δO of carbonate, quartz and phosphate from belemnite guards: implications for the isotopic record of old fossils and the isotopic composition of ancient seawater

Belemnite guards of Cretaceous and Jurassic age were found to contain varying amounts of quartz deposited both on the external surface and inside the rostrum. The oxygen isotopic composition of coexisting carbonate, quartz and phosphate from the same rostrum was measured according to well-established techniques. None of these compounds showed isotopic values in equilibrium with one another. Assuming δ¹⁸O values of the diagenetic water within the range of meteoric waters, the δ¹⁸O(SiO₂) yield temperatures in agreement with the apparent secondary origin of this phase. The δ¹⁸O(CO₃²⁻) range, with a certain continuity, between −10.8 and +0.97 PDB-1 with most of the intermediate values being within the range of the carbonate isotopic values of Mesozoic fossils. The most positive isotopic results obtained from phosphate are close to +23/+24‰ (V-SMOW). They can hardly be related to a secondary origin of the phosphate, or to the presence of diagenetic effects, since these results are among the most positive ever measured on phosphate. As far as we know there is no widespread diagenetic process determining an ¹⁸O enrichment of phosphate. The very low concentration of phosphate did not allow the determination of its mineralogical composition. All the available δ¹⁸O(PO₄³⁻) values from belemnite and non-belemnite fossils of marine origin of Tertiary and Mesozoic age are reported along with the newly measured belemnites. The following conclusions may be drawn from the data reported: (1) the pristine oxygen isotope composition of fossil marine organisms (either carbonate or phosphate) may easily undergo fairly large changes because of oxygen isotope exchange processes with diagenetic water; this process is apparent even in the case of geologically recent fossils; (2) the δ¹⁸O(PO₄³⁻) of belemnite rostra seems to be, at least in the case of the most positive results, in isotopic equilibrium with environmental water because of the similarity between the results from Cretaceous belemnites and the results from Cretaceous and Lower Tertiary pelecypods and fish teeth; 3) if so, the only feasible interpretation that can be suggested for the ¹⁸O enriched data is the possibility of a relatively large variation of the oxygen isotopic composition of ocean paleowater from Jurassic to recent time.     

Fractal analysis of mingled/mixed magmas: an example from the Upper Pollara eruption (Salina Island, southern Tyrrhenian Sea, Italy)

Upper Pollara eruption products (13 ka, Salina Island, Italy) include both homogeneous and heterogeneous pumices resulting from mixing/mingling processes between an HK andesite and a high-SiO₂ rhyolite. Representative samples of heterogeneous pumices are collected and analyzed in order to check the correspondence between glass composition and morphological features of the mingling/mixing structures. Image analysis techniques are applied and eight grey color ranges (classes) are extracted from high-resolution scans of pumice. Class 1 (lighter colors) and class 8 (darker colors) show end-member glass compositions, i.e. HK andesite and high-SiO₂ rhyolite, respectively. These two classes show spot- to cluster-like morphological structures. Intermediate classes show an HK dacitic to rhyolitic composition and a banding- to fold-like morphology. Fractal analysis by box-counting of the boundary pattern of eight grey classified images is performed over a length scale of 0.028–1.8 cm. Fractal dimension D is between 1.01 and 1.84. Coupled fractal analysis and geochemical data reveal that D increases as the degree of magma interaction (homogenization) increases. This feature well fits the results from numerical models on the convective mixing of fluids driven by thermal convection. We conclude that the increase of D observed in the Upper Pollara samples reflects the transition from fractal mixing to homogenization. End-member magmas (HK andesite and high-SiO₂ rhyolite) represent isolated mixing regions, while homogenized magmas represent active mixing regions. In the analyzed pumices, isolated and active mixing regions coexist at scales between 10⁻⁴ and 10⁻² m. Morphological and compositional features of the Upper Pollara pumices result from turbulence.     

Distrubution of Dissolved and Particulate Iron, copper and Manganese in the Shelf waters of the Ross sea (Antarctica)

Abstract. During the austral summer 1997–98, within the framework of the activities of the Climatic Long-term Interaction for the Massbalance in Antarctica (CLIMA) Project of the Italian National Program for Antarctic Research (PNRA) in the Ross Sea, measurements were conducted to focus on the role of dissolved iron, copper and manganese as micronutrients, and on their distribution in suspended particulate matter in different water masses. Sampling was carried out in two selected shelf areas, both important for formation and mixing processes of the water bodies.
Metal data were evaluated together with physical measurements and classical chemical parameters such as oxygen and nutrients.
In both the studied areas, the distribution of dissolved metals along the waste column confirmed their micronutrient behaviour, showing depletion where phytoplanktonic activities occurred.
The trend of particulate metals underlined the scavenging phenomena along the water column and presented an interesting correlation at intermediate depths with the amount and origin of suspended matter.     

Research progress in volcanology in the Neapolitan area, southern Italy: a review and some alternative views

Comprehensive reviews are given for the major volcanic systems that occur in the greater metropolitan area of Naples, southern Italy; Mt. Somma-Vesuvius to the east and the Campi Flegrei volcanic system to the west. Also included in the review is a detailed discussion of the large, highly explosive Campania Volcanic Zone (CVZ) ignimbrite events. These volcanic areas have been studied for more than 100 years, yet significant differences of opinion exist related to fundamental issues of origin and distribution. We present some alternative views related to petrogenesis on some issues based on more than 25 years of research. The relationship between risk assessment and management that impacts the threatened society or culture and the past and ongoing fundamental volcanological research is an essential part of the science. Countries with limited resources may be forced to accept an increased risk but even highly industrialized societies may not be able to completely eliminate deaths from volcanic eruptions. Scientific studies of the hazardous regions should be comprehensive and include reasonable alternative interpretations as this information reveals the level of confidence that must be conveyed to the public officials. The authors review the state of the art of risk assessment and management of the volcanic hazards in the Neapolitan region in light of the review of research.     

Controls on the lateral channel-migration rate of braided channel systems in coarse non-cohesive sediment

Lateral movements of alluvial river channels control the extent and reworking rates of alluvial fans, floodplains, deltas, and alluvial sections of bedrock rivers. These lateral movements can occur by gradual channel migration or by sudden changes in channel position (avulsions). Whereas models exist for rates of river avulsion, we lack a detailed understanding of the rates of lateral channel migration on the scale of a channel belt. In a two-step process, we develop here an expression for the lateral migration rate of braided channel systems in coarse, non-cohesive sediment. On the basis of photographic and topographic data from laboratory experiments of braided channels performed under constant external boundary conditions, we first explore the impact of autogenic variations of the channel-system geometry (i.e. channel-bank heights, water depths, channel-system width, and channel slope) on channel-migration rates. In agreement with theoretical expectations, we find that, under such constant boundary conditions, the laterally reworked volume of sediment is constant and lateral channel-migration rates scale inversely with the channel-bank height. Furthermore, when channel-bank heights are accounted for, lateral migration rates are independent of the remaining channel geometry parameters. These constraints allow us, in a second step, to derive two alternative expressions for lateral channel-migration rates under different boundary conditions using dimensional analysis. Fits of a compilation of laboratory experiments to these expressions suggest that, for a given channel bank-height, migration rates are strongly sensitive to water discharges and more weakly sensitive to sediment discharges. In addition, external perturbations, such as changes in sediment and water discharges or base level fall, can indirectly affect lateral channel-migration rates by modulating channel-bank heights. © 2019 The Author. Earth Surface Processes and Landforms published by John Wiley & Sons, Ltd. © 2019 The Author. Earth Surface Processes and Landforms published by John Wiley & Sons, Ltd.     

Late Pleistocene vertebrate-bearing deposits at San Teodoro Cave (North-Eastern Sicily): Preliminary data on faunal diversification and chronology

This paper deals with the chronology and the possible correlations among levels of different excavated areas in the Pleistocene vertebrate-bearing deposits at the large San Teodoro Cave (North-Eastern Sicily). Two trenches have been excavated along the eastern side of the cave, located at a distance from the entrance, respectively, of 8 m (α trench) and 28 m (β trench) and at different depths. Lithological features, biometrical data from small mammals and ecological data from molluscs point to similar environmental conditions for the α trench deposits and those located along the eastern wall of the cave in the eastern part of the β trench. The same evidence, and the taphonomic features of large mammals, points to different environmental conditions and perhaps to different ages for the deposits located in the western part of the β trench. The survival of elephants in Sicily up to 32,000 years ago is a new significant result of the ²³⁰Th/²³⁴U dating carried out from a concretionary stratum from the β trench and represents the youngest elephant survival in the western Mediterranean islands.     

Roughness control on hydraulic conductivity in fractured rocks

The influence of joint roughness on the typologies of fluid flow inside fractures is well known and, thanks to experiences in the field of hydraulics, it has been studied from both a physical and mathematical point of view. Nevertheless, the formulations adopted by traditional hydraulic models are hardly applicable in the geological field, because of the difficulty encountered in the roughness parameter estimation. Normally this parameter can be estimated using the joint roughness coefficient (JRC), which considers both the asperity height and its regularity and directional trend. The main advantage in using the JRC arises from the fact that it can easily be obtained from geological-technical surveys and from comparison with the standard Barton profiles. Some relationships have been built up that allow for the estimation of the hydraulic conductivity tensor (an essential parameter for understanding water flow in fractured rock masses), not only as a function of traditional parameters like aperture, spacing, dip and dip direction, etc., but also of joint roughness, precisely expressed in terms of the roughness coefficient. These relationships have been studied initially from a theoretical point of view and then practically, through laboratory investigations.

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Resumen  Se conoce muy bien la influencia de la rugosidad de las grietas en las tipologías del flujo de fluidos a lo interior de las fracturas y gracias a las experiencias en el campo de hidráulica ha sido posible estudiarla desde puntos de vista matemáticos y físicos. Sin embargo, las formulaciones adoptadas por los modelos hidráulicos tradicionales tienen poca aplicabilidad en el campo geológico debido a la dificultad relacionada con la estimación del parámetro de rugosidad. Normalmente este parámetro puede estimarse usando el coeficiente de rugosidad de grieta (JRC) el cual considera tanto la altura de la aspereza como su regularidad y tendencia direccional. La principal ventaja de utilizar el JRC se deriva del hecho que puede obtenerse fácilmente de levantamientos técnico-geológicos y de la comparación con los perfiles Standard Barton. Se han construido algunas relaciones que permiten la estimación del tensor de conductividad hidráulica (un parámetro esencial para el entendimiento del flujo de agua en masas de roca fracturadas), no solo en función de parámetros tradicionales como apertura, espaciado, buzamiento y dirección de buzamiento, etc., sino también en función de la rugosidad de la grieta estimada con precisión en términos del coeficiente de rugosidad. Estas relaciones se han estudiado inicialmente desde un punto de vista teórico y luego de modo práctico a través de investigaciones de laboratorio.

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Résumé  L’influence de la rugosité des joints sur les types d’écoulement de fluide dans les fractures est bien connue et a été étudiée aussi bien du point de vue physique que mathématique grace à des expériences menées dans le domaine de l’hydraulique. Cependant les formulations adoptées dans les modèles hydrauliques traditionnels sont difficilement applicables dans le domaine de la géologie à cause de la difficulté rencontrée pour estimer la rugosité. Ce paramètre peut normalement être apprécié grace au coefficient de rugosité du joint (JRC), lequel prend en compte à la fois la hauteur de l’aspérité ainsi que sa régularité et sa direction. Le principal avantage dans l’utilisation du JRC réside dans le fait qu’il peut facilement être obtenu à partir d’études techniques-géologiques et par comparaison avec la classification de Barton. Des relations qui permettent une estimation du tenseur de conductivité hydraulique (un paramètre essentiel pour comprendre l’écoulement de l’eau dans les masses rocheuses fracturées) ont été élaborées, pas seulement en fonction de paramètres traditionnels tels que l’ouverture, l’espacement, l’inclinaison et la direction d’inclinaison, etc , mais aussi en prenant en compte la rugosité des joints à travers le coefficient de rugosité. Ces relations ont initialement été étudiées d’un point de vue théorique puis expérimentalement à travers des recherches en laboratoire.

     

The effect of cation ordering and temperature on the high-pressure behaviour of dolomite

Synchrotron single-crystal X-ray diffraction experiments at high-pressure and high-temperature conditions were performed up to 20 GPa and 573.0(2) K on a fully ordered stoichiometric dolomite and a partially disordered stoichiometric dolomite [order parameter, s = 0.26(6)]. The ordered dolomite was found to be stable up to approximately 14 GPa at ambient temperature and up to approximately 17 GPa at T = 573.0(2) K. The P–V data from the ambient temperature experiments were analysed by a second-order Birch–Murnaghan equation-of-state giving K ₀ = 92.7(9) GPa for the ordered dolomite and K ₀ = 92.5(8) GPa for the disordered dolomite. The high-temperature data, collected for the ordered sample, were fitted by a third-order Birch–Murnaghan equation-of-state resulting in K ₀ = 95(6) GPa and K′ = 2.6(7). In order to compare the three experiments results, a third-order Birch–Murnaghan equation-of-state was also calculated for the ambient temperature experiments giving K ₀ = 93(3) GPa, K′ = 3.9(6) for the ordered dolomite and K ₀ = 92(3) GPa, K′ = 4.0(4) for the disordered dolomite. The derived axial moduli show that dolomite compresses very anisotropically, being the c-axis approximately three times more compressible than the a-axis. The axial compressibility increases as T increases, and the a-axis is the most temperature-influenced axis. On the contrary, axial compressibility is not influenced by disordering. Structural refinements at different pressures show that Ca and Mg octahedra are almost equally compressible in the ordered dolomite with K(CaO₆) = 109(4) GPa and K(MgO₆) = 103(3) GPa. On the contrary, CaO₆ compressibility is reduced and MgO₆ compressibility is increased in the disordered crystal structure where K(CaO₆) = 139(4) GPa and K(MgO₆) = 89(4) GPa. Disordering is found to increase CaO₆ and to decrease MgO₆ bond strengths, thus making stiffer the Ca octahedron and softer the Mg octahedron. Cation polyhedra are distorted in both ordered and disordered dolomites and they increase in regularity as P increases. Ordered dolomite approaches regularity at approximately 14 GPa. The increase in regularity of octahedra in the disordered dolomite is strongly affected by the very slow regularization of MgO₆ with respect to CaO₆. The phase transition to the high-pressure polymorph of dolomite (dolomite-II), which is driven by a significant increase in the regularity of both cations polyhedra and mineral crystal structure, occurs in the ordered dolomite at ambient temperature at approximately 14 GPa; whereas no clear evidences of phase transition were observed as regards the disordered crystal structure.     

1D velocity structure of the Po River plain (Northern Italy) assessed by combining strong motion and ambient noise data

Strong ground motions recorded on the sedimentary deposits of the Po River alluvial plain during the Emilia (Northern Italy) Mw 5.7 earthquake of May 29, 2012 are used to assess the vertical profile of shear-wave velocity above the limestone basement. Data were collected by a linear array installed for site effect studies after the Mw 5.9 mainshock of May 20, 2012. The array stations, equipped with both strong and weak motion sensors, are aligned in the South–North direction, at distances ranging from 1 to 26 km from the epicenter. The vertical components of ground motion show very distinctive, large-amplitude, low-frequency dispersive wave trains. Wavelet analysis yields group-velocity dispersion curve in the 0.2–0.7 Hz frequency band. The availability of a long ambient noise record allows estimates of the site resonance frequency along with its stability among stations. The joint inversion of dispersion of surface waves and ellipticity curves derived from ambient noise H/V allows extending investigations down to the sediment-limestone interface, at a depth of about 5,000 m. Our results add new information about the velocity structure at a scale that is intermediate between the local scale already investigated by other authors with small-aperture arrays using ambient noise and the regional scale inferred from modeling of seismogram waveforms recorded at hundreds of kilometers from the source.