Morphology of the Itapeva to Tramandai transgressive dunefield barrier system and mid‐ to late Holocene sea level change

The surface morphology of the transgressive dunefield barrier extending from Itapeva to Tramandai along the northern littoral of Rio Grande do Sul, is examined and an attempt is presented to link morphological changes across the barrier to Holocene sea level changes. The 4·5 km wide Holocene barrier displays two typical morphologies: an inner part dominated by large‐scale, continuous alongshore, overlapping dunefield phases comprising sand sheets, dunes, deflation plains and precipitation ridges; and an outer part dominated by discontinuous, medium‐ to small‐scale, triangular to lobate transgressive dunefield phases, cut by both active and relict (palaeo‐) creeks or washouts. Holocene sea level in the region rose to c. +1 to +3 m above present reaching a maximum around 5100 years bp and then progressively fell to the present level. We argue that the effect on barrier development was to suppress the development of a drainage system during the rising and maximum stages, and encourage the development of an organized drainage system in the form of regularly spaced washouts during the falling period, and that this change in sea level from rising to falling therefore produced the large‐scale differences in barrier morphology. Copyright © 2006 John Wiley & Sons, Ltd.     

Comparison of soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters

The choice of sampling method for soil solution is of great importance. In this paper soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters have been studied with the purpose of investigating systematic differences between them. The samples were taken at 4 depths from an acidified forest soil as well as from adjacent lime and ash treated soils. A centrifugation drainage method was compared with two types of suction lysimeters (‘Rhizon’ and ‘Prenart’) and zero-tension lysimeters. About half of the 27 variables measured showed a significant difference between the sampling methods used. Typically the centrifuged samples had lower pH (4.0 vs. 4.4), Ca (21 μM vs. 30 μM) and Mg (25 μM vs. 34 μM) concentrations and higher Cl (330 μM vs. 230 μM) and DOC (4.4 mM vs. 3.2 mM) concentrations than the Rhizon lysimeters. Also the other lysimeters showed significant differences compared to the centrifuged samples for about half the number of analytes. Centrifuged samples had higher concentrations of all analytes except NO₃ and PO₄ compared to zero-tension lysimeters and also for all analytes except NO₃ and Al compared to Prenart lysimeters. Among the environmental factors considered depth showed an influence to some extent, while sampling occasion had a great significant impact on the difference between the centrifugation method and the Rhizon lysimeters. Factors like individual pits or soil treatment did not show any influence on the difference between the methods.     

Outgoing long wave radiation variability from IR satellite data prior to major earthquakes

Our analysis of the continuous outgoing long wave earth radiation (OLR) indicates anomalous variations prior to a number of medium to large earthquakes. The most recent analysis of OLR is from the M9.0 Sumatra Andaman Islands mega trust event. We compared the reference fields for December 2001 to 2004 and found OLR anomalous values, > 80 W/m², (2σ) within the epicentral area on Dec 21, 2004, 5 days before the event. We used the NOAA/IR daily (one degree) and monthly (two and half degree) gridded data to differentiate between the global and seasonal variability and the transient local anomalies. The cause of such anomalies is not fully understood; one possible explanation is the existence of thermal outgoing radiation as a result of near ground air ionization and latent heat change due to change of air humidity and temperature. This phenomenon is hypothesized to be part of a relationship between tectonic stresses, electrochemical and thermodynamic processes in the atmosphere and increasing mid IR flux, all part of a family of electromagnetic (EM) phenomena related to earthquake activity. The time scale of the observed variations is a few weeks before the onset of the seismic event. In comparison with several years of data, the observed time-series preceding the earthquake had unusually high OLR. The OLR anomaly corresponds to a large area of ground coverage and coincides with the main epicentral zone. The significance of these observations is explored using data from most recent East Asian earthquake swarm of December 2004 and three other earthquakes.     

Modeled Sverdrup flow in the North Atlantic from 11 different wind stress climatologies

In studies of large-scale ocean dynamics, often quoted values of Sverdrup transport are computed using the Hellerman–Rosenstein wind stress climatology. The Sverdrup solution varies, however, depending on the wind set used. We examine the differences in the large-scale upper ocean response to different surface momentum forcing fields for the North Atlantic Ocean by comparing the different Sverdrup interior/Munk western boundary layer solutions produced by a 1/16° linear numerical ocean model forced by 11 different wind stress climatologies. Significant differences in the results underscore the importance of careful selection of a wind set for Sverdrup transport calculation and for driving nonlinear models. This high-resolution modeling approach to solving the linear wind-driven ocean circulation problem is a convenient way to discern details of the Sverdrup flow and Munk western boundary layers in areas of complicated geometry such as the Caribbean and Bahamas. In addition, the linear solutions from a large number of wind sets provide a well-understood baseline oceanic response to wind stress forcing and thus, (1) insight into the dynamics of observed circulation features, by themselves and in conjunction with nonlinear models, and (2) insight into nonlinear model sensitivity to the choice of wind-forcing product.The wind stress products are evaluated and insight into the linear dynamics of specific ocean features is obtained by examining wind stress curl patterns in relation to the corresponding high-resolution linear solutions in conjunction with observational knowledge of the ocean circulation. In the Sverdrup/Munk solutions, the Gulf Stream pathway consists of two branches. One separates from the coast at the observed separation point, but penetrates due east in an unrealistic manner. The other, which overshoots the separation point at Cape Hatteras and continues to flow northward along the continental boundary, is required to balance the Sverdrup interior transport. A similar depiction of the Gulf Stream is commonly seen in the mean flow of nonlinear, eddy-resolving basin-scale models of the North Atlantic Ocean. An O(1) change from linear dynamics is required for realistic simulation of the Gulf Stream pathway. Nine of the eleven Sverdrup solutions have a C-shaped subtropical gyre, similar to what is seen in dynamic height contours derived from observations. Three mechanisms are identified that can contribute to this pattern in the Sverdrup transport contours. Along 27°N, several wind sets drive realistic total western boundary current transport (within 10% of observed) when a 14 Sv global thermohaline contribution is added (COADS, ECMWF 10 m re-analysis and operational, Hellerman–Rosenstein and National Centers for Environmental Prediction (NCEP) surface stress re-analysis), a few drive transport that is substantially too high (ECMWF 1000 mb re-analysis and operational and Isemer–Hasse) and Fleet Numerical Meteorology and Oceanography Center (FNMOC) surface stresses give linear transport that is slightly weaker than observed. However, higher order dynamics are required to explain the partitioning of this transport between the Florida Straits and just east of the Bahamas (minimal in the linear solutions vs. 5 Sv observed east of the Bahamas). Part of the Azores Current transport is explained by Sverdrup dynamics. So are the basic path of the North Atlantic Current (NAC) and the circulation features within the Intra-Americas Sea (IAS), when a linear rendition of the northward upper ocean return flow of the global thermohaline circulation is added in the form of a Munk western boundary layer.     

Assessment of the ecological quality status of soft-bottoms in Reunion Island (tropical Southwest Indian Ocean) using AZTI marine biotic indices

The ability of the two synthetic marine biotic indices, AMBI and M-AMBI, to account for changes in the ecological quality of coastal soft bottoms of Reunion Island according to disturbances was assessed from macrobenthic samples collected in five sectors between 1994 and 2004. Samples were collected under non-perturbed conditions and at two sites subjected to heavy organic enrichment. Both indices are based on a classification of macrofauna into ecological groups (EG), and their transfer to tropical waters required some adaptations. These indices proved efficient in detecting a degradation of habitat quality. Their use resulted in the classification of all sites sampled between 1996 and 1998 as "good" or "high". M-AMBI nevertheless tended to result in the attribution of a slightly worse ecological quality status than AMBI. Together with an update of the EG species list for the Indian Ocean area, our results support the extension of both indices for the assessment of tropical soft bottoms.     

Organic matter fluxes and marsh stability in a rapidly submerging estuarine marsh

We studied organic matter cycling in two Gulf Coast tidal, nonsaline marsh sites where subsidence causes marine intrusion and rapid submergence, which mimics increased sea-level rise. The sites experienced equally rapid submergence but different degrees of marine intrusion. Vegetation was hummocked and much of the marsh lacked rooted vegetation. Aboveground standing crop and production, as measured by sequential harvesting, were low relative to other Gulf CoastSpartina patens marshes. Soil bulk density was lower than reported for healthyS. alterniflora growth but that may be unimportant at the current, moderate sulfate levels. Belowground production, as measured by sequential harvesting, was extremely fast within hummocks, but much of the marsh received little or no belowground inputs. Aboveground production was slower at the more saline site (681 g m^?2 yr^?1) than at the less saline site (1,252 g m^?2 yr^?1). Belowground production over the entire marsh surface averaged 1,401 g m^?2 yr^?1 at the less saline site and 585 g m^?2 yr^?1 at the more saline site. Respiration, as measured by CO₂ emissions in the field and corrected for CH₄ emissions, was slower at the less saline site (956 g m^?2 yr^?1) than at the more saline site (1,438 g m^?2 yr^?1), reflecting greater contributions byS. alterniflora at the more saline site which is known to decompose more rapidly thanS. patens. Burial of organic matter was faster at the less saline site (796 g m^?2 yr^?1) than at the more saline site (434 g m^?2, yr^?1), likely in response to faster production and slower decomposition at the less saline site. Thus vertical accretion was faster at the less saline site (1.3 cm yr^?1) than at the more saline site (0.85 cm yr^?1); slower vertical accretion increased flooding at the more saline site. More organic matter was available for export at the less saline site (1,377 g m^?2 yr^?1) than at the more saline site (98 g m^?2 yr^?1). These data indicated that organic matter production decreased and burial increased in response to greenhouse-like conditions brought on by subsidence. *** DIRECT SUPPORT *** A01BY069 00016     

Particulate content of savanna fire emissions

As part of the FOS-DECAFE experiment at Lamto (Ivory Coast) in January 1991, various aerosol samples were collected at ground level near prescribed fires or under local background conditions, to characterize the emissions of particulate matter from the burning of savanna vegetation. This paper deals with total aerosol (TPM) and carbon measurements. Detailed trace element and polycyclic hydrocarbon data are discussed in other papers presented in this issue.Near the fire plumes, the aerosols from biomass burning are primarily of a carbonaceous nature (C%70% of the aerosol mass) and consist predominantly of submicron particles (more than 90% in mass.) They are characterized by their organic nature (black to total carbon ratio Cb/Ct in the range 3–20%) and their high potassium content (K/Cb0.6). These aerosols undergo aging during their first minutes in the atmosphere causing slight alterations in their size distribution and chemical composition. However, they remain enriched in potassium (K/Cb=0.21) and pyrene, a polycyclic aromatic hydrocarbon, such that both of these species may be used as tracers of savanna burning aerosols. We show that during this period of the year, the background atmosphere experiences severe pollution from both terrigenous sources and regional biomass burning (44% of the aerosol). Daynight variations of the background carbon concentrations suggest that fire ignition and spreading occur primarily during the day. Simultaneous TPM and CO₂ real-time measurements point to a temporal and spatial heterogeneity of the burning so that the ratio of the above background concentrations (TPM/CO₂) varies from 2 to 400 g/kg C. Smoldering processes are intense sources of particles but particulate emissions may also be important during the rapidly spreading heading fires in connection with the generation of heavy brown smoke. We propose emission factor values (EF) for aerosols from the savanna biomass burning aerosols: EF (TPM)=11.4±4.6 and 69±25 g/kg C_{dry plant} and EF(Ct)=7.4±3.4 and 56±16 g C/kg C_{dry plant} for flaming and smoldering processes respectively. In these estimates, the range of uncertainty is mostly due to the intra-fire variability. These values are significantly lower than those reported in the literature for the combustion of other types of vegetation. But due to the large amounts of vegetation biomass being burnt in African savannas, the annual flux of particulate carbon into the atmosphere is estimated to be of the order of 8 Tg C, which rivals particulate carbon emissions from anthropogenic activities in temperate regions.     

The fusion crust of the Winchcombe meteorite: A preserved record of atmospheric entry processes

Fusion crusts form during the atmospheric entry heating of meteorites and preserve a record of the conditions that occurred during deceleration in the atmosphere. The fusion crust of the Winchcombe meteorite closely resembles that of other stony meteorites, and in particular CM2 chondrites, since it is dominated by olivine phenocrysts set in a glassy mesostasis with magnetite, and is highly vesicular. Dehydration cracks are unusually abundant in Winchcombe. Failure of this weak layer is an additional ablation mechanism to produce large numbers of particles during deceleration, consistent with the observation of pulses of plasma in videos of the Winchcombe fireball. Calving events might provide an observable phenomenon related to meteorites that are particularly susceptible to dehydration. Oscillatory zoning is observed within olivine phenocrysts in the fusion crust, in contrast to other meteorites, perhaps owing to temperature fluctuations resulting from calving events. Magnetite monolayers are found in the crust, and have also not been previously reported, and form discontinuous strata. These features grade into magnetite rims formed on the external surface of the crust and suggest the trapping of surface magnetite by collapse of melt. Magnetite monolayers may be a feature of meteorites that undergo significant degassing. Silicate warts with dendritic textures were observed and are suggested to be droplets ablated from another stone in the shower. They, therefore, represent the first evidence for intershower transfer of ablation materials and are consistent with the other evidence in the Winchcombe meteorite for unusually intense gas loss and ablation, despite its low entry velocity.     

Simulating Stable Isotope Ratios in Plumes of Groundwater Pollutants with BIOSCREEN‐AT‐ISO

BIOSCREEN is a well‐known simple tool for evaluating the transport of dissolved contaminants in groundwater, ideal for rapid screening and teaching. This work extends the BIOSCREEN model for the calculation of stable isotope ratios in contaminants. A three‐dimensional exact solution of the reactive transport from a patch source, accounting for fractionation by first‐order decay and/or sorption, is used. The results match those from a previously published isotope model but are much simpler to obtain. Two different isotopes may be computed, and dual isotope plots can be viewed. The dual isotope assessment is a rapidly emerging new approach for identifying process mechanisms in aquifers. Furthermore, deviations of isotope ratios at specific reactive positions with respect to “bulk” ratios in the whole compound can be simulated. This model is named BIOSCREEN‐AT‐ISO and will be downloadable from the journal homepage.