A magnetic study of Etruscan bucchero pottery: An application of rock magnetism to archaeometry

We have applied techniques used in rock magnetism to the study of possible temporal changes in provenance and firing conditions of a collection of Etruscan bucchero pottery fragments representing the interval between 800 B.C. to 400 B.C. To our knowledge, this is the first time that such procedures have been applied to ancient ceramic wares. Our preliminary magnetic measurements demonstrate that this approach can provide useful archaeological information, as exemplified by the following results: (1) Bucchero ceramic styles sottile, spesso, and possibly pesante, contained magnetic particles of similar grain sizes, which suggested a common provenance and similar firing conditions for these pot typologies. (2) Ceramic styles buccheroid impasto and grey bucchero each had magnetic characteristics different from those in (1). However, too few samples of these were available for any definite conclusions. (3) The occurrence of magnetite, and not hematite, in all samples indicated that firing conditions were effectively reducing. (4) Variations in the amount of magnetite in different samples indicated that slight inhomogeneities must have existed in the iron oxide/hydroxide content of the local clay source. Most magnetic techniques are fast, easy, and generally nondestructive. Some magnetic properties, such as initial susceptibility, saturation remanent magnetization, and coercivity of remanence, can even be measured in the field. At the least, magnetic measurements can be used initially to discriminate among different groups of potsherds. Selected samples can then be analyzed with more elaborate methods of archaeometry.     

Molluscan assemblages from archaeological deposits

Research about the impact of prehistoric human subsistence strategies upon prey populations of shellfish is based on the assumption that trends in shell size are directly related to collection strategies. A shell midden on San Juan Island, Washington, where archaeological research is sponsored by the University of Washington and hosted by the National Park Service, provides large samples of shells from separate archaeological deposits. the shells from each deposit produce size-frequency distributions that vary in shape (modality). Because several factors (the original prey population, the method of collection and transport, the environment of deposition, and post-depositional processes) affect the size-frequency distribution differentially, the shell measurements do not provide the direct archaeological information expected.     

Arsenic in sediments, groundwater, and streamwater of a glauconitic Coastal Plain terrain, New Jersey, USA—Chemical “fingerprints” for geogenic and anthropogenic sources

Glauconite-bearing deposits are found worldwide, but As levels have been determined for relatively few. The As content of glauconites in sediments of the Inner Coastal Plain of New Jersey can exceed 100 mg/kg, and total As concentrations (up to 5.95 μg/L) found historically and recently in streamwaters exceed the State standard. In a major watershed of the Inner Coastal Plain, chemical “fingerprints” were developed for streambed sediments and groundwater to identify contributions of As to the watershed from geologic and anthropogenic sources. The fingerprint for streambed sediments, which included Be, Cr, Fe and V, indicated that As was predominantly of geologic origin. High concentrations of dissolved organic C, nutrients (and Cl⁻) in shallow groundwater indicated anthropogenic inputs that provided an environment where microbial activity released As from minerals to groundwater discharging to the stream. Particulates in streamwater during high flow constituted most of the As load; the chemical patterns for these particulates resembled the geologic fingerprint of the streambed sediments. The As/Cr ratio of these suspended particles likely indicates they derived not only from runoff, but from groundwater inputs, because As contributed by groundwater is sequestered on streambed sediments. Agricultural inputs of As were not clearly identified, although chemical characteristics of some sediments indicated vehicle-related inputs of metals. Sediment sampling during dry and wet years showed that, under differing hydrologic conditions, local anthropogenic fingerprints could be obscured but the geologic fingerprint, indicating glauconitic sediments as an As source, was robust.     

Subsurface hydrology of tile-drained headwater catchments: Compatibility of concepts and hydrochemistry

Concepts and terms used in previous multidisciplinary studies of tile-drained aquitard-dominated catchments (TDADC) are inconsistent and confusing. We provide a well-defined, comprehensive conceptual model of the subsurface hydrology of TDADC by selecting seven mutually compatible and consistent concepts. These concepts are: (1) groundwater as the main source of baseflow in headwater streams, (2) dominance of ‘pre-event’ water in stormflow, (3) importance of both macropores and matrix, (4) changes in flowpaths with rate of stream discharge, (5) dominance of shallow, lateral subsurface flow, (6) interactive nature of subsurface water, (7) transpiration of groundwater. This conceptual model was successfully ‘field-tested’ by examining data collected in a TDADC in a rural area of southern Ontario, Canada. The data consist mainly of chemical and isotopes tracers in water samples (headwater streams, groundwater, precipitation, tile water, soil-surface water), supplemented by water levels and meteorological data.     

Baseflow and peakflow chemical responses to experimental applications of ammonium sulphate to forested watersheds in north‐central West Virginia,USA

Stream water was analysed to determine how induced watershed acidification changed the chemistry of peakflow and baseflow and to compare the relative timing of these changes. Two watersheds in north‐central West Virginia, WS3 and WS9, were subjected to three applications of ammonium sulphate fertilizer per year to induce acidification. A third watershed, WS4, was the control. Samples were collected for 8 years from WS9 and for 9 years from WS3. Prior to analyses, concentration data were flow adjusted, and the influence of natural background changes was removed by accounting for the chemical responses measured from WS4. This yielded residual values that were evaluated using robust locally weighted regression and Mann–Kendall tests. On WS3, analyte responses during baseflow and peakflow were similar, although peakflow responses occurred soon after the first treatment whereas baseflow responses lagged 1–2 years. This lag in baseflow responses corresponded well with the mean transit time of baseflow on WS3. Anion adsorption on WS3 apparently delayed increases in SO₄ leaching, but resulted in enhanced early leaching losses of Cl and NO₃. Leaching of Ca and Mg was strongly tied, both by timing and stoichiometrically, to NO₃ and SO₄ leaching. F‐factors for WS3 baseflow and peakflow indicated that the catchment was insensitive to acid neutralizing capacity reductions both before and during treatment, although NO₃ played a large role in reducing the treatment period F‐factor. By contrast, the addition of fertilizer to WS9 created an acid sensitive system in both baseflow and peakflow. On WS9, baseflow and peakflow responses also were similar to each other, but there was no time lag after treatment for baseflow. Changes in concentrations generally were not as great on WS9 as on WS3, and several ions showed no significant changes, particularly for peakflow. The lesser response to treatment on WS9 is attributed to the past abusive farming and site preparation before larch planting that resulted in poor soil fertility, erosion, and consequently, physical and chemical similarities between upper and lower soil layers. Even with fertilizer‐induced NO₃ and SO₄ leaching increases, base cations were in low supplies and, therefore, unavailable to leach via charge pairing. The absence of a time lag in treatment responses for WS9 baseflow indicates that it has substantially different flow paths than WS3. The different hydrologies on these nearby watersheds illustrates the importance of understanding watershed hydrology when establishing a monitoring programme to detect ecosystem change. Published in 2002 by John Wiley & Sons, Ltd.     

A comparison of multifrequency HF radar and ADCP measurements ofnear-surface currents during COPE-3

A high-frequency multifrequency coastal radar operating at four frequencies between 4.8 and 21.8 MHz was used as part of the third Chesapeake Bay Outflow Plume Experiment (COPE-3) during October and November, 1997. The radar system surveyed the open ocean east of the coast and just south of the mouth of Chesapeake Bay from two sites separated by about 20 km. Measurements were taken once an hour, and the eastward and northward components of ocean currents were estimated at four depths ranging from about 0.5 m to 2.5 m below the surface for each location on a 2 by 2 km grid. Direction of arrival of the signals was estimated using the MUSIC algorithm. The radar measurements were compared to currents measured by several moored acoustic Doppler current profilers (ADCPs) with range bins 2-14 m below the water surface. The vertical structure of the current was examined by utilizing four different radar wavelengths, which respond to ocean currents at different depths, and by using several ADCP range bins separated by 1-m intervals. The radar and ADCP current estimates were highly correlated and showed similar depth behavior, and there was significant correlation between radar current estimates at different wavelengths and wind speed