Nutrient Inputs, Phytoplankton Response, and CO2 Variations in a Semi-Enclosed Subtropical Embayment, Kaneohe Bay, Hawaii

The marine shelf areas in subtropical and tropical regions represent only 35% of the total shelf areas globally, but receive a disproportionately large amount of water (65%) and sediment (58%) discharges that enter such environments. Small rivers and/or streams that drain the mountainous areas in these climatic zones deliver the majority of the sediment and nutrient inputs to these narrow shelf environments; such inputs often occur as discrete, episodic introductions associated with storm events. To gain insight into the linked biogeochemical behavior of subtropical/tropical mountainous watershed-coastal ocean ecosystems, this work describes the use of a buoy system to monitor autonomously water quality responses to land-derived nutrient inputs and physical forcing associated with local storm events in the coastal ocean of southern Kaneohe Bay, Oahu, Hawaii, USA. The data represent 2.5 years of near-real time observations at a fixed station, collected concurrently with spatially distributed synoptic sampling over larger sections of Kaneohe Bay. Storm events cause most of the fluvial nutrient, particulate, and dissolved organic carbon inputs to Kaneohe Bay. Nutrient loadings from direct rainfall and/or terrestrial runoff produce an immediate increase in the N:P ratio of bay waters up to values of 48 and drive phytoplankton biomass growth. Rapid uptake of such nutrient subsidies by phytoplankton causes rapid declines of N levels, return to N-limited conditions, and subsequent decline of phytoplankton biomass over timescales ranging from a few days to several weeks, depending on conditions and proximity to the sources of runoff. The enhanced productivity may promote the drawing down of pCO₂ and lowering of surface water column carbonate saturation states, and in some events, a temporary shift from N to P limitation. The productivity-driven CO₂ drawdown may temporarily lead to air-to-sea transfer of atmospheric CO₂ in a system that is on an annual basis a source of CO₂ to the atmosphere due to calcification and perhaps heterotrophy. Storms may also strongly affect proximal coastal zone pCO₂ and hence carbonate saturation state due to river runoff flushing out high pCO₂ soil and ground waters. Mixing of the CO₂-charged water with seawater causes a salting out effect that releases CO₂ to the atmosphere. Many subtropical and tropical systems throughout the Pacific region are similar to Kaneohe Bay, and our work provides an important indication of the variability and range of CO₂ dynamics that are likely to exist elsewhere. Such variability must be taken into account in any analysis of the direction and magnitude of the air?Csea CO₂ exchange for the integrated coastal ocean, proximal and distal. It cannot be overemphasized that this research illustrates several examples of how high frequency sampling by a moored autonomous system can provide details about ecosystem responses to stochastic atmospheric forcing that are commonly missed by traditional synoptic observational approaches. Finally, the work exemplifies the utility of combining synoptic sampling and real-time autonomous observations to elucidate the biogeochemical and physical responses of coastal subtropical/tropical coral reef ecosystems to climatic perturbations.     

Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.     

Tyre track pools and puddles – Anthropogenic contributors to aquatic biodiversity

Twelve sites of tyre track pools and puddles situated in woodland, heath and pasture in Dorset UK were examined to determine their macroinvertebrate species richness and community changes over the course of one year.174 taxa were found with Diptera (59) and Coleoptera (48) contributing 61% of the total. The most frequently occurring and ubiquitous groups were nematoceran dipterans, Oligochaeta, Coleoptera, Crustacea and Lamellibranchiata.Species richness varied with season and on average was highest in March and November samples. On average only 26% (range 16–40%) of the combined total number of taxa found in spring (March) and autumn (November) samples from a site were also found there in each of these seasons individually, indicating a high species turnover through the year.The tyre track pools contributed to local aquatic biodiversity by adding 29 taxa to previously published taxa lists from aquatic habitats in the area. The relative richness of the tyre track pools is attributed to their successional variation in a heterogeneous landscape.Conservation value of 9 of the 12 sites was rated Very high to High and nine regionally notable or rare taxa were recorded. It is suggested that the important conservation status of the tyre track pools warrants greater recognition and further intensive study.     

Le massif granitique de Lesponne (Hautes Pyrénées): Un exemple de massif plutonique hercynien à mise en place diapirique syncinématique

Résumé Le massif plutonique de Lesponne est un petit complexe de granitoÏdes calco-alcalins affleurant au coeur d'un important dÔme structural, au sein d'un encaissant micaschisteux ordovicien surmonté par des formations calcaréo-pélitiques dévoniennes. A partir de l'étude structurale du massif et de son encaissant d'où ressortent le parallélisme entre la forme allongée du massif et les mégastructures plissées hercyniennes, la continuité entre la foliation des granitoÏdes et la schistosité hercynienne majeure de l'encaissant, la zonation de la déformation de part et d'autre du contact massif encaissant, la simultanéité entre le thermométamorphisme et la déformation développés autour du massif, le massif de Lesponne est interprété comme un corps intrusif dont la mise en place diapirique est synchrone de la déformation hercynienne majeure.

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The Lesponne plutonic massif is a small complex of calcalkaline granitoids cropping out in the core of an important structural dome, within Ordovician micaschists covered by Siluro-Devonian calc-pelitic formations. The structural study of the massif and its country rocks shows that: 1) the long axis of the massif tends to be parallel to the main Hercynian folds; 2) the foliation of the granitoids pass in continuity to the major Hercynian cleavage of the enclosing rocks; 3) the zonation of the strain in the massif and its enclosing rocks is parallel to the envelope of the pluton and 4) the contact metamorphism was synchronous with the main Hercynian deformation. This leads to interpret the Lesponne massif as an intrusive stock diapirically emplaced during the main Hercynian deformation.

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Zusammenfassung Der Pluton von Lesponne ist ein kleiner Komplex kalkalkalischer granitischer Gesteine im Zentrum einer bedeutenden Domstruktur. Er ist umgeben von ordovizischen Glimmerschiefern und wird überlagert von einer kalkigtonigen Devonabfolge. Strukturelle Untersuchungen im Granitmassiv und in den benachbarten Randbereichen erbrachten folgende Ergebnisse: Parallelität der Längsachse des Massivs und der varizischen Gro\faltenstruktur, Fortsetzung der varisszischen Hauptschieferung der Randgesteine ins Massiv in Form einer Schieferung zonare Anordnung der Deformation beiderseits des Kontaktes zwischen dem Massiv und den Randgesteinen, Gleichzeitigkeit von Thermometamorphose und Deformation der Randgesteine in der Umgebung des Massivs. Daraus lä\t sich ableiten, da\ das Massiv von Lesponne einen Intrusivkörper darstellt, dessen diapirische Platznahme synchron mit der variszischen Hauptdeformation erfolgte.

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Lesponne (Hautes Pyrénées) - , . - . : ; ; . . , Lesponne , .

     

Sulphur uptake by salt grasses,mangroves, and seagrasses in anaerobic sediments

Stable sulfur isotope analyses show that rooted estuarine plants growing in anoxic sediments incorporate substantial amounts of ³⁴S-depleted sulfides, or oxidation products thereof. In roots, this incorporation predominates over sulfate uptake from interstitial porewater. Either the plants incorporate normally toxic sulfides, or they are creating and using a specialized nutrient pool of oxidized sulfides at the root-sediment interface.     

Late Quaternary environmental changes on Pacific islands: controversy,certainty and conjecture

The late Quaternary history of the Pacific islands is poorly known. Most details about Pleistocene history come from studies of ocean-floor sediments, although a few insular pollen records extend back into the last glacial stage. There is limited evidence for Last Glacial Maximum (LGM) aridity and a rise in LGM–early Holocene precipitation associated with strengthening of the Southern Oscillation. The middle Holocene warming is best represented by sea-level records, which, from all parts of the Pacific, now show a contemporary maximum ca. 5000–3000 yr BP. Late Holocene cooling and precipitation increase were probably more widespread than available data suggest. The advent of humans into Pacific island environments, mostly during the late Holocene, is critically reviewed. Vegetation change may have, at least in part, been the result of climate change. Many Pacific island grasslands may be climatogenic rather than anthropogenic. Fires may have occurred naturally long before people arrived on Pacific islands. Ideas about early human impacts on Pacific island enviroments need to be critically reviewed. © 1997 John Wiley & Sons, Ltd.     

Natural and Post-Urbanization Signatures of Hypoxia in Two Basins of Puget Sound: Historical Reconstruction of Redox Sensitive Metals and Organic Matter Inputs

Hypoxia has been observed in Hood Canal, Puget Sound, WA, USA since the 1970s. Four long sediment cores were collected in 2005 and age-dated to resolve natural and post-urbanization signatures of hypoxia and organic matter (OM) sources in two contrasting basins of Puget Sound: Main Basin and Hood Canal. Paleoecological indicators used for sediment reconstructions included pollen, stable carbon and nitrogen isotopes (??¹³C and ??¹⁵N), biomarkers of terrestrial OM (TOM), biogenic silica (BSi), and redox-sensitive metals (RSM). The sedimentary reconstructions illustrated a gradient in RSM enrichment factors as Hood Canal > Main Basin, southern > northern cores, and pre-1900s > 1900?C2005. The urbanization of Puget Sound watersheds during the 1900s was reflected as shifts in all the paleoecological signatures. Pollen distributions shifted from predominantly old growth conifer to successional alder, dominant OM signatures recorded a decrease in the proportion of marine OM (MOM) concomitant with an increase in the proportion of TOM, and the weight % of BSi decreased. However, these shifts were not coincidental with an overall increase in the enrichment of RSM or ??¹⁵N signatures indicative of cultural eutrophication. The increased percentage of TOM was independently verified by both the elemental ratios and lignin yields. In addition, isotopic signatures, BSi, and RSMs all suggest that OM shifts may be due to a reduction in primary productivity rather than an increase in OM regeneration in the water column or at the sediment/water interface. Therefore, the reconstructions suggested the Hood Canal has been under a more oxygenated ??stance?? during the twentieth century compared to prior periods. However, these 2005 cores and their resolutions do not encompass the period of high resolution water column measurements that showed short-lived hypoxia events and fish kills in Hood Canal during the early twenty-first century. The decoupling between the increased watershed-scale anthropogenic alterations recorded in the OM signatures and the relatively depleted RSM during the twentieth century suggests that physical processes, such as deep-water ventilation, may be responsible for the historical variation in oxygen levels. Specifically, climate oscillations may influence the ventilation and/or productivity of deep water in Puget Sound and particularly their least mixed regions.