Chemistry of alkali extraction of brown coals—I. Kinetics, characterisation and implications to coalification

Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state ¹³C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils.     

Data processing and initial results from the CE-3 Extreme Ultraviolet Camera

The Extreme Ultraviolet Camera(EUVC) onboard the Chang'e-3(CE-3)lander is used to observe the structure and dynamics of Earth's plasmasphere from the Moon. By detecting the resonance line emission of helium ions(He+) at 30.4 nm, the EUVC images the entire plasmasphere with a time resolution of 10 min and a spatial resolution of about 0.1 Earth radius(RE) in a single frame. We first present details about the data processing from EUVC and the data acquisition in the commissioning phase, and then report some initial results, which reflect the basic features of the plasmasphere well. The photon count and emission intensity of EUVC are consistent with previous observations and models, which indicate that the EUVC works normally and can provide high quality data for future studies.     

Cadmium and phosphorus cycling in the water column of the South China Sea: The roles of biotic and abiotic particles

The concentrations of cadmium, phosphorus, and aluminum in size-fractionated phytoplankton, zooplankton, and sinking particles are determined using ICPMS to evaluate the roles of biotic and abiotic particles on the cycling and ratios of Cd and P in the water column. Plankton were collected with a filtration apparatus equipped with 10-, 60-, and 150-μm aperture plankton nets on two occasions (2002 and 2006), and sinking particles were sampled by moored sediment traps deployed at depths of 120, 600, and 3500 m from 2004 to 2005. In contrast to what our previous study revealed, i.e., that most of the other bioactive trace metals in plankton were strongly correlated with abiotic Al and adsorbed on phytoplankton [Ho, T.Y., Wen, L.S., You, C.F., Lee, D.C., 2007. The trace metal composition of size-fractionated plankton in the South China Sea: biotic versus abiotic sources. Limnol Oceanogr 52, 1776–88.], Cd/P ratios, ranging from 0.12 to 0.34 mmol/mol P, did not vary with Al and exhibited fairly consistent values among different sizes of plankton, showing that Cd was mostly incorporated on an intracellular basis. In terms of the sinking particles, fluxes in Cd and P as well as in Cd/P ratios were strongly influenced by both biotic and abiotic particles. Overall, the Cd/P ratios in the sinking particles ranged from 0.03 to 1.2 mmol/mol, with the highest value observed in traps at 120 m during the productive season. The lowest value was observed in deep water during high flux periods for lithogenic particles. At surface depth, flux and Cd/P ratios were elevated during the most productive season in the region. The elevated ratios in the traps at 120 m were most likely related to preferential uptake of Cd for the dominant species (coccolithophores) during the productive period. Relatively, Cd/P ratios sharply decreased with increasing Al flux in deep water and ratios were much lower than the expected Cd/P ratios obtained from the relative portion of lithogenic and biogenic particles, indicating that the adsorption of soluble P into lithogenic particles was significant in the deep water during high lithogenic particle flux periods. Using averaged annual fluxes and standing stock in the water column, the residence time of biogenic Cd and P are 0.10 and 0.20, 250 and 100, and 9100 and 5000 years respectively in the top 120 m, 600 m, and water column as a whole, also showing preferential removal for Cd in the euphotic zone but relatively higher removal rates for P in the deep water. Our study suggests that the shift in microalgal community structure along with input of lithogenic minerals are both potentially important factors in influencing Cd/P ratios in oceanic water on a geological time scale.     

不同光生物反应器培养坛紫菜 丝状体的比较研究

Vegetative cells of Porphyra haitanensis sporophytes were grown in a bubble-column and a draft-tube internal-loop airlift bioreactor at 20℃ with an illuminance of 40μmol photons m-2 s-1 for 20days. The draft-tube internal-loop airlift bioreactor yielded maximum cell density of 4850mg DCW (Dried Cell Weight)/L and higher growth rate of 0.094/d, compared to the bubble-column, 3950mg DCW/L and 0.086/d, respectively. The advantages were related to the more homogeneous fluid dynamic characteristics in the draft-tube internal-loop airlift bioreactor than the bubble-column bioreactor.     

Theoretical wind wave frequency spectra in deep water——Ⅰ. Form of spectrum

In this part ot the paper theoretical wind-wave spectra nave been derived oy (I) expressing the spectrum in series composed of exponential terms; (2) assuming that the spectrum satisfies a high order linear ordinary differential equation; (3) introducing proper parameters in the spectrum; and (4) making use of some known charateristics of wind-wave spectrum, for instance, the law governing the equilibrium range. The spectrum obtained contains the zero order moment of the spectrum m0, the peak frequency ω0 and the ratio R =ω/ω0 (ω being the mean zero-crossing frequency) as parameters. The shape of the nondimensional spectrum S(ω) = ω0S(ω)/m0(ω=ω/ω0) changes with R and theoretically reduces to a Dirac delta function δ(ω-1) when R = 1. A spectrum of simplified form is given for practical uses, in which R is replaced by a peakness factor P=S(1).     

Seasonal circulation in the southeastern Huanghai Sea

The seasonal circulation in the southeastern Huanghai Sea has been studied with hydrographic data,which were observed in February and June 1994 and bimonthly during 1970-1990,and numerical model results.Horiwntal distributions of temperature and salinity in 1994 are quite different due to strong tidal mixing so that we need a analysis to see the real distributions of water masses.The mixing ratio analysis with the data of 1970-1990 shows the connection of the waters in the west coasts of Kotea Peninsula with warm and saline waters from the south in summer,which means northward inflows along the west coasts of Korea Peninsula in summer.With this flow,the seasonal circulations,which are deduced from the seasonal change of water mass distributions in the lower layer,are warm inflows in winter and mld outflows in summer in the central Huanghai Sea,and cold outflows in winter and warm inflows in summer along the west coasts of Korea Peninsula.The seasonally changed inflows might be the Huanghai Sea Warm Current.The monsoon winds can drive such circulations.However,summer monsoon winds are weak and irregular.As one of other possible dynamics,the variation of Kuroshio transport is numerically studied with allowing sea level fluctuations.Although it should be studied more,it possibly drives the summer circulations.The real circulations seem to be driven by both of them.     

Dynamics of subtidal flow in the Taiwan Strait

Two current meter moorings were deployed in the Taiwan Strait from 3 April to 5 May 1983. The data indicate that the subtidal flow in this rather wide strait can be separated into two parts: the mean flow and wind-driven flow, which make about equal contributions to the overall flow. The mean flow is probably originates from branching of the Kuroshio through Bashi Channel. The magnitude of the current is nearly 30 cm sec^–1 flowing northward, and the corresponding along-strait sea surface slope is on the order of 10^–7. The residual flow is a local wind-driven flow, and reaches a frictionally balanced state in about 4 hr. Assuming a linear drag law for the bottom stress, a hindcast scheme is constructed and the results compare well with the observations.     

Time-averaged sub-layer concentration profiles in oscillatory sheet flows

Although thin on the order of several to tens of millimeters, sheet flows normally comprise a lower pick-up sub-layer and an upper contact-load sub-layer, separated at the bed level (z = 0). The time-averaged concentration profile in the pick-up sub-layer shows a ‘convex upward’ curvature, but ‘concave upward’ shape characterizes the time-averaged concentration profile in the contact-load sub-layer. The time-dependent concentration in the contact-load sub-layer is approximately in-phase with the free stream flow velocity, whereas it is nearly in anti-phase with the free stream flow velocity in the pick-up sub-layer. Two distinct analytical expressions of the time-averaged concentration profiles for the respective sub-layers are proposed. The expressions are validated with detailed observation datasets collected in the Groβer Wellenkanal (GWK) prototype wave flume in Hannover, Germany. The agreement between the predicted and the measured values is excellent. Interparticle collisions in the pick-up sub-layer and convective lifting processes associated with vortex shedding in the contact-load sub-layer are considered responsible for the opposite curvatures and in-phase/anti-phase concentration variations. Both transitional boundary and reference concentration are also elaborated.     

Hydrologic implications of the isotopic kinetic fractionation of open-water evaporation

The kinetic fractionation of open-water evaporation against the stable water isotope H_2 ~(18)O is an important mechanism underlying many hydrologic studies that use ~(18)O as an isotopic tracer. A recent in-situ measurement of the isotopic water vapor flux over a lake indicates that the kinetic effect is much weaker(kinetic factor 6.2‰) than assumed previously(kinetic factor14.2‰) by lake isotopic budget studies. This study investigates the implications of the weak kinetic effect for studies of deuterium excess-humidity relationships, regional moisture recycling, and global evapotranspiration partitioning. The results indicate that the low kinetic factor is consistent with the deuterium excess-humidity relationships observed over open oceans.The moisture recycling rate in the Great Lakes region derived from the isotopic tracer method with the low kinetic factor is a much better agreement with those from atmospheric modeling studies than if the default kinetic factor of 14.2‰ is used. The ratio of transpiration to evapotranspiration at global scale decreases from 84±9%(with the default kinetic factor) to 76±19%(with the low kinetic factor), the latter of which is in slightly better agreement with other non-isotopic partitioning results.     

Performance spectra based method for the seismic design of structures equipped with passive supplemental damping systems

A new direct performance‐based design method utilizing design tools called performance‐spectra (P‐Spectra) for low‐rise to medium‐rise frame structures incorporating supplemental damping devices is presented. P‐Spectra are graphic tools that relate the responses of nonlinear SDOF systems with supplemental dampers to various damping parameters and dynamic system properties that structural designers can control. These tools integrate multiple response quantities that are important to the performance of a structure into a single compact graphical format to facilitate direct comparison of different potential solutions that satisfy a set of predetermined performance objectives under various levels of seismic hazard. An SDOF to MDOF transformation procedure that defines the required supplemental damping properties for the MDOF structure to achieve the response defined by the target SDOF system is also presented for hysteretic, linear viscous and viscoelastic damping devices. Using nonlinear time‐history analyses of idealized shear structures, the accuracy of the transformation procedure is verified. A seismic performance upgrade design example is presented to demonstrate the usefulness of the proposed method for achieving design performance goals using supplemental damping devices. Copyright © 2012 John Wiley & Sons, Ltd.