Emission estimates of methyl chloride from industrial sources in China based on high frequency atmospheric observations

Methyl Chloride (CH₃Cl) is a chlorine-containing trace gas in the atmosphere contributing significantly to stratospheric ozone depletion (Carpenter et al. 2014). In the global CH₃Cl budget, the atmospheric CH₃Cl emissions is predominantly maintained by natural sources, of which magnitudes have been relatively well-constrained. However, significant uncertainties still remain in the CH₃Cl emission strengths from anthropogenic sources. High-frequency and high-precision in situ measurements of atmospheric CH₃Cl concentrations obtained since 2008 at Gosan station (a remote background site in the East Asia) reveal significant pollution events superimposed on the seasonally varying regional background levels. Back trajectory statistics showed that air masses corresponding to the observed CH₃Cl enhancement largely originated from regions of intensive industrial activities in China. Based on an inter-species correlation method, estimates of CH₃Cl emissions from manufacturing industries including coal combustion, use of feedstocks, or process agents in chemical production for China (2008–2012) are 297 ± 71 Gg yr.^?1 in 2008 to 480 ± 99 Gg yr.^?1 in 2009, followed by a gradual decrease of about 25% between 2009 and 2012 (398 ± 92 Gg yr.^?1 for 2010; 286 ± 68 Gg yr.^?1 for 2011; 358 ± 92 Gg yr.^?1 for 2012). The annual average of industrial CH₃Cl emissions for 2008–2012 (363 ± 85 Gg yr.^?1) in China is comparable to the known total global anthropogenic CH₃Cl emissions accounting only for coal combustion and indoor biofuel use. This may suggest that unless emissions from the chemical industry are accounted for, global anthropogenic emissions of CH₃Cl have been substantially underestimated. In particular, since industrial production and use of CH₃Cl have not been regulated under the Montreal Protocol (MP) or its successor amendments, continuous monitoring of Chinese CH₃Cl outflow is important to properly evaluate its anthropogenic emissions.     

Welded tuff infilling a volcanic vent at Weolseong,Republic of Korea

A plug of parataxitically welded tuff, with an elliptical (700 × 400 m) cross section, crops out in Weolseong district, Republic of Korea. It intrudes late Cretaceous granodiorite and extrusive tuffs of the Chisulryoung Volcanic Formation and displays a steeply inclined welding foliation, concordant with the intrusive contacts, and a subvertical stretching lineation. These fabrics are interpreted as resulting from laminar shearing in a boundary layer during deposition of the tuff by agglutination along the walls of a vent which served as a feeder for extrusive ignimbrites.     

Reservoir siltation in the semi‐arid highlands of northern Ethiopia: sediment yield–catchment area relationship and a semi‐quantitative approach for predicting sediment yield

Due to shortage of rainfall and its increasing variability, moisture stress is identified to be one of the most critical factors affecting agricultural productivity in the drylands of Ethiopia. To circumvent this problem, a strategy of supplemental irrigation through surface water harvesting was adopted by the government and several micro‐dams have been built in the semi‐arid parts of the country. However, the benefits from the water harvesting schemes are not sustainable because of rapid water storage loss due to siltation. There is, therefore, an urgent need for improved catchment‐based erosion control and sediment management strategies. The design and implementation of such strategies require data on the rate and magnitude of sediment deposition. To this end, reservoir surveys were conducted to estimate sediment deposition rate for 11 reservoirs identified to be representative of catchments in the Tigray region of northern Ethiopia. Two approaches were employed during the survey: one was based on measurement of sediment thickness in reservoirs while the other was based on comparing the original and existing topography of the reservoir‐beds. The average annual sediment yield estimated for the study sites was about 19 t ha^?1 y^?1. An equation of the type SSY = 3á36A^0á67 (with SSY = area specific sediment yield in t ha^?1 y^?1 and A = catchment area in km²) was also established for the study region, which is opposite to the ‘universal’ SSY–A relationship. In order to improve the sediment yield predictive capability of A, it was integrated with a factorial index that assesses the catchment's propensity to erosion and potential sediment yield. The effect of accelerated sediment deposition on water storage loss of reservoirs and possible controlling factors of the SSY–A relationship are outlined. The potential semi‐quantitative scoring approach to characterize catchments in terms of erosion sensitivity and the significance of the A‐index approach to predict SSY of similar catchments are also highlighted. Copyright © 2006 John Wiley & Sons, Ltd.     

1/f noise analyses of urbanization effects on streamflow characteristics

Nonstationary hydrologic behaviour resulting from rapid industrialization and urbanization, combined with climate change effects, likely produces greater challenges in water resources and flood risk managements. Our country‐wide analyses for South Korea, based on spectral analysis technique, revealed how streamflow characteristics have shifted towards a less hydrologic memory state, which indicates a weaker temporal autocorrelation in the time series. Specifically, we analysed 1/f^α noise of streamflow in 78 unit watersheds in five major river basins in South Korea to investigate the effects of urbanization on stream hydrologic responses over a 30‐year period. The average slope of runoff spectra, α₀, was 0.94 ± 0.20, indicating that runoffs are characterized by pink noise. The distribution of α₀ showed a convergence towards <0.5 with increasing urbanization, indicating a clear effect of memory loss due to expanded impervious surface areas in watersheds. Among the watersheds examined, 59 showed bi‐fractal scaling regimes, with scale break points located around 17.5 days. Analysis of the three spectral slopes, α₀ (average), α_L (in low‐frequency domain), and α_H (in high‐frequency domain), revealed a threshold of urbanization ratio (UR) of ~15% from which all the three slopes decrease, and additional thresholds of UR around 6–7% are found from which all the three slopes increase as UR increases. While hydrologic responses of watersheds are the result of complex and compound interplay among many factors such as climate and topography, increasing urbanization seems to dominantly control the hydrologic properties resulting in homogenization of spectral slopes among various watersheds. Copyright © 2015 John Wiley & Sons, Ltd.     

Hydraulic and Thermal Conductivities of Kaolin–Silica Mixtures under Different Consolidation Stresses

Stable backfill materials for the heat sensitive structures of buried power cables, hot water pipes, and gas pipelines are suggested to have low permeability and high heat transfer characteristics. The hydraulic and thermal conductivities of backfill materials or clay liners are important parameters in proper design and construction of geotechnical structures involved with heat transfers. In this study, to investigate the optimal natural backfill or liner materials, thermal and hydraulic conductivities of kaolin–silica mixtures examined based on the results from laboratory tests under different consolidation conditions. From the experiment results, the thermal conductivity increases while hydraulic conductivity decreases with increasing density during consolidation process. As a result, back-fill materials with high kaolin content under low consolidation stress were desirable materials for burial of heat sensitive structures.     

Progressive change of tidal wave characteristics from the eastern Yellow Sea to the Asan Bay,a strongly convergent bay in the west coast of Korea

Although there have been studies on the tide in convergent bay (or estuary), the tide change in terms of phase speed, amplitude, and phase difference between elevation and tidal current from a coastal ocean to a convergent bay has not been clearly shown so far. This study systematically examines the change of tidal wave characteristics from the eastern Yellow Sea to the Asan Bay, a strongly convergent bay on the west coast of Korea, using observations and an analytical model. As the tidal wave propagates from the eastern Yellow Sea into the Asan Bay, the phase speed, amplitude, and phase difference between elevation and tidal current increase along the channel. Such a phenomenon represents a unique example of tide change from a coastal ocean to a convergent bay, indicating dominance of convergence over friction in the Asan Bay. Both analytically computed tidal amplitude and travelling time compare well with observations. In the Asan Bay, the influence of the reflected wave is only felt in the upper one fifth of the bay and is almost unperceivable in the rest of the bay. The analytical analyses presented in this paper are particularly useful for understanding the relative importance of channel convergence, bottom friction, and reflected wave on the tidal characteristics change along the channel and the proposed method could be applicable to other estuaries.     

A scattering-based over-land rainfall retrieval algorithm for South Korea using GCOM-W1/AMSR-2 data

Heavy summer rainfall is a primary natural disaster affecting lives and properties in the Korean Peninsula. This study presents a satellite-based rainfall rate retrieval algorithm for the South Korea combining polarization-corrected temperature (PCT) and scattering index (SI) data from the 36.5 and 89.0 GHz channels of the Advanced microwave Scanning Radiometer 2 (AMSR-2) onboard the Global Change Observation Mission (GCOM)-W1 satellite. The coefficients for the algorithm were obtained from spatial and temporal collocation data from the AMSR-2 and groundbased automatic weather station rain gauges from 1 July - 30 August during the years, 2012-2015. There were time delays of about 25 minutes between the AMSR-2 observations and the ground raingauge measurements. A new linearly-combined rainfall retrieval algorithm focused on heavy rain for the PCT and SI was validated using ground-based rainfall observations for the South Korea from 1 July - 30 August, 2016. The validation presented PCT and SI methods showed slightly improved results for rainfall > 5 mm h^-1 compared to the current ASMR-2 level 2 data. The best bias and root mean square error (RMSE) for the PCT method at AMSR-2 36.5 GHz were 2.09 mm h^-1 and 7.29 mm h^-1, respectively, while the current official AMSR-2 rainfall rates show a larger bias and RMSE (4.80 mm h^-1 and 9.35 mm h^-1, respectively). This study provides a scatteringbased over-land rainfall retrieval algorithm for South Korea affected by stationary front rain and typhoons with the advantages of the previous PCT and SI methods to be applied to a variety of spaceborne passive microwave radiometers.