpendicular to ground water flow, there is also an equal spacing between wells in an equidistant network. A simulation model was used to compare an equidistant network to a peripheral monitoring configuration, in which wells were spaced evenly along the downgradient boundaries of a landfill. The equidistant network yielded a 12.4% higher detection efficiency and also facilitated earlier release detection. In practice, the graphical approach that yields equidistant configurations can be used to identify candidate monitoring networks to detect potential releases from landfills.     

The dynamics of xenolith assimilation

Xenolith assimilation has been simulated with experiments involving melting wax spheres into hot water and aqueous solutions and characterised by a theoretical analysis. Both the cases of neutrally buoyant stationary spheres and spheres sinking through the hot host fluid are examined. Melt generated on a sphere's surface flows (compositional convection) in two regimes; as a sheet over one hemisphere and then detaching as finger plumes from the other. Positional variations in the melting rate are dominantly controlled by differences in the melt layer thickness which influence the thermal gradient and heat flux across the layer. The theoretical model predicts melt layer thicknesses and the heat flux from the surrounding fluid. Calculated melting rates agree well with experimental measurements. Partial melting of non-eutectic compositions produces a layer of crystal-melt mush at the xenolith's surface. The theoretical analysis is extended to account for variation in rheological properties across the mush layer. When stoped into typical magmas, xenoliths of common continental crust lithologies are predicted to melt at rates in the order of 2 mm/hour. Thicknesses of the mobile mush layer around xenoliths are predicted to be typically a few centimetres. Relatively mafic lithologies can melt quicker than silicic compositions because, although they are typically more refractory, their lower melt viscosities result in thinner mush layers and so higher heat fluxes. Especially quick melting of water-saturated lithologies occurs as a consequence of both the reduction in melting temperatures and melt viscosities. Due to hot ambient conditions in the lower continental crust the assimilation of xenoliths into underplated basaltic magma can be very rapid. For granulites and mafic-granulites the predicted melting rates are up to 17 mm/hour. Fast rates of melting and efficient mixing of melt into the host magma indicate that assimilation of xenoliths will have a significant influence on the compositional and thermal evolution of magmas. Received: 7 November 1996 / Accepted: 5 January 1998     

Models of corundum origin from alkali basaltic terrains: a reappraisal

Corundums from basalt fields, particularly in Australia and Asia, include a dominant blue-green-yellow zoned “magmatic” suite (BGY suite) and subsidiary vari-coloured “metamorphic” suites. The BGY corundums have distinctive trace element contents (up to 0.04 wt% Ga₂O₃ and low Cr/Ga and Ti/Ga ratios <1). Different melt origins for BGY corundums are considered here from their inclusion and intergrowth mineralogy, petrologic associations and tectonic setting. Analysed primary inclusion minerals (over 100 inclusions) cover typical feldspars, zircon and Nb-Ta oxides and also include hercynite-magnetite, gahnospinel, rutile-ilmenite solid solution, calcic plagioclase, Ni-rich pyrrhotite, thorite and low-Si and Fe-rich glassy inclusions. This widens a previous inclusion survey; New England, East Australia corundums contain the most diverse inclusion suite known from basalt fields (20 phases). Zircon inclusion, intergrowth and megacryst rare earth element data show similar patterns, except for Eu which shows variable depletion. Temperature estimates from magnetite exsolution, feldspar compositions and fluid inclusion homogenization suggest that some corundums crystallized between 685–900 °C. Overlap of inclusion Nb, Ta oxide compositions with new comparative data from niobium-yttrium-fluorine enriched granitic pegmatites favour a silicate melt origin for the corundums. The feasibility of crystallizing corundum from low-volume initial melting of amphibole-bearing mantle assemblages was tested using the MELTS program on amphibole-pyroxenite xenolith chemistry from basalts. Corundum appears in the calculations at 720–880 °C and 0.7–1.1 GPa with residual feldspathic assemblages that match mineral compositions found in corundums and their related xenoliths. A model that generates melts from amphibole-bearing lithospheric mantle during magmatic plume activity is proposed for BGY corundum formation. Received: 3 January 1997 / Accepted: 8 July 1998     

Palaeostress analysis of the northern Nijar and southern Vera basins: constraints for the Neogene displacement history of major strike-slip faults in the Betic Cordilleras, SE Spain

This paper presents the results of a detailed structural analysis of the northern Nijar and southern Vera basins with special emphasis on the evolution of the regional stress field and the associated timing of movement of the Serrata, Gafarillos and Palomares strike-slip fault zones. These major fault zones control the Neogene deformation of the SE Internal Betic Cordilleras in Spain. Detailed stress analysis on Neogene sediments of the Vera and Nijar basins shows a strike-slip regime with NW–SE-oriented subhorizontal maximum principal stress (σ₁) during Tortonian and earliest Messinian times. Under the influence of this stress field, dextral displacement along the N090E-trending Gafarillos fault zone resulted in deformation of the sediments of the southern Sorbas and northeastern Nijar basins. During the early Messinian a clock-wise rotation of the stress field occurred. Stress analysis in rocks with late–early Messinian up to Quaternary ages in the Nijar and Vera basins indicates a strike-slip regime with N–S-oriented subhorizontal maximum principal stress (σ₁). Under the influence of this stress field the main activity along the N010E-striking Palomares strike-slip fault zone took place, resulting in deformation of the Neogene sediments of the southeastern Vera basin and culminating in a maximum sinistral displacement of more than 20 km. At the same time the stress field was not suitably oriented to exert a large shear component on the Gafarillos fault zone, which activity ended after the earliest Messinian. Fault and outcrop patterns of syntectonic Neogene sediments in the Vera basin show that displacement along the Palomares fault zone decreased at the end of the Middle Miocene although minor displacement phases may still have occurred during the Late Miocene and possibly even Pliocene. From the Middle Miocene onward, deformation in the Nijar basin was controlled by sinistral displacement along the N040E-trending Serrata strike-slip fault zone.     

On the use of microtremor recordings in seismic microzonation

Experimental methods involving microtremor recordings are useful for determining site effects in regions of moderate seismic activity where ground motion records are few, and in urban or industrial contexts where the noise level is high. The aim of this study is to establish a microzonation by using the Nogoshi–Nakamura method,[1, 2] a simple experimental technique based on microtremor recordings. Since the physical phenomena underlying the method are only partially understood, the spectral responses obtained cannot be used alone. We, therefore, complete our experimental results by comparing them with the solutions of a one-dimensional numerical simulation (SHAKE91).[3, 4] The experimental programme was carried out on a plain near the Rhone Delta (South of France). H/V spectral ratios were calculated at 137 noise measurement points. In addition, we were able to compute the numerical transfer functions from soil columns defined by geotechnical characteristics inside the studied region. A comparison of the results obtained by the experimental and numerical methods showed that the fundamental frequencies are in good agreement, but that the amplitudes obtained by the two techniques are sometimes different. The analysis of H/V spectral ratios enabled us to establish maps to characterize the region: a resonance frequency map and maps of amplification levels as a function of frequency range, leading to a seismic microzonation for the whole of the region.     

The Injection, Acceleration, and Dynamical Influence of Interstellar Pickup Ions at the Solar Wind Termination Shock

The interaction of interstellar pickup ions with the solar wind termination shock is reviewed and assessed. The pickup ions mass and momentum load the wind and increase its pressure, effects which decrease the strength of the shock and its distance from the Sun. The pickup hydrogen may contribute substantially to the "reflected" ion population, which should provide most of the dissipation at the supercritical quasi-perpendicular shock. A fraction of the pickup ions impinging on the shock is "injected" into the process of diffusive shock acceleration to form the anomalous cosmic ray component. An injection mechanism which accounts for the apparent absence of solar wind ions in the anomalous component is "shock surfing", in which pickup ions which approach the shock slowly may be trapped between the upstream Lorentz force and the shock potential and accelerated in the motional electric field beyond the energy threshold for diffusive shock acceleration. However, the simplest interpretation of shock surfing would favor less massive pickup ion species, in contradiction with Voyager observations of anomalous component composition. A possible extension of the shock surfing mechanism is considered, as well as other injection mechanisms. Finally, the pressure of the anomalous component may modify the structure of the termination shock, which in turn may influence injection rates. This revised version was published online in July 2006 with corrections to the Cover Date.     

The stellar content of a spiral arm of NGC 4321

The effects of the passage of a spiral arm through the disc of the giant Virgo Sc galaxy NGC 4321 are investigated with Hubble Space Telescope WFPC2 images in two colours. Concentrating on a portion of the southern spiral arm of NGC 4321, we have applied a new program to solve for the star formation histories in the arm and interarm regions separately. The observational uncertainties and the variable crowding across the spiral arm are taken into account using the results of artificial star tests. In the interarm regions the data are consistent with a constant star formation rate for the last 50 Myr while the stars in the arm region show a star formation rate four times larger than in the interarm regions in the last 5 Myr.     

Light curves of SN 1998A and comparison with similar unusual SNe

Following the proposal by Damineli that the central object of Eta Carinae may be an early-type binary, we perform numerical simulations of the X-ray emission from colliding stellar winds. A synthetic light curve has been generated which qualitatively agrees with the recent X-ray variability, and provides further support for the binary model. In particular, the model predicts a rise in the observed X-ray emission towards periastron, followed by a sharp drop and subsequent recovery. This is indeed what is seen in the RXTE light curve, although some problems concerning the X-ray spectrum at periastron still need to be explained. The simulations suggest that the width of the periastron dip will provide strong constraints on the binary and stellar wind properties of the components of Eta Car.     

The restricted stability of osumilite under hydrous conditions in the system K2O-MgO–Al2O3–SiO2–H2O

Osumilite_ss was synthesized as a single phase product in the model system K₂O-MgO-Al₂O₃-SiO₂ at 800° C/ 0.5 Kbar water pressure and at 800° to 840° C/1.0 Kbar total pressure with 0.3 in the gas phase. The experimentally determined solid solubility range of synthetic osumilites can be expressed by the formula KMg₂(Al_3-xMg_x) (Al_2–xSi_10+x)O₃₀ with 0x0.4. A survey of sixteen chemical analyses of natural osumilites from eleven occurrences shows a solid solubility characterized by 0x0.6. Reversed stability experiments for the synthetic osumilite KMg₂(Al_2.75Mg_0.25)(Al_1.75Si_10.25)O₃₀ determined at water pressure equal to total pressure demonstrate its restriction to water pressures below 0.8 Kbar (at 0.5 Kbar, the stability range is between 765° and 800° C). At the lower thermal stability limit osumilite+H₂O vapor break down to cordierite+K feldspar+phlogopite_ss+quartz, at the higher one to cordierite+K feldspar+phlogopite+liquid. Reduction of water fugacity will expand the stability field largely by shifting the lower and higher thermal stability limits to lower and higher temperatures, respectively. The dependence of osumilite stability on water fugacity makes osumilite a sensitive indicator mineral for dry conditions in rocks formed at total pressures higher than about 0.8 Kbar.