Secondary Silicates as a Barrier to Carbon Capture and Storage in Deccan Basalt

Investigating the immobilization of CO₂,previous basalt-water-CO₂ interaction studies revealed the formation of carbonates over a short period,but with the extensive formation of secondary silicates(SS).The mechanisms involved in these processes remain unresolved,so the present study was undertaken to understand secondary mineral formation mechanisms.XRPD and Rietveld refinement data for neo-formed minerals show a drastic decrease in the Ca-O bond length,with the calcite st...     

EFFECT OF VERTICAL CONTACT ON WENNER RESISTIVITY SOUNDINGS*

The allowance for the influence of a vertical contact is evaluated on Wenner resistivity sounding curves, which are graphically constructed on bilogarithmic paper over simple composite earth models consisting of a vertical contact separating two- or three layered earth on one side and a homogeneous medium on the other side. The error incurred in the graphical constructions is explored. Finally, the use of these graphically constructed sounding curves is shown in the interpretation of two Wenner field soundings measured in a complex geologic area.     

THE BLIND-ZONE PROBLEM IN MULTIPLE REFRACTION-LAYER OVERBURDEN SITUATIONS*

The blind zone problem is examined with a view to provide a simple means of solving the problem in the general case of arbitrary number of refraction layers constituting the overburden to the masked layers. Considering the first arrival refraction interval corresponding to the masked layer which reduces to zero under blind zone conditions, a method to solve the problem is presented. Derivation of the critical distance expression is also included and convenient solutions to compute the thicknesses of the blind zone and its immediate overlayer are worked out. Based on test calculations on some known instances, the efficacy of the method is illustrated. A Fortran program for use when large numbers of refraction layers are involved under the overburden or when more than one masked layer is encountered is available from the authors.     

TRANSIENT ELECTROMAGNETIC RESPONSE OF A CONDUCTING SPHERE EXCITED BY DIFFERENT TYPES OF INPUT PULSES*

A technique utilizing the convolution theorem is developed to obtain the time-domain electromagnetic response for a number of input pulses from the given step-function response. For illustration an idealized model of a homogeneously conducting non-permeable sphere placed in a uniform field is considered. The nature of the responses due to different types of pulses and their usefulness in estimating the constitution parameter of the sphere are discussed. To show the applicability of the suggested technique to generalized systems, calculations for a conducting permeable sphere are presented in the appendix.     

Anomalous Mössbauer parameters in the second generation regolith Ghubara meteorite

Abstract— We conducted Mössbauer spectroscopic studies on the Ghubara meteorite which had been described as at least two‐generation regolith breccia on the macro scale. The isomer shift and quadrupole splitting of the Fe‐Ni part are quite different from those obtained in ordinary chondrites, reflecting shock effects. We observed a large amount of magnetite that may have come from weathering of, primarily, the silicate fraction. We found very similar iron mineralogy in the Densmore meteorite.     

Analytical solution of advection–diffusion equation in heterogeneous infinite medium using Green’s function method

Some analytical solutions of one-dimensional advection–diffusion equation (ADE) with variable dispersion coefficient and velocity are obtained using Green’s function method (GFM). The variability attributes to the heterogeneity of hydro-geological media like river bed or aquifer in more general ways than that in the previous works. Dispersion coefficient is considered temporally dependent, while velocity is considered spatially and temporally dependent. The spatial dependence is considered to be linear and temporal dependence is considered to be of linear, exponential and asymptotic. The spatio-temporal dependence of velocity is considered in three ways. Results of previous works are also derived validating the results of the present work. To use GFM, a moving coordinate transformation is developed through which this ADE is reduced into a form, whose analytical solution is already known. Analytical solutions are obtained for the pollutant’s mass dispersion from an instantaneous point source as well as from a continuous point source in a heterogeneous medium. The effect of such dependence on the mass transport is explained through the illustrations of the analytical solutions.     

USE OF ELECTRICAL RESISTIVITY METHODS FOR THE STUDY OF COAL SEAMS IN PARTS OF THE RANIGANJ COALFIELD (INDIA)*

The surface resistivity method has been used to study a few exposed coal seams located in the northwestern part of the Raniganj Coalfield (belonging to the Damodar Valley Gondwana basin), India. Different electrode configurations, viz., Wenner, two-electrode and half-Schlumberger, have been used with different electrode spacings in horizontal profiling. The vertical distribution of resistivity has been studied using Schlumberger configuration at different locations along the profile. Laboratory studies of resistivity (at partial to full water saturation conditions) and porosity of different coal, shaly sandstone and sandstone samples of the survey area had already been carried out before the field survey. The results indicated the presence of a good resistivity contrast between the coal seams and the surrounding formations. The field results did not bear this out: the resistivity responses of the coal formations on the profiles and sounding curves are not as clear as one would expect for such high contents. The Wenner profiles show a broad resistivity anomaly over the coal seams. Two-electrode profiles are less noisy than Wenner profiles. Sharp peaks have been observed over the coal seams. The half-Schlumberger configuration seems the best: all the coal seams and their edges can be accurately outlined on the resistivity curves. Borehole data close to the profile have been used for correlating the field results. There is good agreement with vertical electrical soundings.     

Inlet sequence: a vertical succession of sedimentary structures and textures created by the lateral migration of tidal inlets

Tidal inlets, narrow, comparatively deep gaps between barrier islands, are channels through which tidal currents flow vigorously as the water enters and leaves the backbarrier lagoons, bays, and intertidal flats and marshes. Many geologists have compared tidal inlets to river channels and have speculated that if an inlet shifts laterally, it should deposit a distinctive sequence of sediments, analogous to the point-bar sequence left by a meandering stream channel. Fire Island Inlet, located 56 km east of New York City, has migrated WSW at a mean rate of 64 m/year during the period 1825–1940. Waves approaching the coast, predominantly from the southeast, have shifted sediment along the shore toward the WSW. Deposition of sediment on the east side of the inlet has forced the tidal currents to erode the west side of the inlet, thus causing lateral migration. Because hydraulic conditions vary from the channel floor to the subaerial part of the spit which is present on the ENE side of the channel, sedimentary structures and textures vary systematically with depth. We have determined the various sedimentary environments associated with the modern Fire Island Inlet, sampled and described the sediments from these environments, and have collected samples from corings made on that part of Fire Island through which the inlet has migrated. On the basis of our studies, we propose an inlet sequence which is formed by the lateral migration of a tidal inlet. The sequence includes five major units, as follows on p. 492. The sediments belonging to various units in this sequence have been identified in four borings made on those parts of Fire Island through which the Fire Island Inlet has migrated since 1825. This sequence should be applicable to other inlets also. We think that the boundary between deep channel and shallow channel units remains relatively fixed at ?4.5 m, whereas the thickness of the deep channel unit is determined by the depth range between ?4.5 m and the total depth of the inlet. Hence, the main source of variation in the inlet sequence will be the thickness of the deep-channel unit. Most of the sediments of the inlet sequence are incised below mean low water; hence they will almost certainly be preserved in the geologic record, even if all other associated sediments from barrier environments located above mean low water are not preserved. Because of the great variability possible in rates of lateral migration of inlets along the shore compared with the rates of barrier displacement perpendicular to the shore, inlet sediments may be preserved as elongate lenses, or as widespread blankets. The shape of inlet deposits reveals much about the behaviour of barriers during a submergence. Hence, inlet sediments should shed new light on sediments of the continental shelves and on basal transgressive sands in the geologic record.