Chlorine isotopic composition in seafloor serpentinites and high-pressure metaperidotites. Insights into oceanic serpentinization and subduction processes

Bulk-rock chlorine content and isotopic composition (δ³⁷Cl) were determined in oceanic serpentinites, high-pressure metaperidotites and metasediments in order to gain constraints on the global chlorine cycle associated with hydrothermal alteration and subduction of oceanic lithosphere. The distribution of insoluble chlorine in oceanic serpentinites was also investigated by electron microprobe. The hydrothermally-altered ultramafic samples were dredged along the South West Indian Ridge and the Mid-Atlantic Ridge. The high-pressure metamorphic samples were collected in the Western Alps: metaperidotites in the Erro-Tobbio unit and metasediments in the Schistes Lustrés nappe.Oceanic serpentinites show relatively large variations of bulk-rock Cl contents and δ³⁷Cl values with mean values of 1105 ± 596 ppm and −0.7 ± 0.4‰, respectively (n = 8; 1σ). Serpentines formed after olivine (meshes) show lower Cl content than those formed after orthopyroxene (bastites). In bastites of two different samples, Cl is positively correlated with Al₂O₃ and negatively correlated with SiO₂. These relationships are interpreted as reflecting preferential Cl-incorporation into the bastite structure distorted by Al (substituted for Si) rather than different alteration conditions between olivine and orthopyroxene minerals. High-pressure metaperidotites display relatively homogeneous Cl contents and δ³⁷Cl values with mean values of 467 ± 88 ppm and −1.4 ± 0.1‰, respectively (n = 7; 1σ). A macroscopic high-pressure olivine-bearing vein, formed from partial devolatilization of serpentinites at ∼2.5 GPa and 500-600 °C, shows a Cl content and a δ³⁷Cl value of 603 ppm and −1.6‰, respectively. Metasediments (n = 2) show low whole-rock Cl contents (<15 ppm Cl) that did not allow Cl isotope analyses to be obtained.The range of negative δ³⁷Cl values observed in oceanic serpentinites is likely to result from water-rock interaction with fluids that have negative δ³⁷Cl values. The homogeneity of δ³⁷Cl values from the high-pressure olivine-bearing vein and the metaperidotite samples implies that progressive loss of Cl inherited from oceanic alteration throughout subduction did not significantly fractionate Cl isotopes. Chlorine recycled in subduction zones via metaperidotites should thus show a range of δ³⁷Cl values similar to the range found in oceanic serpentinized peridotites.     

Crowdsourcing a cyclist perspective on suggested recreational paths in real-world networks

ABSTRACT

Routing and navigation services for leisure activities are conditioned by special needs and trade-offs. The advent of online communities and large crowdsourced datasets offers opportunities to improve the adoption of a user’s perspective in these suggested paths. This paper focuses on achieving two goals. First, the presented methodology analyses a dataset of 190,610 historical GPS traces to gain insights into the appreciation or attractiveness of each edge in a real-world network for a specific leisure activity (i.e. road cycling). Second, as literature on these leisure activities is still sparse, we want to create a thorough understanding of the activities at hand for future work. An appreciation model is proposed and the spread of this score is analyzed in shortest-path alternatives of popular routing engines for this activity. This analysis successfully discriminates these shortest paths based on the scoring value and three morphological parameters of the path. However, the robustness of the model should be improved to ensure the viability of the proposed approach in future work. More specifically, further research on the local optimality of the route choices will be imperative.     

Coastal response to the Holocene transgression in the Bahamas: episodic sedimentation versus continuous sea-level rise

Sedimentological and petrographic study of Holocene deposits in the Eastern Bahamas shows that sedimentation occurred episodically during this period of continually rising sea-level.

The Holocene stratigraphic record exposed on the islands of San Salvador, Lee Stocking and Cat consists of two distinctive units separated by a paleosol: (1) 5000 year-old oolitic eolianites deposited when sea-level was lower than today, and (2) 3000 to 500 year-old bioclastic paleo-beaches and dunes that are congruent with the present stand of sea-level.

A five-stage model that reconciles intermittent sedimentation pattern with continuous sea-level rise is presented. Pre-Holocene topography and changes in the rate of the transgression seem to regulate local⁴ hydrodynamic conditions, which in turn control onset and offset of sedimentary processes.

This Holocene example of episodic sedimentation during an uninterrupted transgression should be considered when studying ancient discontinuities that are systematically interpreted in terms of relative sea-level fall.     

Anharmonicity and high-temperature heat capacity of crystals: the examples of Ca2GeO4, Mg2GeO4 and CaMgGeO4 olivines

Drop-calorimetry determinations of the isobaric heat capacity (C_P) of Mg₂GeO₄, Ca₂GeO₄ and CaMgGeO₄ have been made up to 1700 K. The thermal expansion coefficient (α) of these olivine germanates has been determined from high-temperature X-ray measurements up to 1500 K. From these measurements and available compressibility data, one calculates that the isochoric heat capacity (C_V) exceeds the harmonic limit of Dulong and Petit above 1000–1200 K. Such an intrinsic anharmonic behaviour can be accounted for by introducing anharmonic parameters a_i=(? ln v _i/?T)_V in vibrational modelling of C_V. These parameters are calculated from pressure and temperature shifts of the vibrational frequencies as measured by Raman spectroscopy up to 10 GPa at room temperature and up to 1300 K at 1 bar. A comparison of the Raman spectra of the three germanates with those of natural olivines justifies once again the use of germanates as silicate analogues. Extensive Ca,Mg disordering likely takes place in CaMgGeO₄, beginning at about 1100 K and leading to unusually high increases of the heat capacity and thermal expansion coefficient.     

A gap in the North American Central Plains conductivity anomaly

The palaeotectonic models of the North American continent have been deeply influenced by the concept of a North American Central Plains conductivity anomaly (NACPCA) which was postulated as a result of large area, wide-spaced, array studies, using the Magnetic Deep Sounding (MDS) method.

A recent closely spaced magnetotelluric (MT) survey across this proposed anomaly near the Canadian-U.S. boundary by Jones and Savage (1986) failed to detect the NACPCA at the location suggested by the MDS. However, this survey did verify a conductivity anomaly discovered by Rankin and Kao (1979) and a new anomaly 75 km east of NACPCA. Our present study verifies this latter anomaly and quantitative results are presented. The striking isotropy in apparent resistivity does not prevent the interpretation of anomalous resistivity distributions. This is discussed in the text.

The failure of the MDS array studies to detect our anomaly is readily explainable by the wide station spacing; however, the failure of the MT survey to detect the NACPCA leads us to the conclusion that it may not be a continuous feature.     

Fully Equipped to Succeed: Migratory Contingents Seen as an Intrinsic Potential for Striped Bass to Exploit a Heterogeneous Environment Early in Life

Migratory contingents, groups of individuals belonging to the same population that adopt different migratory patterns, have been identified in numerous Striped Bass (Morone saxatilis) populations along North American East Coast. We tested the hypothesis that migratory contingents may develop early in life to maximize the exploitation of the variety of habitats faced by a recently introduced fish population. Using the discriminatory power provided by otolith chemistry, we studied early-life history stages of Striped Bass in a recently reintroduced population in the St. Lawrence Estuary. Migratory patterns were inferred using multivariate analysis of four otolith trace elements (Sr, Ba, Mn, and Mg) on juveniles (0+ and 1+). Three migratory contingents were identified during early-life history stages: freshwater residents, oligohaline migrants, and mesohaline migrants. This study demonstrates the rapid establishment, in less than 10 years since initial stocking, of three migratory contingents initiated early in life among the St. Lawrence Striped Bass population. We postulate that diversification provided by the establishment of distinct migratory contingents among early-life history stages promotes the rapid colonization of new environments through the exploration and exploitation of an increased number of nursery habitats.     

Long-term fish and macro-crustacean community variation in a Mediterranean lagoon

The fish and macro-crustacean community of the Vaccarès lagoon (Rhône River delta, South France) was sampled monthly from 1993 to 2002. The lagoon salinity shifted from 15 in 1993 to 5 in 1994–1997 and went back to 15 in 1999–2002. Connections with the sea also varied during the study period with larger openings in 1996–1997. During the study period, the community changed to revert in 2002 to a state similar to 1993. These changes consisted of a sequence of increased and decreased patterns of freshwater species and some marine species. Typical lagoon species tended to resist to salinity changes. Freshwater species colonised the lagoon when the salinity was low. Marine species may have varied both in relation to connections with the sea and to indirect effects of freshwater outflow. This study shows that community changes following environmental variations can be delayed in time, and emphasises the need for long-term studies.     

Structural style and evolution of the Gulf of Lion Oligo-Miocene rifting: role of the Pyrenean orogeny

The Gulf of Lion margin results from the Cligo-Aquitanian rifting and Burdigalian crustal separation between continental Europe and Corsica-Sardinia. Immediately before the onset of extension, the area of the Gulf of Lion was affected by the Pyrenean orogeny which controlled the structural style of the evolving margin. During extension, the foreland of the Pyrenean orogen was affected by extensional thin-skinned tectonics. The décollement level ramped down into the basement, in areas where the latter was thickened during orogeny. In this intermediate part, the margin was extended by several crustal-scale low-angle faults, which generated small amounts of syn-rift sedimentation compared with the accumulation of post-rift sediments. However, more than 4 km of syn-rift sediments were deposited in the Camargue basin, which is located at the transition between thin- and thick-skinned extensional systems. Kinematic restorations and stratigraphy suggest a pre-rift surface elevation above sea-level of at least 1 km in the intermediate part of the margin, which is in agreement with reduced syn-rift sedimentation. The slope area extends seaward of the North Pyrenean Fault, a terrane boundary inherited from the Pyrenean collision. This part of the margin was stretched by seaward dipping low-angle block tilting of the upper crust, and antithetic lower crustal and sub-crustal detachment. The lithospheric structures inherited from the Pyrenean orogeny exerted a strong control on the kinematics of the rifting and on the distribution and history of subsidence. Such parameters need to be integrated in the definition of pre-rift initial conditions in future basin-modelling of the Gulf of Lion.