Defining organominerals: Comment on ‘Defining biominerals and organominerals: Direct and indirect indicators of life’ by Perry et al. (2007, Sedimentary Geology, 201, 157–179)

The paper by Perry et al. (2007, Defining biominerals and organominerals: Direct and indirect indicators of life, Sedimentary Geology, 201, 157–179) proposes to introduce “the new term ‘organomineral’” to describe mineral products whose formation is induced by by-products of biological activity, dead and decaying organisms, or nonbiological organic compounds, to be distinguished from the biomineral components of living organisms. The substantive ‘organomineral’, however, is not new: it was first introduced in 1993, with basically the same definition and distinction from biominerals, at the 7th International Symposium on Biomineralization (Défarge and Trichet, 1995, From biominerals to ‘organominerals’: The example of the modern lacustrine calcareous stromatolites from Polynesian atolls, Bulletin de l'Institut Océanographique de Monaco, n° spéc. 14, vol. 2, pp. 265–271). Thereafter, more than twenty-five papers by various authors have been devoted to organominerals and organomineral formation (‘organomineralization’) processes. Only two of these papers are cited by Perry et al., and without any reference to the definitions, or even the terms ‘organomineral’ or ‘organomineralization’, which they included. Moreover, Perry et al. tend to enlarge the original concept of organomineral to encompass all minerals containing organic matter, whether these organic compounds are active or passive in the mineralization, which introduces ambiguities detrimental to a fine understanding of present and past geobiological processes. Finally, Perry et al. propose to consider organominerals as indirect biosignatures that could be used in the search for evidence of life in the geological record and extraterrestrial bodies. This latter proposition also is problematical, in that organominerals may be formed in association with prebiotic or abiotic organic matter.     

Ab initio quantum mechanical study of γ-AlOOH boehmite: structure and vibrational spectrum

The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc2₁, P2₁/c. Cmcm turns out to correspond to a transition state, whereas Cmc2₁ and P2₁/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm⁻¹). For the Al-OH bending modes (800–1,300 cm⁻¹) an absolute differences of 50–100 cm⁻¹ is observed; for the OH stretching modes (3,200–3,500 cm⁻¹) it increases to 120–200 cm⁻¹: anharmonicity is large because OH groups are involved in strong hydrogen bonds.     

利用步长模拟对青藏高原涡度方差测量法的质量评价

利用痕迹模拟方法对青藏高原两处地方涡度方差的测量数据进行了质量分析，揭示了其空间和时间结构。分析表明高达1/3的测量没有达到必要的数据正确假设。尽管这样对潜热、CO2、动量通量的测量基本通过测试，可以适用于基础研究，但是经常发现特定的风矢量违背基本假设条件。感热通量的测量允许使用不间断的连续测量法，然而由于局地地形的影响少量评估指数未能合理解释，但能够指示出组织结构及用于导出边界层中尺度流体模型假说。     

Projected climate change impacts on spatial distribution of bioclimatic zones and ecoregions within the Kailash Sacred Landscape of China,India, Nepal

Rapidly accelerating climate change in the Himalaya is projected to have major implications for montane species, ecosystems, and mountain farming and pastoral systems. A geospatial modeling approach based on a global environmental stratification is used to explore potential impacts of projected climate change on the spatial distribution of bioclimatic strata and ecoregions within the transboundary Kailash Sacred Landscape (KSL) of China, India and Nepal. Twenty-eight strata, comprising seven bioclimatic zones, were aggregated to develop an ecoregional classification of 12 ecoregions (generally defined by their potential dominant vegetation type), based upon vegetation and landcover characteristics. Projected climate change impacts were modeled by reconstructing the stratification based upon an ensemble of 19 Earth System Models (CIMP5) across four Representative Concentration Pathways (RCP) emission scenarios (i.e. 63 impact simulations), and identifying the change in spatial distribution of bioclimatic zones and ecoregions. Large and substantial shifts in bioclimatic conditions can be expected throughout the KSL area by the year 2050, within all bioclimatic zones and ecoregions. Over 76 % of the total area may shift to a different stratum, 55 % to a different bioclimatic zone, and 36.6 % to a different ecoregion. Potential impacts include upward shift in mean elevation of bioclimatic zones (357 m) and ecoregions (371 m), decreases in area of the highest elevation zones and ecoregions, large expansion of the lower tropical and sub-tropical zones and ecoregions, and the disappearance of several strata representing unique bioclimatic conditions within the KSL, with potentially high levels of biotic perturbance by 2050, and a high likelihood of major consequences for biodiversity, ecosystems, ecosystem services, conservation efforts and sustainable development policies in the region.     

The influence of the coast on the dynamics of upwelling fronts: Part II. Numerical simulations

We investigated the dynamics of upwelling fronts near a coast. This work was first motivated by laboratory experiments [Bouruet-Aubertot, Linden, Dyn. Atmos. Oceans, 2002] in which the front is produced by the adjustment of a buoyant fluid initially confined within a bottomless cylinder. It was shown that cyclonic eddies consisting of coastal waters are enhanced when the front is unstable near the coast (the outer vertical boundary). The purpose of this paper is to provide further insights into this process. We reproduced the experimental configuration using a three-dimensional model of the primitive equations. We first show that for coastal fronts more potential energy, in terms of the maximum available potential energy, is released than for open-ocean fronts. Therefore, waves of larger amplitude are generated during the adjustment and the mean flow that establishes has a higher kinetic energy in the former case. Then as baroclinic instability starts and wave crests reach the boundary, cyclonic eddies are enhanced as in the laboratory experiments and in a similar way. However, in contrast to the laboratory experiments, offshore advection of cyclonic eddies can occur in two stages, depending on the spatial organization of the baroclinic wave. When the baroclinic wave consists of the sum of different modes and is thus highly asymmetric, the offshore advection of cyclonic eddies occurs just after their enhancement at the boundary, as in the laboratory experiments. By contrast, when a single-mode baroclinic wave develops, neighboring cyclonic eddies first merge before being advected offshore. Very different behavior is observed for open-ocean fronts. First a mixed baroclinic–barotropic instability grows. Then the eddies transfer their energy to the mean flow and the barotropic and baroclinic instabilities start again. An excellent agreement is obtained with the main result obtained in the laboratory experiments: the ratio between growth rates of surface cyclonic and anticyclonic vorticity increases as the instability develops nearer to the coast.     

The LMDZ4 general circulation model: climate performance and sensitivity to parametrized physics with emphasis on tropical convection

The LMDZ4 general circulation model is the atmospheric component of the IPSL–CM4 coupled model which has been used to perform climate change simulations for the 4th IPCC assessment report. The main aspects of the model climatology (forced by observed sea surface temperature) are documented here, as well as the major improvements with respect to the previous versions, which mainly come form the parametrization of tropical convection. A methodology is proposed to help analyse the sensitivity of the tropical Hadley–Walker circulation to the parametrization of cumulus convection and clouds. The tropical circulation is characterized using scalar potentials associated with the horizontal wind and horizontal transport of geopotential (the Laplacian of which is proportional to the total vertical momentum in the atmospheric column). The effect of parametrized physics is analysed in a regime sorted framework using the vertical velocity at 500 hPa as a proxy for large scale vertical motion. Compared to Tiedtke’s convection scheme, used in previous versions, the Emanuel’s scheme improves the representation of the Hadley–Walker circulation, with a relatively stronger and deeper large scale vertical ascent over tropical continents, and suppresses the marked patterns of concentrated rainfall over oceans. Thanks to the regime sorted analyses, these differences are attributed to intrinsic differences in the vertical distribution of convective heating, and to the lack of self-inhibition by precipitating downdraughts in Tiedtke’s parametrization. Both the convection and cloud schemes are shown to control the relative importance of large scale convection over land and ocean, an important point for the behaviour of the coupled model.     

Mid-Holocene to present-day evolution of the Indian monsoon in transient global simulations

The low-frequency evolution of Indian rainfall mean-state and associated interannual-to-decadal variability is discussed for the last 6000 years from a multi-configuration ensemble of fully coupled global transient simulations. This period is marked by a shift of Indian Summer Monsoon Rainfall (ISMR) distribution towards drier conditions, including extremes, and a contraction of the rainy season. The drying is larger in simulations with higher horizontal resolution of the atmosphere and revised land surface hydrology. Vegetation–climate interactions and the way runoff is routed to ocean modulate the timing of the monsoon onset but have negligible effects on the evolution of seasonal rainfall amounts in our modeling framework in which carbon cycling is always active. This drying trend is accompanied by changes in ISMR interannual-to-decadal variability decreasing over north and south India but increasing over central India (20°–25° N). The ISMR interannual-to-decadal variability is decomposed into six physically consistent regimes using a clustering technique to further characterize its changes and associated teleconnections. From 6 to 3.8 kyr bp, the century-to-century modulations in the frequency of occurrence associated to the regimes are asynchronous between the simulations. Orbitally-driven trends can only be detected for two regimes over the whole 6–0 kyr bp period. These two regimes reflect increased influence of ENSO on both ISMR and Indian Ocean Dipole as the inter-hemispheric energy gradient weakens. Severe long-term droughts are also shown to be a combination of long-term drying and internally generated low-frequency modulations of the interannual-to-decadal variability.

     

Untersuchungen zum Abbau von Pharmaka in kommunalen Kläranlagen mit HPLC-Electrospray-Massenspektrometrie

Examination of the Degradation of Drugs in Municipal Sewage Plants Using Liquid Chromatography-Electrospray Mass Spectrometry Numerous drugs can be identified in the secondary effluent of municipal sewage plants. In order to obtain information about the degree of elimination (adsorption, aerobic degradation) of these compounds, a batch reactor containing different drugs in environmentally relevant concentrations and a suspension of activated sludge was coupled to a HPLC-MS-MS system. During a testing period of three days concentration-time-curves were recorded. For most of the examined drugs (acetamidoantipyrine, crotamiton, diclofenac, primidone, propyphenazone) solely a strong decrease of the initial concentration within the first 15 minutes was observed, which was interpreted primarily as adsorption to the activated sludge. For acetaminophenol and pentoxifyllin an additional slower decrease in concentration within several hours was observed. This slower elimination was interpreted to be caused mainly by primary degradation. It could be shown that dihydrocodeine is oxidized to hydrocodone in the batch reactor. The conjugate acetaminophen glucuronide was cleaved.     

What controls the extreme flow through the Kerama Gap: a global HYbrid Coordinate Ocean Model reanalysis point of view

Ocean Dynamics - The temporal variability of volume transport from the North Pacific Ocean to the East China Sea (ECS) through the Kerama Gap (between Okinawa Island and Miyakojima Island—a...