华北地区煤的显微组分结焦性热台试验

为探讨煤的显微组分的结焦性，对不同变质程度煤的镜质组、壳质组和惰性组分别进行了显微镜热台加热试验．在加热过程中，活性组分经历了３个明显不同的变化阶段，即变形阶段、胶质体形成阶段以及固化阶段．随煤变质程度的增加，镜质组的初变温度和胶质体形成时的温度逐渐增大，而固结温度变化规律不明显；壳质组在低变质阶段因受热而挥发掉，但随煤级增高其变形程度减弱；半镜质组在受热过程中也有变形和少量胶质体形成，而惰性组只发生微弱变化．在低变质阶段，活性显微组分形成的焦炭显微结构以各向同性为主；随变质程度的增高，焦炭显微结构中各向异性成分比例增大     

老湾花岗质熔体中水的演化

老湾花岗质熔体中水的演化特征表明,随着岩浆熔体的演化,溶解于熔体中的水经历不饱和→饱和→过饱和的过程以及在过饱和状态下水以气泡形式逸出熔体,成矿流体的气泡逸出可能是“含矿岩浆热液”形成的主要方式。     

The Lower Changjiang (Yangzi/Yangtze River) metallogenic belt, east central China: intrusion- and wall rock-hosted Cu–Fe–Au, Mo, Zn, Pb, Ag deposits

The lower valley of Changjiang, from Wuhan of the Hubei Province in the west to Zhenjiang of the Jiangsu Province in the east, contains more than 200 polymetallic (Cu–Fe–Au, Mo, Zn, Pb, Ag) deposits and is one of the most important metallogenic belts in China. This metallogenic belt, situated at the northern margin of the Yangzi craton and bordered by the Dabieshan ultrahigh pressure metamorphic belt to the north, consists mainly of Cambrian–Triassic marine clastic sedimentary rocks and carbonate and evaporite rocks, which overlay a Precambrian basement and are intruded by Yanshanian (205 to 64 Ma) granitoid intrusions and subvolcanic complexes. Repeated tectonism from Late Proterozoic to Triassic resulted in extensively developed networks of faults and folds involving the Cambrian–Triassic sedimentary strata and the Precambrian basement. The Yanshanian granitoid intrusions and subvolcanic complexes in the Lower Changjiang metallogenic belt are characterized by whole-rock δ¹⁸O of +8‰ to +10‰, initial ⁸⁷Sr/⁸⁶Sr of 0.704 to 0.708, and εNd^t from −10 to −17 and have been interpreted to have originated from mixing between juvenile mantle and old crustal materials. Also, the Yanshanian granitoids exhibit eastward younging and increase in alkalinity (i.e., from older calc–alkaline in the west to younger subalkaline–alkaline in the east), which are related to oblique collision between the Yangzi and Sino-Korean cratons and tectonic evolution from early compressional to late extensional or rifting regimes. Most polymetallic deposits in the Lower Changjiang metallogenic belt are clustered in seven districts where the Yanshanian magmatism is particularly extensive: from west to east, Edong, Jiurui, Anqing–Guichi, Luzhong, Tongling, Ningwu and Ningzhen. Mineralization is characterized by the occurrence of three distinct types of orebodies in individual deposits: orebodies in Yanshanian granitoid intrusions, skarn orebodies at the contact zones between the Yanshanian intrusions and Late Paleozoic–Early Mesozoic sedimentary rocks, and stratabound massive sulfide orebodies in the Late Paleozoic–Early Mesozoic sedimentary strata. The most important host sedimentary strata are the Middle Carboniferous Huanglong Formation, Lower Permian and Lower–Middle Triassic carbonate and evaporite rocks. The intrusion-hosted and skarn orebodies exhibit well-developed zonation in alteration assemblages, metal contents, and isotopic compositions within individual deposits, and apparently formed from hydrothermal activities related to the Yanshanian magmatism. The stratabound massive sulfide orebodies in the Late Paleozoic–Early Mesozoic sedimentary strata have long been suggested to have formed from sedimentary or volcano-sedimentary exhalative processes in shallow marine environments. However, extensive research over the last 40 years failed to produce unequivocal evidence for syngenetic mineralization. On the basis of geological relationships and isotope geochemical characteristics, we propose a carbonate-hosted replacement deposit model for the genesis of these stratabound massive sulfide orebodies and associated skarn orebodies. This model suggests that epigenetic mineralization resulted from interactions between magmatic fluids evolved from the Yanshanian intrusions with carbonate and evaporite wall rocks. Mineralization was an integral but distal part of the larger hydrothermal systems that formed the proximal skarn orebodies at the contact zones and the intrusion-hosted orebodies. The stratabound massive sulfide deposits of the Lower Changjiang metallogenic belt share many features with the well-studied, high-temperature, carbonate-hosted replacement deposits of northern Mexico and western United States, particularly with respect to association with small, shallow granitoid complexes, structural and stratigraphic controls on mineralization, alteration assemblages, geometry of orebodies, metal association, metal zonation and isotopic systematics.     

鄂尔多斯盆地早侏罗世富县期沉积演化: 大洋缺氧事件前后陆地气候变化的响应*

托阿尔期早期早侏罗世大洋缺氧事件(T-OAE,~183.8 Ma)是一次全球性的地质事件,鄂尔多斯盆地下侏罗统富县组记录了此次地质事件的陆地响应过程。主要基于盆地东缘野外地质调查、扫描电镜及薄片分析,本次研究描述了盆地东北部富县组岩性、颜色和沉积序列,利用前人研究成果总结了富县期岩相古地理变化规律及沉积模式,认为富县期经历了由干旱到湿润的古气候变化: 富县组下部含植物化石较为丰富的白色砂砾岩及黑色、灰色泥页岩沉积于湿润气候时期,对应着盆地下切河谷发育期和填平补齐期; 而上覆的罕见植物化石的杂色、红色泥页岩为(富县期晚期)相对平坦地形条件下的沉积,对应着早、中侏罗世湿润气候背景下的一次干旱气候脉动,为托阿尔期大洋缺氧事件在陆相环境的气候响应,可由此进行富县组区域等时性对比。研究认为“粗富县”为下切谷内河流充填沉积, “细富县”形成于湖泊环境或河漫环境, “黑富县”和“白富县”是湿润气候条件下沉积产物,而“红富县”和“杂富县”为T-OAE期后干旱条件下形成。     

Electron Probe Microanalysis of Bromine in Minerals and Glasses with Correction for Spectral Interference from Aluminium,and Comparison with Microbeam Synchrotron X‐Ray Fluorescence Spectrometry

The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al₂O₃ content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g^?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g^?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g^?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g^?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses.     

海底扩散体系含天然气水合物沉积物制样方法与装置

天然气水合物是分布在海洋和大陆多年冻土中的一种具有巨大商业开发价值的新型战略性替代能源。同时,含天然气水合物地层中水合物的分解将带来严重的地质灾害和气候问题的关注。试验室内开展含天然气水合物沉积物物理力学性质研究需要首先解决的是制样问题,即在试验室内快速形成符合现场原位形成模式的试样,并且水合物均匀分布于土样孔隙中。海洋天然气水合物主要是在扩散体系中形成的,即溶解在水中的气体以扩散迁移的方式进入温压条件适合的地层内与水结合生成天然气水合物。文中试验方法与装置利用高压恒流泵驱动溶有气体的去离子水在土样中循环,采用磁力搅拌装置加速和增大气体在水中的溶解,使土样在较短时间内被溶气水饱和,然后将土样温度降低至与气体压力相对应的相变温度以下后,溶于水中的气体与水结合生成水合物析出,且均匀地填充土样孔隙中。采用粉土和CO2气体试验表明,制得含水合物沉积物大约需1 d的时间,通过观察和测试含水率证明,所制得试样具有良好的均匀性,解决了目前在试验中采用的制样方法所制得的试样中水合物分布不均匀以及水合物形成时间过长的问题,为进一步开展含天然气水合物沉积物物理力学试验提供了技术保证     

中国侏罗系煤成油若干问题

在阐述了煤成油的概念，总结和评述了煤生油显微组分，生油门限，生油范围和生油高峰等问题后，本文通过吐哈等盆地侏罗系煤生油显微组分组成特征，可溶有机质演化，成熟度和有机质丰度，油源及原油成熟度对比；含煤岩系中煤层和泥岩的厚度及总量和煤及泥岩最高沥青和总烃转化率的对比； 其族组成和煤成原油的族组成特征的对比，提出了中国侏罗系煤成油盆地中泥岩比煤层对煤成油田形成有大的贡献看法。     

致密砂岩储层含气测井特征及定量评价

致密砂岩储层孔隙度低、渗透率低、非均质性强,气层所对应的测井响应特征较为复杂,气层识别和评价难度较大、多解性突出。传统上,利用常规测井曲线进行含气性评价多是定性评价,在利用智能识别法评价含气性时,也是利用分类模型进行定性评价;而利用常规测井资料定量评价含气性比较困难。本文首先以岩心、地质、试气资料和常规测井曲线为基础,利用交会图法进行致密砂岩含气特征分析,建立含气性定性评价指标;然后,利用广义回归神经网络（GRNN）预测含气量和含水量,构造含气性和含水性指示曲线,定量评价致密砂岩的含气性;最后,定性评价和定量评价综合使用,以评价致密砂岩含气性,并在苏里格地区盒₈段进行应用,取得了较好的应用效果。     

沉积学研究热点与进展:第32届国际沉积学会议综述*

第32届国际沉积学会议(32nd IAS Meeting of Sedimentology)于2016年5月23—25日在摩洛哥马拉喀什召开, 来自43个国家和地区的360余名学者参加了本次会议。综述研究表明, 会议研究热点为陆相沉积环境、浅水沉积与滨岸潮汐、深水沉积与事件沉积、碳酸盐与化学岩沉积、沉积过程与盆地分析、成岩作用与油气储集层等研究领域。会议主要研究进展表现为: 波浪再悬浮作用(wave resuspension)与异重流(hyperpycnal flows)是陆架边缘斜坡快速进积的主要因素;海啸发生周期为14~35, ka, 后积层理(backset-bedding)为海啸沉积识别标志;海底滑坡多由海底地震、天然气水合物泄露等触发, 其块状搬运沉积物(MTD)包括滑塌头部、滑动底面、滑塌主体以及滑塌后期浊流沉积;玄武岩等基岩的风化作用提供硅与富镁碱性水, 有利于菱沸石与白云石的形成;受构造作用影响, 隆起剥蚀区与沉积区可互为转化;物源性质、供给量及搬运或分散过程控制了沉积面貌(源汇系统);构造活动直接控制可容纳空间变化、地貌变化、源区剥蚀速率、沉积物供应速率等。最后, 本文对比了中外沉积学发展差异, 讨论了中国沉积学发展方向。