Lipids and trophic linkages in harp seal (Phoca groenlandica) from the eastern Barents Sea

Fatty acid profiles and lipid biomarkers from 20 harp seals were used to investigate the foraging ecology of harp seals and the transfer of energy through the Franz Josef Land-Novaya Zemlya food chain. High levels of the Calanus fatty acid trophic markers (FATMs) 20:1(n-9) (mean 14.6%) and 22:1(n-11) (mean 6.5%), together with the typical dinoflagellate FATMs 22:6(n-3) (mean 6.5%) and C18PUFA (mean 5.5%), were found in blubber samples. Based on the analyses of the fatty acid profiles separated by principal component analysis, we confirmed the importance of polar cod ( Boreogadus saida ) and the pelagic amphipod Themisto libellula in the diet of harp seal. The high levels of 22:6(n-3), C18PUFA and C20 and C22 FATMs show that the harp seal lipids mainly originate from dinoflagellates consumed by Calanus copepods.     

Evaluation of microbiologically induced corrosion in an estuary

A dockside experiment was designed at the mouth of the Pascagoula River in Pascagoula, Mississippi, to evaluate corrosion in welded Cu/Ni piping systems. Localized corrosion was shown to be due to the following sequence of events: (1) metal segregation during welding processes, (2) settlemnt of sulfide-producing bacteria in welds, (3) disruption of surface films by turbulence, and (4) formation of adjacent cathodic and anodic areas.     

Time-based correlation of biogenic,lithogenic and authigenic sediment components with anthropogenic inputs in the Gulf of Mexico NECOP study area

Hypotheses related to variability in seasonal hypoxic conditions, coastal nutrient enhancement, and off-shelf transport of carbon on the Louisiana continental shelf were tested by characterization of biogenic, lithogenic, and authigenic components from two shelf and one Mississippi Canyon sediment cores. The authigenic-phase glauconite occurs above detection limits only in the core from the hypoxic area. A major increase in glauconite concentration was coincident with the onset (≈1940) of the increased use of commercial fertilizers in the United States. In the same hypoxic-area core, benthic foraminifera species diversity decreases upcore from approximately the turn of the century to the present in a manner concurrent with glauconite and fertilizer increases. A subset of opportunistic benthic foraminifera species, known to become more prominent in stressed environments (i.e., hypoxic), increased upcore from ～52% of the total population at core bottom to ≈90% at core top. These benthic foraminifera population and diversity changes were not apparent in a “control” core outside the area of documented hypoxia. Seaward of the shelf, in the Mississippi Canyon, coincident increases in sediment accumulation rate, percentages of coarse fraction and of organic carbon at core top indicate increased offshelf transport of carbon and other components. Quartz percentages indicate that episodic down-canyon transport has been active to core bottom (prior to the mid 1800s).     

South East Europe electricity roadmap – modelling energy transition in the electricity sectors

One of the most important challenges for the South East Europe region will be replacing more than 30% of its presently installed fossil fuel generation capacity by the end of 2030, and more than 95% by 2050 if its age structure is considered. This requires a strong policy framework to incentivise new investments in a region currently lacking investors, but also presents an opportunity to shape the electricity sector over the long term according to the broader energy transition strategy of the EU and the Energy Community. The aim of this paper is to assess what type of long-term pathways exist for electricity sector development in the region if they follow the energy transition process of the EU. In this model-based scenario assessment, long term electricity sector futures are explored using a set of interlinked electricity models evaluating the level of renewable energy investment required in the region to reach a deep decarbonization target, assuming emission reduction above 94% by 2050 compared to 1990 in line with the long term market integration and climate policy goals of the EU. It also explores what are the most important system wide impacts of the high deployment of renewable energy concerning generation adequacy and security of supply.

Key policy insights

• Energy policies in the South East Europe (SEE) region, both at the national and regional level, should focus on enabling renewable energy integration, as this will be a key component of the future energy mix.

• EU and Energy Community policies should be incorporated into national energy planning to ensure that SEE countries embark on the energy transition process at an early stage.

• Stranded costs should be carefully considered in decision-making on new fossil-fuel generation and gas network investment in order to avoid lock-in to carbon intensive technologies.

• If consistent decarbonization policy prevails, with a significant and persistent CO2 price signal, the role of natural gas remains transitory in the region.

• The SEE region offers relatively cheap decarbonization options: the power sector can reduce GHG emissions above 94% by 2050 in the modelled scenarios.

     

Lode–gold mineralization in the Tanami region, northern Australia

The Tanami region of northern Australia has emerged over the last two decades as the largest gold-producing region in the Northern Territory. Gold is hosted by epigenetic quartz veins in sedimentary and mafic rocks, and by sulfide-rich replacement zones within iron formation. Although limited, geochronological data suggest that most mineralization occurred at about 1,805–1,790 Ma, during a period of extensive granite intrusion, although structural relationships suggest that some deposits predate this period. There are three main goldfields in the Tanami region: the Dead Bullock Soak goldfield, which hosts the world-class Callie deposit; The Granites goldfield; and the Tanami goldfield. In the Dead Bullock Soak goldfield, deposits are hosted by carbonaceous siltstone and iron formation where a late (D₅) structural corridor intersects an early F₁ anticlinorium. In The Granites goldfield, deposits are hosted by highly sheared iron formation and are interpreted to predate D₅. The Tanami goldfield consists of a large number of small, mostly basalt-hosted deposits that probably formed at a high structural level during D₅. The D₅ structures that host most deposits formed in a convergent structural regime with σ ₁ oriented between E–W and ENE–WSW. Structures active during D₅ include NE-trending oblique thrust (dextral) faults and ESE-trending (sinistral) faults that curve into N- to NNW-trending reverse faults localized in supracrustal belts between and around granite complexes. Granite intrusions also locally perturbed the stress field, possibly localizing structures and deposits. Forward modeling and preliminary interpretations of reflection seismic data indicate that all faults extend into the mid-crust. In areas characterized by the N- to NW-trending faults, orebodies also tend to be N- to NW-trending, localized in dilational jogs or in fractured, competent rock units. In areas characterized by ESE-trending faults, the orebodies and veins tend to strike broadly east at an angle consistent with tensional fractures opened during E–W- to ENE–WSW-directed transpression. Many of these deposits are hosted by reactive rock units such as carbonaceous siltstone and iron formation. Ore deposition occurred at depths ranging from 1.5 to 11 km from generally low to moderate salinity carbonic fluids with temperatures from 200 to 430°C, similar to lode–gold fluids elsewhere in the world. These fluids are interpreted as the product of metamorphic dewatering caused by enhanced heat flow, although it is also possible that the fluids were derived from coeval granites. Lead isotope data suggest that lead in the ore fluids had multiple sources. Hydrogen and oxygen isotope data are consistent with both metamorphic and magmatic origins for ore fluids. Gold deposition is interpreted to be caused by fluid unmixing and sulfidation of host rocks. Fluid unmixing is caused by three different processes: (1) CO₂ unmixing caused by interaction of ore fluids with carbonaceous siltstone; (2) depressurization caused by pressure cycling in shear zones; and (3) boiling as ore fluids move to shallow levels. Deposits in the Tanami region may illustrate the continuum model of lode–gold deposition suggested by Groves (Mineralium Deposita 28:366–374, 1993) for Archean districts.     

The organic geochemistry of ancient sediments—Part II

Several shales and oils ranging in age from 3 million to 2·7 billion years have been investigated for their hydrocarbon content using gas chromatography and mass spectrometry as primary analytical tools. From the Soudan Shale from Minnesota (2·7 × 10⁹yr) the C₁₈, C₁₉, C₂₀ and C₂₁ isoprenoid-alkanes were obtained. The Antrim shale from Michigan (about 265 × 10⁶ yr) yielded the C₁₆, C₁₈, C₁₉, C₂₀ and C₂₁ isoprenoids, as well as a C₁₆ iso-alkane and the C₁₈ and C₁₉ cyclohexyl n-alkanes. The San Joaquin Oil (30 × 10⁶ yr) and the Abbott Rock Oil (3 × 10⁶ yr) contained the C₁₆, C₁₈, C₁₉, C₂₀ and the C₁₈, C₁₉, C₂₀ and C₂₁ isoprenoids respectively. In addition, a series of iso-alkanes (C₁₆−C₁₈), anteiso-alkanes (C₁₆−C₁₈) and n-alkylcyclohexanes (C₁₆−C₁₉) as well as a C₂₁ isoprenoid were obtained from the Nonesuch Seep Oil (1 × 10⁹ yr). This analysis provides a comprehensive picture of the types of biogenic hydrocarbons found in oils and shales of widely differing ages, and in particular, the finding of isoprenoid alkanes in the Soudan Shale furnishes evidence for life processes at that period of geological time.     

Documenting natural wear on antlers: A first step in identifying use-wear on purported antler tools

Natural behavior of the deer can leave various modifications on the antlers. Deer often rub their antlers against tree bark and bushes and use them intensively during male–male competition. All of these behaviors can leave marks on the antlers. Distinguishing these naturally-made marks from human-made marks is crucial in accurately identifying antler tools from archaeological sites. This study examined 347 white-tailed deer antlers to document the types and frequencies of the natural modifications. Scratches, polish, deformation, and fractures on the tip are the most frequently found modifications. Unless the modifications on the antlers from archaeological sites can be distinguished from these natural modifications, the nature of the purported antler tools remains questionable.     

Relationships between rocky desertification and spatial pattern of land use in typical karst area,Southwest China

Karst rocky desertification is a typical type of land degradation in the Southwest China. An attempt was made to study quantitatively the relationships between rocky desertification and spatial pattern of land use through applying spatial analysis of Geographical Information System in Nandong underground river system, a typical karst area, Southwest China. The spatial distribution of rocky desertification and spatial pattern of land use were obtained from interpreting Landsat Images in Nandong area in 2007 by supervised classifications, and verified and rectified through field survey. The results indicate that: (1) the total land deserted area covers 378.3 km², or 23.4% of the total area, of which intense, moderate and slight rocky desertification covers 269.46, 54.2, and 54.63 km², respectively, in Nandong area. (2) There is an obvious effect of spatial pattern of land use on rocky desertification. With the increase of elevation and slope, there is a higher occurrence ratio of rocky desertification in the cultivated land and grass land. Also, more than half of total rocky desertification was dominated within the areas of 4 km from the construction land, and 97% of total rocky desertification was dominated within the areas of 10 km from the construction land in Nandong area. And what can be known from the data is that the primary effect distance of human on rocky desertification from the construction land is 4 km, and the farthest effect distance of human on rocky desertification from the construction land is 10 km in Nandong area.