火试金法测定铜精矿中金含量结果的不确定度评定

对火试金法测定铜精矿中金含量的结果进行不确定度评定。分析了铜精矿样品称量、铜精矿样品的不均匀性和配料处理,以及金粒称量等因素对金含量测量结果不确定度的影响,并得出火试金法测量铜精矿中金含量的扩展不确定度。     

Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain

Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO₃ type water with depleted δ¹⁸O and δD (mean value of −8.8‰ δ¹⁸O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO₃–Cl–SO₄ type), and heavier δ¹⁸O and δD were observed (around −8‰ δ¹⁸O). Before the surface water with mean δ¹⁸O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ¹⁸O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO₃, Na–HCO₃, to Na–SO₄. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.     

Microbial release of potassium from K-bearing minerals by thermophilic fungus Aspergillus fumigatus

A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles.     

两千年来黑河流域水资源平衡估算与下游水环境演变驱动分析

利用地方史志、历史地理、树木年轮和近代器测记录相关的黑河流域历史时期人口变动、水土资源开发利用、下游湖泊变化、流域水资源和气候变化等资料, 通过对比上游出山水资源量、中游人类活动水资源利用量和下游湖泊面积变化, 在千年-百年时间尺度上对流域水资源平衡进行了估算, 并分析了历史时期各阶段下游湖泊水环境和天然绿洲演变过程和驱动机制. 研究结果表明: 在黑河流域, 气候变化条件下的上游山区水资源总量和中游走廊平原区绿洲人类活动用水后下泄的水资源量, 决定了下游水环境演变过程;在两千年来显现出不同历史阶段的流域水资源平衡模式和下游水环境演变特征, 以及气候变化和人类活动在不同历史时期的耦合驱动机制.     

中祁连东段什川杂岩基的岩石化学特征及年代学研究

祁连造山带被托菜南山-了高山构造带及宗务隆山-贵得构造带分为北祁连、中祁连及南祁连构造带。什川岩基位于中祁连构造带东部,由闪长岩、斜长花岗岩、二长花岗岩组成;对二长花岗岩进行U-Pb单颗粒锆石微区LA-ICP-MS同位素测定,获得444.6Ma及414.3Ma两组加权平均年龄,前者代表岩石的形成年龄,后者代表构造热事件年龄。二长花岗岩主量元素W(SiO_2)=68.66%～80.77%,w(K_2O)/w(Na_2O)>1和A/CNK介于0.95～1.21间,总体为钾质钙碱性过铝质花岗岩。岩石富集LILE元素(K、Th、Rb、Ba等),亏损HFSE元素(Ta、Nb、Y等);稀土元素总量较高(∑REE多介于109.05×10~(-6)～322.66×10~(-6)),轻重稀土强烈分馏(∑LREE/∑HREE介于7.92～31.68),稀土元素分配模式为轻稀土富集型,具中等-强Eu负异常(δEu=0.26～0.58)。岩石矿物组合及岩石地球化学特征共同表明,什川岩基为中上地壳泥砂质岩石部分熔融而成,形成温度较低,为加厚地壳拆沉熔融成因。这为祁连造山带构造演化及其深部动力学机制研究提供了新的资料。     

Copula函数在多变量水文分析计算中的应用及研究进展

综述了多变量水文分析计算方法及存在的问题.系统地介绍了Copula函数的基本理论与方法,分析探讨Copula函数在多变量水文计算领域的适用性及优越性.总结了Copula函数应用的关键技术,包括参数估计、拟合检验及类型选择等,并展望了Copula函数的研究应用前景.     

长牡蛎碱性磷酸酶的分离纯化及部分性质研究

本文以长牡蛎为酶源提取材料,用正丁醇抽提,硫酸铵分级分离,DEAE-52和Sephadex G-100柱层析,得到一定纯度的碱性磷酸酶,提纯倍数为61.96,比活力达1.326U/mg.该酶的最适pH值9.6,最适温度38℃,初速度6.8μmol/(dm~3·min),米氏常数Km值为1.30mmol/dm~3.实验结果表明,Mg~(2+)对该酶有明显的激活作用;Zn~(2+)、Cu~(2+)、Hg~(2+)对该酶有明显的抑制作用.     

高压技术在深海沉积物兼性嗜压菌的筛选和鉴定中的应用

通过自行改进的高压培养罐及高压设备,对深海沉积物进行可培养微生物的筛选,获得6株具有较强耐受压力的细菌.16SrDNA的测序结果表明这些细菌分别属于6个不同的菌属.压力生长试验的结果表明这6株细菌在40MPa的条件下仍然具有较强的生长能力,属于兼性嗜压菌.对不同压力下生长的细菌做显微镜检,结果显示,除了一株芽孢杆菌在40MPa下的菌体形态发生了明显的变化外,其它5株细菌在压力条件下的菌体的分裂均没有受到明显的影响.     

机载雷达高度计对海况及海面风速的测量研究

运用我国自行研制的ＺＨＧ－１型Ｘ波段机载雷达高度计于１９９５年４月１３日－４月１８日在青岛附近海域进行的海上飞行实验数据，及导出的均方根波高、有效波高、均方根波陡算法模型，得到了上述海况参数值。     

黄海的风、潮混合特征及其对冷水团边界的影响

本文第一作者早在1985年就提出,潮混合效应控制着夏季黄海冷水团的边界及海面冷水分布(赵保仁,1985)。1987年又进一步通过水文调査资料和卫星图片给出了黄海周围的浅水陆架锋(或称潮汐锋)的分布及强锋区的跨锋断面中的温度、盐度和坏流结构特征,并指出夏季的黄海沿岸流在性质上属沿锋面运动的强流(赵保仁,1987a,b),而后又对黄海西部的陆架锋进行了一次专门调査(赵保仁等,1991)。此外,他还指出黄海的强温跃层的形成和转移现象也与潮混合现象密切相关(赵保仁,1989)。因此,研究潮混合现象对阐明发生在黄海的多水文物理现象都是至关重要的。 为深入了解黄海的潮混合特征,作者把渤海、黄海和东海作为一个整体完成了一次精度较高的潮汐、溯流数值计算,在潮汐、潮流的分布方面,揭示了前人尚未阐明的一些特征。本文根据这些数值结果,计算了近最大潮流流速和层化参数,阐明了渤海、黄海和东海的潮混合特征及其对降温期黄海冷水团分布变化的影响。此外,还用 Sim pson等人(1981)的能量模式计算了南黄海西部的风、潮混合效率。