Radiocarbon redating of contaminated samples from a tropical volcano: the Mansion ‘Series’ of St Kitts,West Indies

Heavy rainfall and dense vegetation on tropical volcanoes produce abundant carbonized wood in pyroclastic deposits, in addition to easy contamination of this wood by root systems and soluble humic material. Because the physical nature of the charcoal varies, some samples are more prone to contamination. Two independent studies of the same volcano, Mt Liamuiga on St Kitts in the Lesser Antilles, sometimes using samples from the same carbonized tree, yielded a systematic difference in radiocarbon ages. An exchange of samples and a re-investigation of three physically distinct types of charcoal yielded the following results. Rare, hard, dense charcoal, lacking contamination, which had yielded a spurious age of 2860 years bp, was redated at 1845±58 years bp. Common soft, friable charcoal with good cellular structure proved to be susceptible to contamination. A field decontamination technique utilized by one group seems significant as it yields older ages than when only routine laboratory pre-treatment was used, indicating that the latter technique only partly removes the dried and hard residue produced by the decomposition of modern plant rootlets. A previous date of 24870 years bp obtained from powdery charcoal in a horizon beneath the Mansion Series contradicted ages older than 41000 years bp from common friable charcoal in the lower Mansion Series. The soft powdery charcoal was re-investigated using a sample collected a few centimeters from the original, although field decontamination of this sample was not possible, more extensive laboratory treatment yielded an age of ca. 43000 years bp, again proving that routine laboratory pretreatments are inadequate. A revised geochronology for the Mansion Series is described and a cautionary discussion is presented for the benefit of investigators using radiocarbon ages to date volcanic deposits.     

An extended finite volume method and fixed-stress approach for modeling fluid injection–induced tensile opening in fractured reservoirs

Fluid injection–induced tensile opening is modeled using an extended finite volume method (XFVM). An embedded fracture strategy is used for the flow problem, that is, the fractures are discretized using finite volume segments without resolving the grid around them. Further, the discontinuities across fractures are modeled using special basis functions. The fracture openings due to enhanced fluid pressure and the associated shear slip due to traction free boundary condition on the fracture segments are both modeled using these special discontinuity basis functions. Mass transfer between fractures and matrix is modeled using the pressure difference. The enhancement of fracture storativity due to tensile opening leads to stronger coupling between flow and mechanics. An iterative scheme relying on the fixed-stress approach for fractures, which conserves the stress dependent terms over each iteration of the flow problem, has been introduced. Tensile opening has been simulated for single fractures embedded in two- and three-dimensional matrices. The convergence criterion for sequentially implicit fixed-stress scheme for fractures embedded in elastic media is established and has been validated numerically. Further, for 2D simulations, the effect of the matrix permeability for fracture propagation due to tensile opening has been studied.     

Organic geochemistry and pore water chemistry of sediments from Mangrove Lake,Bermuda

Mangrove Lake, Bermuda, is a small coastal, brackish-water lake that has accumulated 14 m of banded, gelatinous, sapropelic sediments in less than 10⁴ yr. Stratigraphic evidence indicates that Mangrove Lake's sedimentary environment has undergone three major depositional changes (peat, freshwater gel, brackish-water gel) as a result of sea level changes. The deposits were examined geochemically in an effort to delineate sedimentological and diagenetic changes. Gas and pore water studies include measurements of sulfides, ammonia, methane, nitrogen gas, calcium, magnesium, chloride, alkalinity, and pH. Results indicate that sulfate reduction is complete, and some evidence is presented for bacterial denitrification and metal sulfide precipitation. The organic-rich sapropel is predominantly algal in origin, composed mostly of carbohydrates and insoluble macromolecular organic matter called humin with minor amounts of proteins, lipids, and humic acids. Carbohydrates and proteins undergo hydrolysis with depth in the marine sapropel but tend to be preserved in the freshwater sapropel. The humin, which has a predominantly aliphatic structure, increases linearly with depth and composes the greatest fraction of the organic matter. Humic acids are minor components and are more like polysaccharides than typical marine humic acids. Fatty acid distributions reveal that the lipids are of an algal and/or terrestrial plant source. Normal alkanes with a total concentration of 75 ppm exhibit two distribution maxima. One is centered about n-C₂₂ with no odd/even predominance, suggestive of a degraded algal source. The other is centered at n-C₃₁ with a distinct odd/even predominance indicative of a vascular plant origin. Stratigraphic changes in the sediment correlate to observed changes in the gas and pore water chemistry and the organic geochemistry.     

Organic carbon isotope ratios in Quaternary cores from the Gulf of Mexico

All of the major deep-water sedimentary provinces of the Gulf of Mexico were sampled with 48 piston cores, representative of the late Quaternary. The amount (per cent) and δ5C¹³ of the organic carbon in the sediment was measured at intervals within each core.Graphs of δC¹³ versus depth for each core give an indication of the sedimentological history of the Gulf. They show the extent of terrestrial influence on the Gulf during the late Pleistocene.Changes in δC¹³ of up to 6.0%.(from ~ ?19%.to ?25%. vs NBS-20) were measured across the Pleistocene-Holocene boundary in cores from the abyssal plain. These changes are consistent with a model wherein varying amounts of land-derived organic carbon were transported to the Gulf basin during glacial periods.By comparing graphs for cores from different areas, it was concluded that the major parameter affecting the δC¹³ values of organic carbon from marine sediments is the relative amount of terrestrial material present in the sediment. The maximum possible effect of the Pleistocene-Holocene temperature change in the Gulf was determined to be ~1.0%, if such an effect occurs at all.     

Comparison of soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters

The choice of sampling method for soil solution is of great importance. In this paper soil solution chemistry sampled by centrifugation, two types of suction lysimeters and zero-tension lysimeters have been studied with the purpose of investigating systematic differences between them. The samples were taken at 4 depths from an acidified forest soil as well as from adjacent lime and ash treated soils. A centrifugation drainage method was compared with two types of suction lysimeters (‘Rhizon’ and ‘Prenart’) and zero-tension lysimeters. About half of the 27 variables measured showed a significant difference between the sampling methods used. Typically the centrifuged samples had lower pH (4.0 vs. 4.4), Ca (21 μM vs. 30 μM) and Mg (25 μM vs. 34 μM) concentrations and higher Cl (330 μM vs. 230 μM) and DOC (4.4 mM vs. 3.2 mM) concentrations than the Rhizon lysimeters. Also the other lysimeters showed significant differences compared to the centrifuged samples for about half the number of analytes. Centrifuged samples had higher concentrations of all analytes except NO₃ and PO₄ compared to zero-tension lysimeters and also for all analytes except NO₃ and Al compared to Prenart lysimeters. Among the environmental factors considered depth showed an influence to some extent, while sampling occasion had a great significant impact on the difference between the centrifugation method and the Rhizon lysimeters. Factors like individual pits or soil treatment did not show any influence on the difference between the methods.     

Organic matter fluxes and marsh stability in a rapidly submerging estuarine marsh

We studied organic matter cycling in two Gulf Coast tidal, nonsaline marsh sites where subsidence causes marine intrusion and rapid submergence, which mimics increased sea-level rise. The sites experienced equally rapid submergence but different degrees of marine intrusion. Vegetation was hummocked and much of the marsh lacked rooted vegetation. Aboveground standing crop and production, as measured by sequential harvesting, were low relative to other Gulf CoastSpartina patens marshes. Soil bulk density was lower than reported for healthyS. alterniflora growth but that may be unimportant at the current, moderate sulfate levels. Belowground production, as measured by sequential harvesting, was extremely fast within hummocks, but much of the marsh received little or no belowground inputs. Aboveground production was slower at the more saline site (681 g m^?2 yr^?1) than at the less saline site (1,252 g m^?2 yr^?1). Belowground production over the entire marsh surface averaged 1,401 g m^?2 yr^?1 at the less saline site and 585 g m^?2 yr^?1 at the more saline site. Respiration, as measured by CO₂ emissions in the field and corrected for CH₄ emissions, was slower at the less saline site (956 g m^?2 yr^?1) than at the more saline site (1,438 g m^?2 yr^?1), reflecting greater contributions byS. alterniflora at the more saline site which is known to decompose more rapidly thanS. patens. Burial of organic matter was faster at the less saline site (796 g m^?2 yr^?1) than at the more saline site (434 g m^?2, yr^?1), likely in response to faster production and slower decomposition at the less saline site. Thus vertical accretion was faster at the less saline site (1.3 cm yr^?1) than at the more saline site (0.85 cm yr^?1); slower vertical accretion increased flooding at the more saline site. More organic matter was available for export at the less saline site (1,377 g m^?2 yr^?1) than at the more saline site (98 g m^?2 yr^?1). These data indicated that organic matter production decreased and burial increased in response to greenhouse-like conditions brought on by subsidence. *** DIRECT SUPPORT *** A01BY069 00016     

Precambrian fluvial deposits: Enigmatic palaeohydrological data from the c. 2–1.9 Ga Waterberg Group, South Africa

Precambrian fluvial systems, lacking the influence of rooted vegetation, probably were characterised by flashy surface runoff, low bank stability, broad channels with abundant bedload, and faster rates of channel migration; consequently, a braided fluvial style is generally accepted. Pre-vegetational braided river systems, active under highly variable palaeoclimatic conditions, may have been more widespread than are modern, ephemeral dry-land braided systems. Aeolian deflation of fine fluvial detritus does not appear to have been prevalent. With the onset of large cratons by the Neoarchaean–Palaeoproterozoic, very large, perennial braided river systems became typical. The c. 2.06–1.88 Ga Waterberg Group, preserved within a Main and a smaller Middelburg basin on the Kaapvaal craton, was deposited largely by alluvial/braided-fluvial and subordinate palaeo-desert environments, within fault-bounded, possibly pull-apart type depositories.

Palaeohydrological data obtained from earlier work in the Middelburg basin (Wilgerivier Formation) are compared to such data derived from the correlated Blouberg Formation, situated along the NE margin of the Main basin. Within the preserved Blouberg depository, palaeohydrological parameters estimated from clast size and cross-bed set thickness data, exhibit rational changes in their values, either in a down-palaeocurrent direction, or from inferred basin margin to palaeo-basin centre. In both the Wilgerivier and Blouberg Formations, calculated palaeoslope values (derived from two separate formulae) plot within the gap separating typical alluvial fan gradients from those which characterise rivers (cf. [Blair, T.C., McPherson, J.G., 1994. Alluvial fans and their natural distinction from rivers based on morphology, hydraulic processes, sedimentary processes, and facies assemblages. J. Sediment. Res. A64, 450–489.]). Although it may be argued that such data support possibly unique fluvial styles within the Precambrian, perhaps related to a combination of major global-scale tectono-thermal and atmospheric–palaeoclimatic events, a simpler explanation of these apparently enigmatic palaeoslope values may be pertinent. Of the two possible palaeohydrological formulae for calculating palaeoslope, one provides results close to typical fluvial gradients; the other formula relies on preserved channel-width data. We suggest that the latter will not be reliable due to problematic preservation of original channel-widths within an active braided fluvial system. We thus find no unequivocal support for a unique fluvial style for the Precambrian, beyond that generally accepted for that period and discussed briefly in the first paragraph.     

The Maltese Islands: climate, vegetation and landscape

The Maltese Islands, situated in the central Mediterranean, occupy an area of only some 316 km². The climate is typically Mediterranean: the average annual rainfall is c. 530 mm of which some 85% falls during the period October to March; the mean monthly temperature range is 12--26 °C, and the islands are very windy and sunny. Although small, the Maltese Islands have a considerable diversity of landscapes and ecosystems which are representative of the range and variety of those of the Mediterranean region. The islands are composed mainly of limestones, the soils are young and are very similar to the parent rocks, and there are no mountains, streams or lakes, but only minor springs; the main geomorphological features are karstic limestone plateaux, hillsides covered with clay taluses, gently rolling limestone plains, valleys which drain runoff during the wet season, steep sea-cliffs on the south-western coasts, and gently sloping rocky shores to the Northeast. The main vegetational assemblages are maquis, garigue and steppe; minor ones include patches of woodland, coastal wetlands, sand dunes, freshwater, and rupestral communities; the latter are the most scientifically important in view of the large number of endemic species they support. Human impact is significant. Some 38% of the land area is cultivated, c. 15% is built up, and the rest is countryside. The present landscape is a result of the interaction of geology and climate, coupled with the intense human exploitation of the environment over many thousands of years, which has altered the original condition of the vegetation cover, principally through the diversion of vast tracts of land to cultivation, the construction of terraces, water catchment devices, irrigation channels and drainage ditches, the grazing of animals on uncultivated land, and the development of land for buildings and industry. The scantiness of the soil, combined with the erratic rainfall and the periodic disturbance of the vegetation cover, has resulted in extensive erosion. As a consequence it is now difficult for the original vegetation to reassert itself, affecting the landscape drastically and permanently. Much of the original native flora has been lost or marginalised and the present day non-urban landscape is now dominated by vegetation consisting mainly of ruderal and introduced species. As the population increases, and human pressure on the environment mounts, such trends are likely to continue and it is only very recently that some important initiatives have been taken to manage the environment and halt the deterioration of the landscape.     

Measurement of natural stresses in a Provence mine (Southern France)

Stress measurements were carried out in the Arc syncline using drifs in a lignite mine. Eleven sites were investigated using the flat jack and hydraulic fracturing (or stimulating) methods. Two stress states were found to coexist, one isotropic, the other highly anisotropic. The orientations of the principal stresses are not homogeneous and an orientation ranging from E-W to NE-SW predominates locally. This does not accord with the regional stress field. The vertical stresses are systematically underestimated.