Stratigraphy and depositional setting of slurry and contained (reflected) beds in the Marnoso‐arenacea Formation (Langhian‐Serravallian) Northern Apennines,Italy

This work presents the stratigraphy and facies analysis of an interval of about 2500 m in the Langhian and Serravallian stratigraphic succession of the foredeep turbidites of the Marnoso‐arenacea Formation. A high‐resolution stratigraphic analysis was performed by measuring seven stratigraphic logs between the Sillaro and Marecchia lines (60 km apart) for a total thickness of about 6700 m. The data suggest that the stratigraphy and depositional setting of the studied interval was influenced by syndepositional structural deformations. The studied stratigraphic succession has been subdivided into five informal stratigraphic units on the basis of how structurally controlled topographic highs and depocentres, a consequence of thrust propagation, change over time. These physiographic changes of the foredeep basin have also been reconstructed through the progressive appearance and disappearance of thrust‐related mass‐transport complexes and of five bed types interpreted as being related to structurally controlled basin morphology. Apart from Bouma‐like Type‐4 beds, Type‐1 tripartite beds, characterized by an internal slurry unit, tend to increase especially in structurally controlled stratigraphic units where intrabasinal topographic highs and depocentres with slope changes favour both mud erosion and decelerations. Type‐2 beds, with an internal slump‐type chaotic unit, characterize the basal boundary of structurally controlled stratigraphic units and are interpreted as indicating tectonic uplift. Type‐3 beds are contained‐reflected beds that indicate different degrees of basin confinement, while Type‐5 are thin and fine‐grained beds deposited by dilute reflected turbulent flows able to rise up the topographic highs. The vertical and lateral distribution of these beds has been used to understand the synsedimentary structural control of the studied stratigraphic succession, represented in the Marnoso‐arenacea Formation by subtle topographic highs and depocentres created by thrust‐propagation folds and emplacements of large mass‐transport complexes.     

Recognition of ancient carbonate wind deposits: lessons from a modern analogue, Chrissi Island, Crete

Carbonate aeolian deposits are common along arid to semiarid, wind-exposed, present-day coastlines bordered by productive carbonate ramps. Lithified carbonate dunes (aeolianites) have been described around the world in marine terraces of Quaternary age, but these deposits have seldom been identified in the Pre-Quaternary record. Several authors have suggested that this scarcity reflects that these deposits form and are preserved only during icehouse periods characterized by high-amplitude sea-level changes. Others [e.g. McKee and Ward Carbonate Depositional Environments (1983) , AAPG Memoirs, Vol. 33, pp. 131–170] suggest that the scarcity of aeolianites in the Pre-Quaternary record could reflect the ‘great difficulty in recognising wind blown carbonate deposits and in differentiating between them [aeolianites] and other carbonate sands of nearshore environments’. It has been considered that carbonate shoreface/foreshore deposits are very difficult to discriminate petrographically from backshore deposits. This petrographic study of recent sediments from the shoreface to backshore along the northern coast of Chrissi Island, Crete, confirms that carbonate aeolian sands can be very easily misinterpreted as shoreface deposits. Textural examination of thin sections by image analysis techniques indicates, however, that grain orientation patterns differ between facies. Shoreface deposits exhibit a unimodal distribution of grain orientation (flat rose diagram), whereas backshore deposits show a tendency towards a bimodal distribution with a significant proportion of vertical grains. This observation has been confirmed in Pleistocene aeolianites from Tunisia and Western Australia. Grain verticality thus seems to be a reliable criterion for discriminating wind-lain carbonate bodies from shoreface deposits. Vertical grains in aeolian carbonate deposits could reflect gravity effects (e.g. reorientation of grains because of meteoric water percolation and air pull-up). Laboratory experiments conducted on carbonate sands under the action of percolating waters confirm this hypothesis. This reorganization process is preferentially developed in recently deposited and loosely packed sands resulting from grainfall and/or grainflow. In addition, this suggests that the presence of vertical grain orientation might be an indicator of the frequency and intensity of rainfalls during deposition.     

Experimental Investigation and Optimization of Thermodynamic Properties and Phase Diagrams in the Systems CaO-SiO2, MgO-SiO2, CaMgSi2O6-SiO2 and CaMgSi2O6-Mg2SiO4 to 1{middle dot}0 GPa

Using experimental results at 1·0 GPa for the systemsCaO–SiO₂, MgO–SiO₂, CaMgSi₂O₆–SiO₂ and CaMgSi₂O₆–Mg₂SiO₄,and all the currently available phase equilibria and thermodynamicdata at 1 bar, we have optimized the thermodynamic propertiesof the liquid phase at 1·0 GPa. The new optimized thermodynamicparameters indicate that pressure has little effect on the topologyof the CaO–SiO₂, CaMgSi₂O₆–SiO₂, and CaMgSi₂O₆–Mg₂SiO₄systems but a pronounced one on the MgO–SiO₂ binary. Themost striking change concerns passage of the MgSiO₃ phase fromperitectic melting at 1 bar to eutectic melting at 1·0GPa. This transition is estimated to occur at 0·41 GPa.For the CaMgSi₂O₆–SiO₂ and CaMgSi₂O₆–Mg₂SiO₄ pseudo-binaries,the size of the field clinopyroxene + liquid increases withincreasing pressure. This change is related to the shift ofthe piercing points clinopyroxene + silica + liquid (from 0·375mol fraction SiO₂ at 1 bar to 0·414 at 1·0 GPa)and clinopyroxene + olivine + liquid (from 0·191 molfraction SiO₂ at 1 bar to 0·331 at 1·0 GPa) thatbound the clinopyroxene + liquid field in the CaMgSi₂O₆·SiO₂and CaMgSi₂O₆·Mg₂SiO₄ pseudo-binaries, respectively. KEY WORDS: CaO–SiO₂; CaMgSi₂O₆–Mg₂SiO₄; CaMgSi₂O₆–SiO₂; experiments; MgO–SiO₂     

Authigenic natroalunite in middle Miocene evaporites from the Gulf of Suez (Gemsa, Egypt)

This paper deals with a new occurrence of sedimentary natroalunite (Na, K) Al₃, (SO₄)₂ (OH)_6, in the caprock of a diapir of middle Miocene evaporites from the Gemsa peninsula, located on the southwestern coast of the Gulf of Suez. Field observations, petrographic examinations and stable isotope (¹⁸O, ³⁴S) measurements on the associated authigenic phases of anhydrite and native sulphur argue for the genesis of natroalunite at a rather high temperature (i.e. higher than 75°C) by the reaction of clay minerals with sulphuric acid. The sulphuric acid was produced by the concatenation of the following reactions which are thought to increase the diagenetic temperature: bacterial reduction of sulphate evaporites, and oxidation of hydrogen sulphide to native sulphur and sulphate where aerated conditions prevailed in the pore fluids. These changes through time from reducing to oxidizing diagenetic conditions were controlled by the progressive uplift of the diapiric system toward the land surface so that the draining ground waters became progressively oxygenated.     

Using TOPMODEL towards identifying and modelling the hydrological patterns within a headwater,humid, tropical catchment

Increasing pressure on the tropical environment requires a more thorough understanding of hydrological processes as part of reconciling the conflicting demands of economic development vis-à-vis sustainable land management. Using TOPMODEL, a physically based semi-distributed topohydrological model, we test its validity in modelling the stream flow dynamics (hydrograph) in a 1 ha tropical rainforest catchment in French Guiana. Another objective is through field validation of TOPMODEL to ascertain possible runoff generation mechanisms. The field validation of the temporal and spatial hydrodynamics across a rainfall–runoff event reveals that TOPMODEL may be suited for applications to this particular tropical rainforest environment; in fact, this is possibly the first successful application of such a model within the humid tropics. The main reasons why the model was successful are the presumed low hydraulic conductivities of the subsoil, coupled with the absence of an additional deep groundwater body, the contribution from which has caused difficulties in application of topographically, ‘physically’ based runoff models elsewhere in the humid tropics. © 1997 John Wiley & Sons, Ltd.