Some Biases in Sampling Multilevel Piezometers for Volatile Organics

Multilevel piezometers are cost-effective monitoring devices for determining the three-dimensional distribution of solutes in ground water. Construction includes flexible tubing (plastic or Teflon®). Their sampling is subject to a number of'potential biases, particularly: (1) losses of volatile organic solutes via volatilization, (2) sorption onto the flexible tubing of the piezometers, (3) leaching of organics from this tubing, and (4) collection of unrepresentative samples due to inadequate piezometer flushing. It is shown that these biases are minimal or are easily controlled in most situations.
Another source of bias has been recognized. Organic solutes present in ground water above the screened level can penetrate the flexible plastic or Teflon tubing and contaminate the sampled water being drawn through this tubing. Laboratory tests and field results indicate this transmission causes low organic contaminant concentrations to be erroneously attributed to ground water which is free of such contaminants. The transmitted organics apparently desorb from the plastic tubing during flushing of even 40 piezometer volumes.
Recognition of this transmission problem provides for a better interpretation of existing organic contaminant distribution data. Caution is advised when considering the use of these monitoring devices in organic solute contaminant studies.     

Stable isotope compositions and water contents of boninite series volcanic rocks from Chichi-jima, Bonin Islands, Japan

Measurements of stable isotope compositions and water contents of boninite series volcanic rocks from the island of Chichi-jima, Bonin Islands, Japan, confirm that a large amount (1.6–2.4 wt.%) of primary water was present in these unusual magmas. An enrichment of 0.6‰ in¹⁸O during differentiation is explained by crystallization of¹⁸O-depleted mafic phases. Silicic glasses have elevated δ¹⁸O values and relatively low δD values indicating that they were modified by low-temperature alteration and hydration processes. Mafic glasses, on the other hand, have for the most part retained their primary isotopic signatures since Eocene time. Primary δD values of −53 for boninite glasses are higher than those of MORB and suggest that the water was derived from subducted oceanic lithosphere.     

Isotopic study of the Manaslu granite (Himalaya,Nepal): inferences on the age and source of Himalayan leucogranites

A detailed isotopic study of the Manaslu leucogranite was carried out. A U-Pb age of 25 Ma and a whole rock Rb-Sr age isochron of 18 Ma were obtained, suggesting that the magmatic activity lasted at least 7 Ma. Initial Sr isotopic ratios are very high (0.740 to 0.760) and initial Nd isotopic ratios are low ( _Nd ⁱⁿ : –13 to –16), and they show the existence of large isotopic variations even at the metre scale. These are not the result of perturbations by fluids but rather they reflect the initial isotopic heterogeneity of the source material which has not been obliterated by magmatic processes (e.g. fusion, mixing by convection). These results also support the crustal origin of this leucogranite. The Tibetan slab paragneisses, whose Sr and Nd isotopic ratios are very similar to those of the granite at an age of 20 Ma, are the most probable parental material. Nd model ages for both the leucogranite and the gneisses are in the range 1.5–2 Ga. A model of formation of the Manaslu granite by coalescence of different batches of magma is in agreement with the present data.     

Le massif granitique de Lesponne (Hautes Pyrénées): Un exemple de massif plutonique hercynien à mise en place diapirique syncinématique

Résumé Le massif plutonique de Lesponne est un petit complexe de granitoÏdes calco-alcalins affleurant au coeur d'un important dÔme structural, au sein d'un encaissant micaschisteux ordovicien surmonté par des formations calcaréo-pélitiques dévoniennes. A partir de l'étude structurale du massif et de son encaissant d'où ressortent le parallélisme entre la forme allongée du massif et les mégastructures plissées hercyniennes, la continuité entre la foliation des granitoÏdes et la schistosité hercynienne majeure de l'encaissant, la zonation de la déformation de part et d'autre du contact massif encaissant, la simultanéité entre le thermométamorphisme et la déformation développés autour du massif, le massif de Lesponne est interprété comme un corps intrusif dont la mise en place diapirique est synchrone de la déformation hercynienne majeure.

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The Lesponne plutonic massif is a small complex of calcalkaline granitoids cropping out in the core of an important structural dome, within Ordovician micaschists covered by Siluro-Devonian calc-pelitic formations. The structural study of the massif and its country rocks shows that: 1) the long axis of the massif tends to be parallel to the main Hercynian folds; 2) the foliation of the granitoids pass in continuity to the major Hercynian cleavage of the enclosing rocks; 3) the zonation of the strain in the massif and its enclosing rocks is parallel to the envelope of the pluton and 4) the contact metamorphism was synchronous with the main Hercynian deformation. This leads to interpret the Lesponne massif as an intrusive stock diapirically emplaced during the main Hercynian deformation.

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Zusammenfassung Der Pluton von Lesponne ist ein kleiner Komplex kalkalkalischer granitischer Gesteine im Zentrum einer bedeutenden Domstruktur. Er ist umgeben von ordovizischen Glimmerschiefern und wird überlagert von einer kalkigtonigen Devonabfolge. Strukturelle Untersuchungen im Granitmassiv und in den benachbarten Randbereichen erbrachten folgende Ergebnisse: Parallelität der Längsachse des Massivs und der varizischen Gro\faltenstruktur, Fortsetzung der varisszischen Hauptschieferung der Randgesteine ins Massiv in Form einer Schieferung zonare Anordnung der Deformation beiderseits des Kontaktes zwischen dem Massiv und den Randgesteinen, Gleichzeitigkeit von Thermometamorphose und Deformation der Randgesteine in der Umgebung des Massivs. Daraus lä\t sich ableiten, da\ das Massiv von Lesponne einen Intrusivkörper darstellt, dessen diapirische Platznahme synchron mit der variszischen Hauptdeformation erfolgte.

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Lesponne (Hautes Pyrénées) - , . - . : ; ; . . , Lesponne , .

     

The ilmenite/titano-magnetite assemblage: kinetics of re-equilibration

Compositions of coexisting ilmenite and titano-magnetite commonly have been used to establish the conditions of formation for igneous and metamorphic rocks (Buddington-Lindsley geothermometer/oxybarometer). Temperatures so determined for some rocks are lower than might be expected for magmatic crystallization. These low temperatures are the result of re-equilibration of the Fe-Ti oxides during slow cooling. This process is one in which titano-magnetites are oxidized and ilmenites are reduced upon cooling along a buffer curve or in the presence of a fluid of constant composition. Textural studies indicate that the reduction of the ilmenite-hematite phase may be the slower reaction consequently, the rate-controlling step of the re-equilibration.The kinetics of the reduction reactions in the two-phase region between the joins for the ilmenite-hematite and magnetite-ulvöspinel solid solution series were studied by thermogravimetric analysis at controlledf_O2. With experiments conducted near the Ni/NiO and QFM buffers, annealed ilmenite(ss) synthetic charges were reduced isothermally. The temperature range for the experiments was 900–1250°C, with total gas-flow rates of 0.35 and 1.0 cm/s. Kinetic data were collected by measuring the weight change during each experiment as a function of time. Additionally, a cooling-rate (0.5°C/hr) experiment was conducted near the QFM buffer from 1150 to 985°C starting with an ilmenite-saturated spinel phase.At 1200°C and 0.35 cm/s flow rate, the reaction mechanism is an interfacial process where mass transport of the reacting gases is the rate-controlling step. In isothermal experiments at 1100°C and lower, diffusion of reactants through a solid product layer was the controlling mechanism. The activation energy for this diffusion process is 59±6 kcal/mole. Significant enhancement of diffusion occurs along grain boundaries.Although the individual phases may re-equilibrate internally upon cooling, the Fe-Ti contents must remain unchanged for proper use of this mineral indicator-i.e. no external re-equilibration. It is imperative that the kinetics of the situation be appreciated. These preliminary kinetic experiments indicate that extreme caution must be exercised when applying this ilmenite/titano-magnetite geothermometer/oxybarometer. These phases may only truly “quench” in the parameters of formation in the case of certain hypabyssal and extrusive occurrences     

The response of the ‘green revolution’ to climatic variability

The purpose of this research is to assess the climatic sensitivity of high yielding variety (‘HYV’) ‘green revolution’ wheat. Improved multiple regression models were constructed for yields in India and Sonora, Mexico — the two most intensively planted regions in the world. After isolating the most important climatic predictors (which, not surprisingly, are total rainfall over the irrigation basins), the models were reduced to the pre-HYV period, and then re-run with successively more years of HYV input. This test indicated that increased adoption of the HYV package is associated with a significant increase in yield sensitivity to the most important climatic determinants of yield. To serve as a control, the U.S. Winter Wheat region was also modelled with a similar method. Overall, there is no significant increase in yield sensitivity to climate during the same period that HYV's were adopted in Mexico and India. Assuming that there is no change in overall climatic variability, this study indicates that production will nonetheless become more variable, particularly as HYV culture is expanded. Ironically, countries with rapidly expanding populations, that rely increasingly on HYV's, will experience the most significant fluctuations.     

Nutrient pore water chemistry,Great Bay,New Hampshire: Benthic fluxes

Benthic fluxes of C, N, P and Si have been measured at two sites in Great Bay Estuary, New Hampshire. Higher fluxes of reactive phosphate, nitrate and reactive silicate were observed at the site where bioturbation is known to occur and the fluxes of NH₄ ⁺, PO₄ ^?3 and reactive silicate at this location were from 3 to 6 times higher than that calculated by simple pore water diffusion models. *** DIRECT SUPPORT *** A01BY019 00010     

Sulphur uptake by salt grasses,mangroves, and seagrasses in anaerobic sediments

Stable sulfur isotope analyses show that rooted estuarine plants growing in anoxic sediments incorporate substantial amounts of ³⁴S-depleted sulfides, or oxidation products thereof. In roots, this incorporation predominates over sulfate uptake from interstitial porewater. Either the plants incorporate normally toxic sulfides, or they are creating and using a specialized nutrient pool of oxidized sulfides at the root-sediment interface.     

Organic geochemistry and pore water chemistry of sediments from Mangrove Lake,Bermuda

Mangrove Lake, Bermuda, is a small coastal, brackish-water lake that has accumulated 14 m of banded, gelatinous, sapropelic sediments in less than 10⁴ yr. Stratigraphic evidence indicates that Mangrove Lake's sedimentary environment has undergone three major depositional changes (peat, freshwater gel, brackish-water gel) as a result of sea level changes. The deposits were examined geochemically in an effort to delineate sedimentological and diagenetic changes. Gas and pore water studies include measurements of sulfides, ammonia, methane, nitrogen gas, calcium, magnesium, chloride, alkalinity, and pH. Results indicate that sulfate reduction is complete, and some evidence is presented for bacterial denitrification and metal sulfide precipitation. The organic-rich sapropel is predominantly algal in origin, composed mostly of carbohydrates and insoluble macromolecular organic matter called humin with minor amounts of proteins, lipids, and humic acids. Carbohydrates and proteins undergo hydrolysis with depth in the marine sapropel but tend to be preserved in the freshwater sapropel. The humin, which has a predominantly aliphatic structure, increases linearly with depth and composes the greatest fraction of the organic matter. Humic acids are minor components and are more like polysaccharides than typical marine humic acids. Fatty acid distributions reveal that the lipids are of an algal and/or terrestrial plant source. Normal alkanes with a total concentration of 75 ppm exhibit two distribution maxima. One is centered about n-C₂₂ with no odd/even predominance, suggestive of a degraded algal source. The other is centered at n-C₃₁ with a distinct odd/even predominance indicative of a vascular plant origin. Stratigraphic changes in the sediment correlate to observed changes in the gas and pore water chemistry and the organic geochemistry.