An57Fe mössbauer effect study of ankerite

A natural sample of ankerite has been characterized by chemical analysis, X-ray diffraction and differential thermal analysis. The composition was found to be (Ca_1.11Mg_0.50Fe_0.33Mn_0.09) [Co₃]_1.99.⁵⁷Fe Mössbauer effect measurements were performed at temperatures between 4.2 and 400 K. At low temperatures (T < 25 K) relaxation effects are clearly dominant. The temperature dependence of the center shift is remarkably well reproduced by a model based on the Debije approximation of the lattice vibrations. In contrast, the temperature dependence of the quadrupole splitting cannot be described by any reasonable crystal field model. It is argued that an orbit-lattice coupling might explain the observed quadrupole splittings. A spectrum recorded in an applied field of 6 T reveals a positive electric field gradient from which an orbital doublet ground state is concluded. Highly anisotropic field reductions are derived but cannot be quantitatively explained due to a lack of knowledge concerning the magnetic structure of ankerite. The line widths decrease significantly with increasing temperature which is only partly due to the decreasing Mössbauer fraction.     

Error analysis in hypocentral locations at Phlegraean Fields

The location reliability of the earthquakes occurred at Phlegraean Fields has been analyzed, and the theoretical errors, inferred from the diagonal elements of the covariance matrix, have been estimated. Using only first P-phase arrivals to the local network (22 stations) and assuming a reading error of 0.05 sec., the average error on the spatial coordinates is estimated to be of the order of 0.2 km.Shallow events (depth<1 km) are very poorly constrained in depth at the borders of the network. The use of both P and S arrival times, recorded by a smaller three component network (10 stations), improves the depth determination.Further analysis has been performed on a set of about 350 selected earthquakes, using two different velocity models.Differences in depth considerably greater than the theoretical errors, and showing highly different patterns have been found.Tests with artificial events, randomly distributed in space, indicate that the observed depth distribution is essentially due to the used velocity model.     

Hydraulics of runoff and loess loam deposition

On many more or less loamy soils, rill erosion is reported to start on slopes that are equal to or steeper than 2–3°; critical Froude numbers for the start of rill wash on these slopes vary between 2·0 and 3·0. This explains why colluvial deposition often occurs on slopes below 2–3°, when water spreads out at the downslope extremities of the rills. The critical hydraulic conditions for loess loam deposition were tested in the laboratory for slopes of 0·5° and 2°, applying unit-discharges (q) up to 10 cm²/s. It appeared from these experiments that for afterflow, without raindrop impact, deposition starts for critical load concentrations (c_cr) varying between several g/1 and about 60 g/l. Under rain c_cr amounts to a minimum value of 100–125 g/l and it increases when the runoff film becomes thinner. Nevertheless, deposition in pluvial runoff is also possible, as was the case during the Weichselian, according to data from quarries in Belgium and in The Netherlands. A modified Kalinske equation is proposed for c_cr prediction, with the introduction of a typical empirical coefficient C_r and considering such factors as shear stress and mean particle size. Massive sedimentation may occur when it stops raining and afterflow starts, since c_cr values are then much lower. It is shown from the Shields' diagram that loamy suspensions are more sensitive to sedimentation than sands in clear water.     

K-Ar ages of basic rocks in the Patia Valley, southwest Colombia

The Patia Valley situated between the Western and Central Cordilleras of the southwest Colombian Andes contains two areas in which Mesozoic basic and ultrabasic rocks crop out in abundance. Late Cretaceous Diabase Group pillow basalts which make up much of the Western Cordillera are at least 81 ± 5 Ma in the E1 Tambo-E1 Peñol area. 105-97 Ma hornblende and whole-rock dates from the ophiolitic Los Azules complex indicate an Albian age of formation, although many dates are lower (65-62 Ma) owing the low-grade ocean-floor metamorphism. The metamorphic age distribution here supports an end of Cretaceous emplacement for the complex rather than the Early-Mid Cretaceous emplacement suggested for North Colombian ophiolites similarly aligned along the Romeral fault system. Tertiary dacites intruding the Low Azules complex are 36-15 Ma.     

Viscosity and configurational entropy of silicate melts

With the configurational entropy theory of relaxation processes of Adam and Gibbs (1965), one predicts that the viscosity depends on temperature according to log $\text{η = A}{}_{\mathrm{e}}\text{+}\text{B}{}_{\mathrm{e}}\text{TS}{}_{\mathrm{<mtext>conf</mtext>}}$, where S_conf is the configurational entropy of the liquid. Thermochemical calculations of S_conf performed for some mineral compositions show the importance of non-configurational contributions to the entropy differences between amorphous and crystalline phases. Except for the case of SiO₂, the available thermodynamic data indicate that the above equation for viscosity accounts quantitatively for the experimentally determined temperature dependence of the viscosity of silicate melts. The Adam and Gibbs theory also provides a simple rationale for the non linear variation of the logarithmic viscosity with composition in mixed alkali silicate liquids at low temperatures, the minimum of viscosity resulting from the contribution of the entropy of mixing to S_conf.     

Evolution of polycyclic alkanes in the Espirito Santo Basin

The distributions of polycyclic alkanes were monitored in a Neocomian sequence (well 1-ESS-34) from the Espirito Santo Basin, southeast Brazil. The profiles included, apart from regular hopanes, significant concentrations of 18α(H), 28,30-bisnorhopane and subordinate amounts of gammacerane. Sterane concentrations, normally with hopane/sterane <5, were compatible with other geochemical data indicating a predominantly planktonic/microbial source of the deposited organic matter. Sample maturities ranged from very immature to the onset of oil generation, allowing biomarker distributions to be followed along a broad maturation range. The ability of certain molecular ratios (e.g. C₂₇ 17α(H)/17β(H)hopanes) to reflect a maturity sequence with depth in the closely-spaced strata of the immature upper levels (Jiquiá Stage) showed the value of molecular techniques over classical geochemical methods (e.g. vitrinite reflectance) for the study of immature sequences. The presence in the oils of southern Espirito Santo of 28,30-bisnorhopane, gammacerane and methyl steranes in similar concentrations as in extracts of the deepest levels of the 1-ESS-34 well qualify the Jiquia Stage as the probable source rock of oils accumulated in the basin.     

Bacterial contribution to sedimentary organic matter; a comparative study of lipid moieties in bacteria and Recent sediments

A systematic study of the lipid composition of thirteen bacterial species and three Recent sediments (methanogenic sediment, cyanobacterial mat and evaporative gypsum crust) was undertaken in an attempt to recognize bacterial organic matter in sediments. A sequential method, which distinguishes between three different modes of occurrence of lipid moieties (free, OH⁻- and H⁺-labile), was applied. The acid-labile fractions are discussed.The three main groups of bacteria, archaebacteria, gram-positive eubacteria and gram-negative eubacteria, are easily distinguished. Methanogenic and extremely halophilic archaebacteria are characterized by the presence of diphytanyl glyceryl ether and the absence of fatty acids. The gram-positive eubacteria contain primarily iso- and anteiso-branched fatty acids whereas the gram-negative bacteria and sediments are dominated by β- and α-hydroxy fatty acids. A wide variety of H⁺-labile hydroxy fatty acids was observed which included several, as yet unknown, structures.β-Hydroxy fatty acids in this H⁺-labile mode of occurrence are exclusively present in bacteria. Their distribution patterns in sediments are considered “fingerprints” of past and present bacterial populations. The specific differences in β -hydroxy fatty acid compositions observed in the different bacteria and the three sediments investigated, suggest that amide-linked β-hydroxy fatty acid patterns are useful as markers of bacterial populations and therefore of environmental conditions.     

Coastal slope terracing and relative sea-level changes: Deductions based on computer simulations

Although a traditional geological survey of terraced coastal slopes is an essential part of studies aimed to reconstruct relative sea-level changes, the stratigraphic and chronological data so obtained frequently prove inadequate to completely unravel the sometimes very complex history of sea-level fluctuation, especially where erosion has prevailed over deposition and/or deposits are difficult to date. On the basis of our experience we think that much additional information can be gained through geomorphological interpretation of the profiles of those slopes. In order to facilitate such interpretation, a computer simulation model is developed that is able to predict the morphogenic response to a variety of possible relative-sea-level histories. The results can be used to envisage some new interpretation keys for the analysis of real situations and, hopefully, as bases for the conception of general models of coastal slope evolution under the action of a variable sea level. Though preliminary, the results so far obtained permit identification of the geomorphological consequences (in terms of resulting slope profile) of ordered successions of transgressions and regressions of different amplitude, rate, order and style. Moreover they provide interesting insights into the role that different styles of tectonic uplift may play in the phenomenon of multiple terracing of coastal slopes.     

Understanding the inelastic seismic behaviour of asymmetric-plan buildings

Studied in this paper is the inelastic seismic behaviour of asymmetric-plan buildings using the histories of base shear and torque. The first step in understanding this behaviour is to construct the base shear and torque surface (BST) for the building, which represents all combinations of shear and torque that applied statically lead to collapse of the structure. Several factors controlling the shape of this surface, such as strength eccentricity and bidirectional ground motion, are identified. Also, their effects on the building responses are studied considering several structural configurations. The results obtained show that the BST surface, in conjunction with the base-shear and torque histories, provides a useful conceptual framework for understanding the behaviour of asymmetric systems. Furthermore, using these surfaces, relevant aspects of the behaviour and design of such buildings become apparent even before dynamic analysis of the structure.     

Multispectral remote sensing of biomass burning in West Africa

Remote sensing measurements provide a vauable means of determining the extent of burning areas and of estimating the overall distribution of pollutant sources (identified from experimental studies) in time and space. This distribution has to be taken into account in the boundary conditions of chemistry atmospheric models.Recent methods developed for the remote sensing of active fires in tropical or temperated forest zones, have been found to be completely inadequate for fire detection on West African savannas. In order to accurately estimate the active fire distribution in the function of different sorts of West African savannas (Sahelian, Sudanian and Guinean) and forests, a multispectral methodology has been developed based on NOAA/11-AVHRR satellite data, with the purpose of eliminating as much as possible the problems related to large surface heterogeneity, confusion and bias, produced by clouds, smoke, haze, background emissivities, etc.Unlike other methods, the results show that the multispectral method, in spite of its selectivity, provides realistic results, and does not under- or over-estimate the number of fires that can be sensed by the satellite. Consequently, this methodology is more appropriate than the simplest ones for a systematic sensing of this phenomenon.