从全国水环境数据库看中国水环境状况

以全国水环境数据库的监测记录为第一手资料,以各大流域片为单位,从宏观上介绍了各大流域片的水质总体概况,包括各类水质所占比例、污染水质的超标物类型等,基本反映了我国各大流域在20世纪90年代的水质状况以及水环境的时空变化特征.总的来说,我国的水环境状况不容乐观,水质污染比较严重,尤其是我国北方的流域片.     

第二松花江流域水电厂综合中长期水文预报的分析研究

基于对第二松花江流域上游小山、松山、两江水电站中长期水文预报研究成果，论述了综合中长期水文预报的研究思路和定性预报、定量预报的分析研究方法。该研究通过2002年实践检验，具有较高的预报精度。     

Dissolution mechanisms of water in depolymerized silicate melts: Constraints from H and Si NMR spectroscopy and ab initio calculations

Dissolution of water in magmas significantly affects phase relations and physical properties. To shed new light on the this issue, we have applied ¹H and ²⁹Si nuclear magnetic resonance (NMR) spectroscopic techniques to hydrous silicate glasses (quenched melts) in the CaO-MgO-SiO₂ (CMS), Na₂O-SiO₂, Na₂O-CaO-SiO₂ and Li₂O-SiO₂ systems. We have also carried out ab initio molecular orbital calculations on representative clusters to gain insight into the experimental results.The most prominent result is the identification of a major peak at ∼1.1 to 1.7 ppm in the ¹H MAS NMR spectra for all the hydrous CMS glasses. On the basis of experimental NMR data for crystalline phases and ab initio calculation results, this peak can be unambiguously attributed to (Ca,Mg)OH groups. Such OH groups, like free oxygens, are only linked to metal cations, but not part of the silicate network, and are thus referred to as free hydroxyls in the paper. This represents the first direct evidence for a substantial proportion (∼13∼29%) of the dissolved water as free hydroxyl groups in quenched hydrous silicate melts. We have found that free hydroxyls are favored by (1) more depolymerized melts and (2) network-modifying cations of higher field strength (Z/R²: Z: charge, R: cation-oxygen bond length) in the order Mg > Ca > Na. Their formation is expected to cause an increase in the melt polymerization, contrary to the effect of SiOH formation. The ²⁹Si MAS NMR results are consistent with such an interpretation. This water dissolution mechanism could be particularly important for ultramafic and mafic magmas.The ¹H MAS NMR spectra for glasses of all the studied compositions contain peaks in the 4 to 17 ppm region, attributable to SiOH of a range of strength of hydrogen bonding and molecular H₂O. The relative population of SiOH with strong hydrogen bonding grows with decreasing field strength of the network-modifying cations. Ab initio calculations confirmed that this trend largely reflects hydrogen bonding with nonbridging oxygens.     

金坛市开发区的数字影像测图

为完善数字化测图功能，通过全数字摄影测量系统(VirtuoZo)的数字影像测图模块(IGS)在金坛市开发区1：500测区中的应用，总结提高测图精度和速度的体会。     

西安市冬季冷暖的历史演变对采暖的影响

本文针对CAPPS2.0系统在业务化自动运行过程中的一些问题,提供了一套具体可行的解决方案,实现了CAPPS系统的全自动运行,具有很高的实用价值。     

侯马市酸雨概况及其气象条件分析

通过对侯马近14a酸雨观测资料分析,发现侯马出现酸雨的概率较大,强度较强,时间变化特征明显,与气象条件关系密切。     

Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China

Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils.     

珠江口盆地白云凹陷新生代构造演化动力学

白云凹陷构造演化史的研究对在白云凹陷开展油气勘探和深水沉积研究具有重要的意义。通过对断裂与沉积结构平面和剖面特点的分析,结合岩浆活动特点,文中提出白云凹陷是一个复式地堑,推测这种结构特点与凹陷下地壳的强烈韧性减薄和颈缩变形有关,表现为热岩石圈的伸展。其发育机制推测与白云凹陷位于构造转换带上有关,特殊的构造位置使白云凹陷成为强烈构造变形区,岩石圈地壳强烈减薄,伴随伸展过程和地幔上涌,脆性地壳或上地幔中部分熔融物质的出现导致岩石圈强度的急剧降低,在区域伸展应力场下以韧性流变方式减薄。岩浆在构造转换带下聚集并发育主岩浆房,由于白云凹陷南北边缘没有发育正断裂系统,岩浆主要沿垂直伸展的方向运移,因此在珠琼运动一幕和二幕南南东向伸展应力作用下,岩浆向白云凹陷的东部和西部运移至北西向基底深大断裂处,那里由于北西向断裂表现为左行张剪性质而成为压力较低的地区,从而成为岩浆上涌和侵位的地方。在岩浆聚集的地区,活动岩浆体附近的脆性变形被分散的韧性变形所取代,因此在凹陷的东北和西南两个角上,发育了张性和张剪性小断裂群,由于热岩石圈弹性较差,白云凹陷长期持续沉降。白云凹陷的断裂活动和沉积演化史还受到南海海盆扩张活动的影响。     

Element mobility during pyrite weathering: implications for acid and heavy metal pollution at mining-impacted sites

Based on back scattered electron images and electron micro-probe analysis results, four alteration layers, including a transition layer, a reticulated ferric oxide layer, a nubby ferric oxide layer and a cellular ferric oxide layer, were identified in the naturally weathering products of pyrite. These layers represent a progressive alteration sequence of pyrite under weathering conditions. The cellular ferric oxide layer correlates with the strongest weathering phase and results from the dissolution of nubby ferric oxide by acidic porewater. Leaching coefficient was introduced to better express the response of element mobility to the degree of pyrite weathering. Its variation shows that the mobility of S, Co and Bi is stronger than As, Cu and Zn. Sulfur in pyrite is oxidized to sulfuric acid and sulfate that are basically released into to porewater, and heavy metals Co and Bi are evidently released by acid dissolution. As, Cu and Zn are enriched in ferric oxide by adsorption and by co-precipitation, but they would re-release to the environment via desorption or dissolution when porewater pH becomes low enough. Consequently, Co, Bi, As, Cu and Zn may pose a substantial impact on water quality. Considering that metal mobility and its concentration in mine waste are two important factors influencing heavy metal pollution at mining-impacted sites, Bi and Co are more important pollutants in this case.