Geochemistry of organic matter and elements of black shale during weathering in Northern Guizhou,Southwestern China: Their mobilization and inter-connection

Different from previous studies on effect of weathering upon geochemical variation along a single weathered profile, this paper provides a new methodology validated by comparing a weathered outcrop samples and their stratigraphic counterpart un-weathered core samples in a nearby shallow borehole. This outcrop and borehole penetrated the Ordovician-Silurian Wufeng–Longmaxi shales, located in the same anticline structure in the northern part of Guizhou Province, Southern China. The mineral composition, major, trace and rare earth elements (REEs) composition and Rock-Eval parameters of outcrop and core samples were analyzed and compared. Organic matter (OM) was observed in the microscope and extracted for elements analysis. The results show that short-term weathering still has significant influence on OM, mineral and elemental composition of black shales. The elements composition shows the outcrop profile was moderately weathered. The REEs compositions do not alter much during weathering process and the REEs composition and their relative ratios still are valid for rock origin determination. The OM, mainly composed by graptolite and bitumen, even entering the highly-over thermal maturity, is still sensitive to the weathering with a systematic loss 30–50% of TOC along the outcrop profile, which suggests that the OM consumption is predominantly controlled by weathering duration and the distance from the weathering surface. In turn, OM has significant influence on the trace elements transportation behavior during weathering. Some trace elements associated with the OM such as V, Cr, Th, U, Ni and Co, change significantly in their absolute concentration during weathering, but their relative ratios do not necessarily change too much and might be still reliable proxies for paleo-environmental determination. The mobility of shale minerals during weathering is in the following order: plagioclase?>?potassium feldspar and dolomite >pyrite and OM. Short-term weathering can also result in considerable transportation of elements and significant variation of minerals content in black shale, which may pose potentially high environmental and engineering risk in the regions rich in black shale.     

Zircon U–Pb–Hf isotopes and geochemistry analyses of the Huyu igneous rocks in northwestern Beijing,China: possible new evidence for the initial destruction of the North China Craton

The timing and extent of cratonic destruction are crucial to understanding the crustal evolution of the North China Craton (NCC). Zircon U–Pb–Hf isotope data and the whole-rock major and trace element characteristics of the Huyu igneous rocks in northwestern Beijing, China, provide possible new evidence for the initial destruction of the NCC. The igneous rocks occur as several sills and dikes, including lamprophyre, monzonite porphyry, and aplite. The lamprophyres have high Mg^# and K₂O contents. The monzonite porphyries have high Mg^#, high K₂O contents, and negative ε_Hf(t) values with zircon U–Pb ages of 225.5–227.7 Ma. These two types of rocks are both enriched in large ion lithosphere elements (LILEs) and light rare earth elements (LREEs) but are depleted in high field strength elements (HFSEs) and high rare earth elements (HREEs) and have almost no Eu anomalies and relatively high total rare earth element (ΣREE) contents. In contrast, the aplites exhibit high silica and K₂O contents, low MgO contents, and more negative ε_Hf(t) values with a zircon U–Pb age of 206.2 Ma. The aplites are also enriched in LILEs and LREEs but are depleted in HFSEs and HREEs, with strongly negative Eu, Ti, P, La, Ce, and Sr anomalies and relatively low ΣREE contents. These results indicate that the lamprophyres and monzonite porphyries represent a continuous cogenetic magma evolution series after melt derived from an enriched metasomatized lithospheric mantle experienced crust assimilation and fractional crystallization. The aplites were produced by the fractional crystallization of low-Mg parental magma derived from melting of the ancient Archaean crust. The occurrence of the Huyu intrusive rocks with many other plutons of similar ages on the northern margin of the NCC suggests that the northern NCC entered an intraplate extensional tectonic environment in the Late Triassic.     

新疆伊吾县宝山铁矿床矽卡岩成因研究

宝山铁矿床位于东准噶尔库兰卡孜干-北塔山-纸房-琼河坝岛弧带东段。宝山铁矿中矽卡岩与铁矿体密切共生,是重要的找矿标志。研究区矽卡岩中石榴子石、透辉石单矿物电子探针分析结果显示,石榴子石属于钙铁榴石-钙铝榴石系列,透辉石属于透辉石-钙铁辉石系列。矽卡岩中高场强元素(如Nb、Ta、Zr、Hf)相对亏损,稀土元素表现出LREE富集,HREE亏损的特点。∑REE为39.90×10~(-6)~178.43×10~(-6),∑LREE/∑HREE比值1.64~7.53,(La/Yb)N比值为1.32~10.10,轻、重稀土元素分异程度较弱,与玄武质凝灰岩具有相似的地球化学特征,这说明矽卡岩是玄武质凝灰岩受后期岩浆热液改造形成,随着温度和压力降低,磁铁矿沉淀形成铁矿体。     

柴达木盆地东部上石炭统克鲁克组碎屑岩储层特征及控制因素

柴达木盆地上石炭统克鲁克组是该区重要的古生界勘探层位,组内发育多套良好的碎屑岩层。为探究其岩石物性特征及控制因素,本次以野外露头调查为基础,利用普通薄片、铸体薄片鉴定及扫描电镜等手段,结合物性测试和压汞资料,对克鲁克组碎屑岩纵向分布规律,储层岩性、物性、孔喉特征及孔隙类型进行分析。认为克鲁克地层中克2段发育的三角洲前缘亚相和克3段的具障壁海岸潮坪相的大套含砾粗砂岩、粗砂岩砂体原生、次生孔洞发育,孔喉大、分布集中、分选好,为有利的碎屑岩储层。早成岩期压实作用、重结晶及胶结作用对克鲁克组砂岩的原生孔隙破坏严重,晚成岩期储层改造形成的溶孔、裂缝—溶孔是油气成藏的主要储存空间。该研究为预测柴东石炭系克鲁克组油气有利区域提供依据,为今后该地区的油气勘探提供理论支撑。     

A temporal analysis of the association between breast cancer and socioeconomic and environmental factors

Although some biological factors have been confirmed to increase the risk of breast cancer, they only account for a small portion of the overall incidence in females. Women’s socioeconomic status and hazardous exposures to potential breast cancer carcinogens could modify their risks of breast cancer. From a public health perspective, it is important to understand what socioeconomic and environmental factors are associated with an elevated risk of breast cancer and how they vary geographically, temporally, and among different populations. Using an integrated approach, this study examines the associations between the incidence rate of invasive breast cancer and socioeconomic characteristics and environmental risks over time in Illinois for two periods: 1999–2003 and 2009–2013. Based on data from the US Census, ACS, and EPA, this study builds two sets of regression models to investigate the associations. The findings reveal that compared to environmental risks, socioeconomic factors are much more significant factors associated with the risk of breast cancer. The significant explanatory variables differ somehow between the two periods, yet with some agreement. Among the environmental risk variables examined, two toxic carcinogens, ethylene oxide and benzene were associated with an elevated risk of breast cancer for each time period respectively.     

3D打印技术在矿床学中的应用研究——以内蒙古乌力吉敖包萤石矿Ⅲ号矿体为例

3D打印(3D printing)是一种以三维模型为样本的快速成形技术,它通过逐层打印或粉末熔铸的方式来构造需要的立体图形。本文从3D打印技术的原理及其发展现状入手,重点列举内蒙古乌力吉敖包萤石矿,利用3D打印机打印具有现实可观性的地质体实体,探讨3D打印技术作为新兴的科技手段应用于矿床学教学与研究的应用价值和发展前景。研究发现,3D打印技术在矿体三维可视化中的应用符合地质图件立体化和3D打印技术多领域化的趋势,未来3D打印技术在地质领域的应用也有助于开拓矿床学教学和研究的新方式与新思路。     

Petrophysical characterisation of tight sandstone gas reservoirs using nuclear magnetic resonance: a case study of the upper Paleozoic strata in the Kangning area,eastern margin of the Ordos Basin,China

Residual and movable porosity are significant parameters for characterising petrophysical properties, especially in tight reservoirs. Eight tight sandstone samples from the upper Paleozoic gas-bearing strata in the Kangning area, from the eastern margin of the Ordos Basin, were analysed using nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), petrography, and porosity and permeability tests. The lithology and pore types were identified and classified using petrography and SEM. The residual and movable porosity were obtained with NMR. In addition, NMR was used to visualise pore structure and pore size distribution. The results suggest that the upper Paleozoic sandstones in the study area mainly comprise feldspathic litharenite and litharenite. The sandstone porosity and permeability are low, with means of 5.9% and 0.549 mD, respectively. Four pore types exist in the tight sandstones: residual primary pores, grain dissolution pores, micropores (clay-dominated) and microfractures. The T₂ spectra under water-saturated conditions correlate with pore size and can be used to distinguish small and large pores based on the transverse relaxation time cutoff value of 10 ms, which corresponds to a pore diameter of 0.232 μm. Small pores account for 72% of the pores in the tight sandstones. The continuous bimodal T₂ spectra suggest good connectivity between small and large pores, despite the low porosity and permeability. In this study, the movable porosity of the major tight sandstone gas reservoirs is higher than the residual porosity, which confirms the effective evaluation of movable porosity to tight sandstone reservoirs, based on NMR experiments.     

Correction to: Assessing real options in urban surface water flood risk management under climate change

Windblown dust originating in China and Mongolia causes health effects and agricultural damage in its source areas and causes Asian dust events in Japan. An early warning system that could be combined with weather forecasts would be helpful in preventing serious damage. However, it is difficult to specify source areas of dust with current dust modeling systems because land surface information, including vegetation coverage and land surface soil water content, is inadequate. To find and monitor dust source regions, a semi-real-time dust erodibility map was developed based on MODIS satellite data that focuses particularly on the threshold wind speed in a target area of northeast Asia including China and Mongolia (35°–50°N, 75°–120°E). The mapping system incorporates satellite data on snow cover, areas of frozen soil, surface soil water content, and vegetation cover.     

珠穆朗玛峰自然保护区湖泊动态及对区域气候变化的响应

利用Landsat卫星影像,采用面向对象分类方法提取珠穆朗玛峰自然保护区湖泊信息,分析了湖泊动态及对区域气候变化的响应关系。结果表明：（1）2015年保护区湖泊总面积为489.07 km²,构造湖、河成湖、冰川湖分别占总面积的77.3%、2.6%、20.1%。（2）1975-2015年,保护区内各类湖泊面积变化速率不同,冰川湖最大（1.05 km²·a^-1）,构造湖次之（-0.85 km²·a^-1）,河成湖最稳定（0.013 km²·a^-1）;保护区南坡冰川湖面积变化速率（0.53 km²·a^-1）略大于北坡（0.52 km²·a^-1）。（3）北坡构造湖、河成湖对区域气候的响应呈阶段性变化规律,1975-2000年珠峰地区气候呈暖湿化趋势,2000年构造湖、河成湖面积达到峰值,两类总计增加22.8 km²;2000-2015年转变为显著的暖干气候,构造湖、河成湖面积均呈减少趋势,总共减少57.16 km²。随着区域气候的变暖,冰川湖总面积不断扩大,近40年间冰川湖面积累计增加43.06 km²。（4）灰色关联度分析显示,年极端低温对构造湖面积变化影响最显著,年均气温对冰川湖起主导作用,年均相对湿度对河成湖影响最大。较其他气候因子而言,降水量对各类湖泊面积变化的影响均最小。     

俯冲带碳酸盐化对深部碳循环的启示:以中国西南天山碳酸盐化云母片岩为例

俯冲带可将地球表层碳输送至深部地幔,同时也记录着俯冲板片来源碳质流体的迁移沉淀机制,对地球深部碳循环具有重大影响。近年来,俯冲带脱碳机制的研究表明流体溶解脱碳作用是冷的大洋俯冲板片释放COH流体的重要方式,而上覆板块(尤其地幔楔)则被认为是缓冲这些COH流体的重要场所,甚至是俯冲带CO_2的唯一"归宿"。事实上,俯冲带岩石本身的固碳能力却受到了忽视,而对俯冲带岩石捕获和固存CO_2(carbon capture and storage,CCS)能力的评估对全球碳通量的估算尤为重要。本文以中国西南天山高压-超高压变质带中碳酸盐化云母片岩为例,探讨俯冲带岩石的碳酸盐化对深部碳循环的影响。西南天山长阿吾子一带的碳酸盐化云母片岩记录了俯冲板片起源的碳质流体对俯冲带云母片岩的交代作用,地球化学特征表明蛇纹岩释放的富水流体溶解俯冲洋壳中的碳酸盐可能是产生COH流体的重要机制。基于碳质流体对多硅白云母(Si(a.p.f.u.)=3.58～3.73)的交代及相对高压的碳酸盐矿物(主要为白云石和菱镁矿)与金红石的共生,结合区域上碳酸盐化云母片岩与高压碳酸盐化蛇纹岩(HP-ophidolomite)的伴生,我们认为云母片岩的碳酸盐化作用可能发生在俯冲板片峰期稍后的高压折返阶段。俯冲带云母片岩的固碳作用表明除了上覆板块,俯冲带岩石本身对于碳质流体也具有很好的吸收能力。初步估算表明俯冲带云母片岩的碳酸盐化每年可固存至少2.46～6.68Mt/yr,约占俯冲板片每年进碳量的4%～17%。