Rare earth elements in suspended and bottom sediments of the Mandovi estuary, central west coast of India: Influence of mining

Rare earth elements (REEs) in the suspended particulate matter (SPM) of the Mandovi estuary indicated that the mean total-REEs (∑REE) and light REE to heavy REE ratios are lower than that of the average suspended sediment in World Rivers and Post-Archean average Australian shale. High ∑REE were associated with high SPM/low salinity and also with high SPM/high salinity. Although the ∑REE broadly agree with SPM levels at each station, their seasonal distributions along transect are different. SPM increased seaward in the estuary both during the monsoon and pre-monsoon, but consistently low at all stations during the post-monsoon. The mean ∑REE decreased marginally seaward and was <25% at sea-end station than at river-end station. Spatial variations in ∑REE are maximum (64%) during the pre-monsoon. Strong to moderate correlation of ∑REE with Al, Fe and Mn in all seasons indicates adsorption and co-precipitation of REEs with aluminosilicate phases and Fe, Mn-oxyhydroxides. The ratio of mean ∑REE in sediment/SPM is low during the monsoon (1.27), followed by pre-monsoon (1.5) and post-monsoon (1.62). The middle REE- and heavy REE-enriched patterns with positive Ce and Eu anomalies are characteristic at every station and season, both in SPM and sediment. They also exhibit tetrad effect with distinct third and fourth tetrads. Fe-Mn ore dust is the most dominant source for REEs. However, the seasonal changes in the supply of detrital silicates, Fe-Mn ore dust and particulates resuspended from bottom sediments diluted the overall effect of salinity on fractionation and distribution of REEs in the estuary.     

Experiments on the settling, overturning and entrainment of bivalve shells and related models

An experimental and theoretical examination has been made of the settling, entrainment and overturning of 176 valves representing 16 common Northwest European marine bivalve species, together with a comparative study of 15 plastic models in the form of segments from cylindrical tubes. Settling behaviour in both stagnant and moving water depends on particle mass, symmetry and concavo-convexity. Separated empty bivalve shells spin and spiral while settling and, if sufficiently elongated, also pitch. At the observed Reynolds numbers, the shells and models fall concave-up, the terminal fall velocity increasing as the square root of the unit immersed mass or weight. The drag coefficient is independent of Reynolds number but increases with surface roughness and, particularly, particle elongation. Turbulence slightly lowers the critical elongation for pitching. A separation vortex lies captive on the upper side of each descending particle. Consequently, an empty bivalve shell traversing a suspension of sand traps grains on its upper side at a rate proportional to their volume concentration and terminal fall velocity. This process, increasing the effective shell mass, is limited only by the capacity of the shell and grain spillage due to the possible onset of pitching. The ratio (non-dimensional) of a quantity proportional to the applied fluid force and the particle unit immersed weight consistently describes the entrainment of concave-up and convex-up particles, and also the immediate overturning of a valve on settling concave-up to the bed. These thresholds vary in relative magnitude with bed-particle friction and particle concavo-convexity. In general, convex-up particles are the most stable; the concave-up entrainment and overturning thresholds are of a substantially lower but similar magnitude. The high frequency of concave-up bivalve attitudes in turbidites is understandable largely in terms of the ability of a settling valve to increase in effective mass by grain entrapment. Convex-up attitudes in the lower parts of turbidites may record currents stronger than the overturning threshold.     

Plate kinematics and the gravity field

Both the system of plate motions and the global gravity field or the geoid are now so precisely known that it seems worthwhile to look for quantitative relationships. Some aspects, such as the general occurrence of positive gravity and geoid anomalies in regions of plate convergence, have long been known. Our aim is to describe the gravitational field in terms of plate-kinematic parameters and we present a preliminary step in this direction: for four plates (Pacific, Nazca, Indian, American) we have computed the correlation of the Gem 8 geoid heights (with reference to an ellipsoid of 1/298.255 ellipticity) with distance from the poles of motion and distance from the axes in an “absolute” frame. The geoid tends first to drop from the ridge axes to at least 10° distance and then to rise toward the convergence zones. This trend is strongest for the Indian plate in collision with Eurasia, is smaller, but very clear for the oceanic Pacific and Nazca plates, and is not developed for the American plate which does not subduct. We did not find a consistent relationship for the geoid with distance from the pivots. A possible interpretation of the results is the return flow of the large-scale mantle circulation.     

The distribution of chlorophyll-a and dominant planktonic components in the coastal transition zone off Concepción, central Chile, during different oceanographic conditions

The oceanographic setting and the planktonic distribution in the coastal transition zone off Concepción (∼35-38°S, ∼73-77°W), an area characterized by its high biological production, were assessed during two different seasons: austral spring with equatorward upwelling favorable winds and austral winter with predominately northerly winds. Oceanographic and biological data (total chlorophyll-a, particulate organic carbon, microplankton, large mesozooplankton >500 μm as potential consumers of microplankton) were obtained during two cruises (October 1998, July 1999) together with satellite imagery for wind stress, geostrophic flow, surface temperature, and chlorophyll-a data. The physical environment during the spring sampling was typical of the upwelling period in this region, with a well-defined density front in the shelf-break area and high concentrations of surface chlorophyll-a (>5 mg m⁻³) on the shelf over the Itata terrace. During the winter sampling, highly variable though weakly upwelling-favorable winds were observed along with lower surface chlorophyll-a values (<2 mg m⁻³) on the shelf. In the oceanic area (>100 km from the coast), cyclonic and anti-cyclonic eddies were evident in the flow field during both periods, the former coinciding with higher chlorophyll-a contents (∼1 mg m⁻³) than in the surrounding waters. Also, a cold, chlorophyll-a rich filament was well defined during the spring sampling, extending from the shelf out to 350-400 km offshore. Along a cross-shelf transect, the micro- and meso-planktonic assemblages displayed higher coastal abundances during the spring cruise but secondary peaks appeared in the oceanic area during the winter cruise, coinciding with the distribution of the eddies. These results suggest that the mesoscale features in this region, in combination with upwelling, play a role in potentially increasing the biological productivity of the coastal transition zone off Concepción.     

Seepage of groundwater nitrate from a riparian agroecosystem into the Wye River estuary

Intensive research in Chesapeake Bay has indicated that reductions in nitrogen inputs to the bay will be necessary to restore water quality to levels needed for resurgence of bay living resources. Fall-line water quality monitoring efferts have characterized diffuse-source nitrogen inputs from a large percentage of the bay drainage basin, but relatively little information exists regarding rates of nitrogen delivery to tidal waters from coastal plain regions. Extensive nitrate contamination of shallow groundwater due to agricultural activities, coupled with the dominant role of subsurface flow in discharge from Coastal Plain regions of the drainage basin, creates the potential for high rates of nitrogen delivery to tidal waters via groundwater seepage. This study utilized intensive hydrologic and water chemistry monitoring from April 1992 through September 1994 to determine the spatial characteristics of the groundwater-estuarine interface, as well as the rates of subsurface nitrogen transport from an agricultural field into nearshore waters of the Wye River, a subestuary of Chesapeake Bay. The hydrogeologic characteristics of the study site resulted in groundwater discharge to the Wye River occurring almost exclusively within 15 m of the shoreline. Calculated groundwater discharge rates were found to vary widely in the short term due to tidal fluctuations but in the long term were driven by seasonal changes in groundwater recharge rates. The zone of groundwater discharge contracted shoreward during summer months of low discharge, and expanded to a maximum width of approximately 15 m during high discharge periods in late winter. Average discharge rates were more than five times higher in winter versus summer months. Groundwater nitrate concentrations entering the discharge zone were relatively stable throughout the study period, with little evidence of denitrification or nitrate uptake by riparian vegetation. Consequently, nitrogen discharge patterns reflected the strong seasonality in groundwater discharge. Annual nitrate-N discharge was approximately 1.2 kg m^?1 of shoreline, indicating drainage basin rates of nitrogen delivery to tidal waters of approximately 60 kg ha^?1.     

Mass movements in cave sediments: investigation of a ∼40,000-year-old guano mudflow inside the entrance of the Great Cave of Niah, Sarawak, Borneo

The West Mouth of the Great Cave at Niah in Sarawak, northwest Borneo and the North Passage that leads to the West Mouth contain large deposits of guano. The main deposit, several metres thick in places, forms the sloping floor of the entire North Passage. A mass movement deposit identified in the West Mouth, having a volume of 600 m³, originated as a guano mudflow up the North Passage in the order of 40,000 years ago. This failure of the guano slope was investigated to determine whether particular conditions or events could be identified as the most likely causes. The physical, hydrological and geotechnical properties of samples of the material were determined so that the stability of the slope could be assessed. Stability analyses showed that shearing failure of the slope would require inputs of water to the slope in quantities for which no feasible explanation can be suggested. However, the properties of the guano are similar to those of loess, indicating a high susceptibility to ‘hydrocollapse’. Very shallow failure of the slope, possibly as several smaller mudflows, could therefore have occurred due to additional water in quantities that could realistically be supplied as rainwater spray, possibly with a seismic trigger. The climate must therefore have been wetter than it is at present. These findings have implications for the interpretation of sediment deposits in other relict caves.     

Fractal analysis of long-range paleoclimatic data: Oxygen isotope record of pacific core V28-239

R/S analysis of the oxygen isotope curve of Pacific core V28-239 yields a fractal dimension of 1.22. This value is considered to characterize global climatic change over the last 2 million years as expressed by changing O¹⁸ ratios and confirms that climatic variations are characterized by long-term persistence. The fractal dimension of 1.22 compares favorably with the approximate fractal dimension of 1.26 for annual precipitation records for nine major cities in the United States. Although the precipitation and oxygen isotope data are measured in different physical units and recorded at different time scales, fractal analysis allows for a mathematical comparison of the two phenomena. Additionally, since the fractal dimensions of the oxygen isotope and precipitation records are similar, it is implied that such fractal dimensions are characteristic of climate change over the spectral range of 10 to 10⁶ years. Given this temperature curves based on fractal parameters of long-term O¹⁸ data could be constructed which would allow examination of characteristics of temperature variation over tens and hundreds of years. Such studies may allow the establishment of limits on natural temperature variation and document the persistence of temperature trends through time. If these trends and limits can be resolved, long-range climatic prediction is feasible.