Unique authigenic mineral assemblages reveal different diagenetic histories in two neighbouring cold‐water coral mounds on Pen Duick Escarpment,Gulf of Cadiz

Alpha Mound and Beta Mound are two cold‐water coral mounds, located on the Pen Duick Escarpment in the Gulf of Cadiz amidst the El Arraiche mud volcano field where focused fluid seepage occurs. Despite the proximity of Alpha Mound and Beta Mound, both mounds differ in their assemblage of authigenic minerals. Alpha Mound features dolomite, framboidal pyrite and gypsum, whereas Beta Mound contains a barite layer and predominantly euhedral pyrite. The diagenetic alteration of the sedimentary record of both mounds is strongly influenced by biogeochemical processes occurring at shallow sulphate methane transition zones. The combined sedimentological, petrographic and isotopic analyses of early diagenetic features in gravity cores from Alpha Mound and Beta Mound indicate that the contrast in mineral assemblages between these mounds is caused by differences in fluid and methane fluxes. Alpha Mound appears to be affected by strong fluctuations in the fluid flow, causing shifts in redox boundaries, whereas Beta Mound seems to be a less dynamic system. To a large extent, the diagenetic regimes within cold‐water coral mounds on the Pen Duick Escarpment appear to be controlled by fluid and methane fluxes deriving from layers underlying the mounds and forcings like pressure gradients caused by bottom current. However, it also becomes evident that authigenic mineral assemblages are not only very sensitive recorders of the diagenetic history of specific cold‐water coral mounds, but also affect diagenetic processes in turn. Dissolution of aragonite, lithification by precipitation of authigenic minerals and subsequent brecciation of these lithified layers may also exert a control on the advective and diffusive fluid flow within these mounds, providing a feedback mechanism on subsequent diagenetic processes.     

The Role of Laser Ranging for Calibrating Jason-1: The Corsica Tracking Campaign

The French Transportable Laser Ranging System (FTLRS), a highly transportable Satellite Laser Ranging (SLR) instrument, was set up in Corsica (from January to September 2002) for participating to the JASON-1 altimeter verification phase. In addition to the tracking of oceanographic satellite missions and in order to perform an accurate positioning, the FTLRS also acquired laser ranging data on geodetic satellites, STARLETTE and STELLA essentially.

The paper describes the analysis strategy mainly based on the use of a short-arc orbit technique to compute accurate 1 cm local orbits, and then the geocentric positioning (2–3 mm relative to GPS). Finally, we established the JASON-1 absolute calibration value, based on 9 SLR short-arcs (between cycles 1 and 26), at 108.2 ± 8.7 mm; the 10-day repeatability is of 26.1 mm showing that a great accuracy has been reached.     

Position of the palaeontological site Aven I des Abîmes de La Fage, at Noailles (Corrèze, France), in the European Pleistocene chronology

Mourer-Chauviré, C., Philippe, M., Quinif, Y., Chaline, J., Debard, E., Guérin, C. & Hugueney, M. 2003 (September): Position of the palaeontological site Aven I des Abîmes de La Fage, at Noailles (Corrèze, France), in the European Pleistocene chronology. Boreas , Vol. 32, pp. 521–531. Oslo. ISSN 0300–9483.
The palaeontological locality of Aven I des Abîmes de La Fage, at Noailles, Corrèze, France, is a limestone swallow hole filling which includes a rich fauna of micro- and macromammals, and one of the most complete Pleistocene avifaunas in the Palearctic. According to the mammal fauna and to the sedimentological study, the filling was previously assigned to the penultimate, Saalian, glaciation. U/Th datings made on a stalagmitic floor deposited in a lateral gallery on top of the filling confirm this previous attribution. Revised lists of the mammal and bird faunas are provided. The comparison of the La Fage fauna with that of other European localities, radiochronologically or biostratigraphically dated, leads to the conclusion that most of the fossiliferous layers were deposited during the Marine Isotope Stage (MIS) 8 (242 to 301 ka).     

Chemical effect of carbonaceous aerosols on the diurnal cycle of MBL ozone at a tropical site: measurements and simulations

During late austral summer and winter 1998, black carbon (BC) aerosols were monitored with an Aethalometer at 2 sites of La Réunion Island (Indian Ocean): Saint‐Denis, the main city and Sainte‐Rose, a quite uninhabited region situated at the east coast. BC concentration data at Saint‐Denis show a marked diurnal cycle, which may be primarily attributed to traffic. The background data found at night‐time display average BC concentrations, ranging from about 80 to 250 ng/m³ whereas during the day, BC concentrations increase by a factor of at least 4. In comparison, BC concentrations vary in the range of 10 to 60 ng/m³ at Sainte‐Rose. Ozone concentration was also measured at Saint‐Denis using a Dasibi photometer and found to be at significant levels (means: 16.5–23 ppbv in April and 28.5–34 ppbv in September). A noticeable increase of ozone concentrations during the day points out the build‐up of pollutants enhancing photochemical transformations. However, during traffic pollution peaks, ozone concentration displays systematic depletion. The comparison of ozone and BC measurements at both seasons points to some possible effects of heterogeneous interaction of ozone and its precursors with BC particles. These interactions were also simulated with a 0D time‐dependent chemistry model using conditions of a polluted site. The measured ozone concentration characteristics (mean concentration and range of variation) are well simulated in the presence of BC. Our model results show that at La Réunion Island adsorption of ozone and its precursors onto BC aerosol particles could be one of the important steps determining ozone concentration characteristics, especially in absence of photochemistry during night‐time.     

Quantitative mineralogical analysis of carbonate sediments by X-ray diffraction: a new, automatic method for sediments with low carbonate content

A new X-ray diffraction method has been developed whereby the weight percentages of aragonite and low and high-magnesium calcite are determined from the integrated peak areas of samples. Peak areas are measured by a step scanning method. The weight percentages of MgCO₃ in calcite are determined from the angular position of the calcite peak. This technique uses a direct calculation method which simplifies the preparation of the samples and the calibration processes and increases the quality of the results. The fully automatic method uses a desk-top computer to guide the diffractometer and to carry out the necessary calculations. Tests on precision and accuracy of the method indicate that results with less than ± 4% error (mineral %) and ± 0.6% error (MgCO₃%) are obtainable for all samples even those with a low (10%) carbonate content.