Polycyclic aromatic hydrocarbons and amino acids in meteorites and ice samples from LaPaz Icefield,Antarctica

Abstract— –We have analyzed ice samples and meteorites from the LaPaz region of Antarctica to investigate the composition of polycyclic aromatic hydrocarbons (PAHs) and amino acids with the goal to understand whether or not there is a compositional relationship between the two reservoirs. Four LL5 ordinary chondrites (OCs) and one CK carbonaceous chondrite were collected as part of the 2003/2004 ANSMET season. Ice samples collected from directly underneath the meteorites were extracted. In addition, exhaust particles from the snowmobiles used during the expedition were collected to investigate possible contributions from this source. The meteorite samples, the particulate matter and solid‐state extracts of the ice samples and the exhaust filters were subjected to two‐step laser mass spectrometry (L2MS) to investigate the PAH composition. For amino acids analysis, the meteorites were extracted with water and acid hydrolyzed, and the extracts were analyzed with offline OPA/NAC derivatization combined with liquid chromatography with UV fluorescence detection and time of flight mass spectrometry (LC‐FD/ToF‐MS). PAHs in the particulate matter of the ice were found to be qualitatively similar to the meteorite samples, indicating that micron‐sized grains of the meteorite may be embedded in the ice samples. The concentration levels of dissolved PAHs in all the ice samples were found to be below the detection limit of the L2MS. The PAH composition of the snowmobile exhaust is significantly different to the one in particulate matter, making it an unlikely source of contamination for Antarctic meteorites. The amino acids glycine, β‐alanine and γ‐amino‐n‐butyric acid that were detected at concentrations of 3 to 19 parts per billion (ppb) are probably indigenous to the Antarctic meteorites. Some of the LaPaz ice samples were also found to contain amino acids at concentration levels of 1 to 33 parts per trillion (ppt), in particular α‐aminoisobutyric acid (AIB), an abundant non‐protein amino acid of extraterrestrial origin found in some carbonaceous chondrites. We hypothesize that this amino acid could have been extracted from Antarctic micrometeorites and the particulate matter of the meteorites during the concentration procedure of the ice samples.     

Geophysical prospecting on the Santorini Islands

A program of geophysical research was carried out as a preliminary stage of study of the Santorini volcanic group. This area is of remarkable geothermal and volcanological interest, and the definition of a volcanological structural model is the starting point for an understanding of the local geodynamic processes. Gravity, magnetic and geoelectrical data proved that:

1. the core of the volcanic edifice consists of a sedimentary-metamorphic basement;
2. the basement is tectonically disturbed and a linear tectonic system produces a graben-type structure in the middle part of the area.

     

Simulating Martian regolith in the laboratory

Regolith and dust cover the surfaces of the Solar Systems solid bodies, and thus constitute the visible surface of these objects. The topmost layers also interact with space or the atmosphere in the case of Mars, Venus and Titan. Surface probes have been proposed, studied and flown to some of these worlds. Landers and some of the mechanisms they carry, e.g. sampling devices, drills and subsurface probes (“moles”) will interact with the porous surface layer. The absence of true extraterrestrial test materials in ample quantities restricts experiments to the use of soil or regolith analogue materials. Several standardized soil simulants have been developed and produced and are commonly used for a variety of laboratory experiments. In this paper we intend to give an overview of some of the most important soil simulants, and describe experiments (penetrometry, thermal conductivity, aeolian transport, goniometry, spectroscopy and exobiology) made in various European laboratory facilities.     

Variations of Indian and African monsoons induced by insolation changes at 6 and 9.5 kyr BP

This study investigates the role of insolation in controlling the Indian and African monsoon evolutions during the Holocene using coupled ocean-atmosphere simulations of 0, 6, 9.5 kyr BP climates, for which only the variations of Earth’s orbital configuration are considered. The two monsoon systems are enhanced at 6 and 9.5 kyr BP, compared to 0 kyr BP, as a result of the intensified seasonal cycle of insolation in the Northern Hemisphere. The analysis of daily climatologies indicates that even though the length of the “celestial” summer season is shorter at 9.5 kyr BP, the rainy season is longer than at present. Emphasis is put on the impact of the precession on the seasonality, which partly explains why the relative amplification of the Indian and African monsoon varies between 9.5 and 6 kyr BP. Moreover, the changes in snow cover over the Tibetan Plateau play a critical role in reinforcing the 9.5 kyr BP monsoon in India during spring. The results suggest that the teleconnection between convection over India and subsidence over the Mediterranean regions, through the Rodwell and Hoskins mechanism, has an impact on the development of the African monsoon at 9.5 kyr BP.     

Climate and vegetation: Simulating the African humid period

The outputs of the climate simulated by two General Circulation Models (GCMs), (IPSL and UGAMP) have been used to force a vegetation model (LPJ-GUESS) to analyze the Holocene African humid period (AHP) and related vegetation changes over the 18°W-35°E, 5°S-25°N region. At the continental scale, simulations with the two models confirm the intensified African monsoon during the Holocene as compared to now, and the early but gradual termination of the AHP in eastern regions as compared to western regions. At the regional scale, the two GCMs results present important differences in the timing of the AHP, its spatial extent and the summer rainfall amplitude. Consequently, the vegetation model simulates changes that are globally in agreement with pollen data, but with large differences according to the region and the model considered. During the AHP, the IPSL climate induced proper vegetation changes in the eastern Sahara and in the Sahel, whereas the UGAMP climate induced correct changes in the western Sahara and in the equatorial zone.     

Spatial patterns of water surface topography at a river confluence

Understanding flow structures in river confluences has largely been the product of interpretations made from measured flow velocity data. Here, we turn the attention to the investigation of the patterns of both the average and standard deviations of the micro‐topography of the water surface at an asymmetrical natural discordant confluence for different flow conditions. Water surface topography is measured using a total station to survey the position of a reflector mounted on a custom‐built raft. To limit error problems related to changes in the water level, measurements are taken and analysed by cross‐stream transects where five water surface profiles are taken before moving to the next transect. Three‐dimensional numerical simulations of the flow dynamics at the field site are used to examine predicted water surface topography for a steady‐state situation. The patterns are interpreted with respect to flow structure dynamics, visual observations of boils, and bed topography. Results indicate that coherent patterns emerge at the water surface of a discordant bed confluence for different flow conditions. The zone of stagnation and the mixing layer are characterized by super‐elevation, a lateral tilt is present at the edge of the mixing layer, and a zone of super‐elevation is present on the tributary side at the downstream junction corner. The latter seems associated with periodical upwelling and is not present in the numerical simulations that do not take into account instantaneous velocity fluctuations. Planform curvature, topographic steering related to the tributary mouth bar, and turbulent structures associated with the mixing layer all play a key role in the pattern of both the average and standard deviation of the water surface topography at confluences. Copyright © 2002 John Wiley & Sons, Ltd.     

Implications of climate change in the twenty‐first century for simulated magnitude and frequency of bed‐material transport in tributaries of the Saint‐Lawrence River

More frequent extreme flood events are likely to occur in many areas in the twenty‐first century due to climate change. The impacts of these changes on sediment transport are examined at the event scale using a 1D morphodynamic model (SEDROUT4‐M) for three tributaries of the Saint‐Lawrence River (Québec, Canada) using daily discharge series generated with a hydrological model (HSAMI) from three global climate models (GCMs). For all tributaries, larger flood events occur in all future scenarios, leading to increases in bed‐material transport rates, number of transport events and number of days in the year where sediment transport occurs. The effective and half‐load discharges increase under all GCM simulations. Differences in flood timing within the tributaries, with a shift of peak annual discharge from the spring towards the winter, compared to the hydrograph of the Saint‐Lawrence River, generate higher sediment transport rates because of increased water surface slope and stream power. Previous research had shown that channel erosion is expected under all GCMs' discharge scenarios. This study shows that, despite lower bed elevations, flood risk is likely to increase as a result of higher flood magnitude, even with falling base level in the Saint‐Lawrence River. Copyright © 2010 John Wiley & Sons, Ltd.