Nitrate source and fate at the catchment scale of the Vibrata River and aquifer (central Italy): an analysis by integrating component approaches and nitrogen isotopes

The aim of this study is to apply an integrated approach to determine nitrate sources and fate in the alluvial aquifer of the River Vibrata (Abruzzi, central Italy) by coupling the Isotope and the Component approaches. Collected data include concentration and nitrogen isotope composition of groundwater samples from the alluvial aquifer and nitrogen loads arising from agricultural and non-agricultural sources. The adopted methodology identified synthetic fertilizers as main sources of nitrate in the Vibrata alluvial aquifer. At the catchment scale, two different zones have been identified: the Upper Valley, where infiltration to groundwater is dominant and nitrogen easily migrates into the aquifer; in this area, nitrate content in groundwater is stable and normally higher than EU requirements. Moreover, streamwaters are fed by groundwater with a nitrate content likely lowered by denitrification processes occurring in the hyporheic zone. In the Lower Valley, runoff processes dominate and the nitrate content in surface waters is higher. Nevertheless, groundwater is locally affected by denitrification that breaks down the nitrate content, which often reaches values consistent with law limits.     

Detailed architecture of a compound incised valley system and correlation with forced regressive wedges: Example of Late Quaternary Têt and Agly rivers,western Gulf of Lions,Mediterranean Sea,France

Quaternary incised valley systems are usually characterized by the preservation of a single valley-fill attributed to the last post-glacial period. Moreover, there are very few cases of correlation between incised valley system developed on inner shelf and sedimentary units observed on the mid to outer shelf, mainly forced regressive wedges. The Roussillon shelf, in the western part of the Gulf of Lion, is a particular example of preserved Quaternary compound incised valley system also characterized by a direct correlation with the forced regressive lowstand wedges on the mid-outer shelf. High-resolution seismic data and a borehole, 60 m deep, located on the beach barrier permit an accurate study of the geometry and lithology of the system. Six imbricated and more or less preserved incised valleys and valley-fills are observed up to the inner to mid-shelf. The key surfaces associated to the incised valleys are correlated to the boundaries of the forced regressive wedges. They are assumed to be reworked surfaces. At the borehole location, only few thin layers, less than 1 m thick, of coarse grain and/or floating pebbles, are observed and should correspond to preserved fluvial lowstand deposits reworked under marine influence. The valley fills are mainly composed of estuarine muddy silts. From AMS ¹⁴C age dating it is inferred that the uppermost incised valley system is younger than 45 ky cal BP. Based on those observations, the six preserved incised valley systems are assumed to be controlled by the last six 4th order sea-level cycles — 100 ky — of the middle to late Quaternary. The paleo-topography of the underlying Plio-Quaternary deposits controls the compound incised valley system location. The deep topography of the Messinian Erosionnal Surface is a controlling factor at a lower degree. The partial preservation of the successive valley fill is attributed not only to the differential subsidence but also to the lateral migration of each incision and to the hydrodynamic regime.     

About the Efficiency of Numerical 1-D and 2-D Modelling of Site Effects in Basin Structures

—In the present study we compare results obtained from experimental estimates of local site amplification effects with those from numerical modelling using four different techniques. We benefit from an extremely precise knowledge of the near-surface structure and experimental estimates of the local amplification factors which are determined from seismic weak-motion data recorded by a dense array across a sedimentary basin at a European test-site in Northern Greece. The possibilities and limitations of the different modelling techniques (a 1-D technique, and three 2-D techniques) to model the effects of local amplification effects are tested. Amplifications calculated by the numerical techniques are only qualitatively compared with observed data from experimental studies in the time domain and directly in the frequency domain.¶As a result we conclude that, in the case of a complex subsurface geometry, 1-D modelling underestimates the amplification patterns in terms of absolute amplification level, and cannot correctly account for resonant frequencies, at least for modes higher than the fundamental mode. If a more realistic incident wave field than just a plane wave is taken into account, 2-D modelling reveals the fundamental frequency and shows adequate amplifications not only at the fundamental frequency but also at higher frequencies. The general trend of the amplifications at the lowest frequencies is well determined by the 2-D numerical modelling, and can therefore supply information for seismic risk analysis.     

On the Problem of Differential Payment for the Use of Different-Quality Surface Waters in Ukraine

The evolution of views and practical decisions regarding the problem of collecting payment for the use of surface waters with regard to their quality in the former USSR and present-day Ukraine is discussed. A simple and feasible method is proposed for differentitation of regional (basin) rates of payment for the use of surface water in Ukraine with allowance made for its quality assessed based on a system of environmental classifications.     

On the current-voltage relationship in auroral breakups and westwards-travelling surges

Auroral precipitating electrons pass through an acceleration region before entering the atmosphere. Regardless of what produces it, a parallel electric field is assumed to cause the acceleration. It is well known that from kinetic theory an expression for the corresponding upward field-aligned current can be calculated, which under certain assumptions can be linearized to j = KV. The K constant, referred to as the Lyons-Evans-Lundin constant, depends on the source density and thermal energy of the magnetospheric electrons; it is an important parameter in magnetosphere-ionosphere coupling models. However, the K parameter is still rather unknown, and values are found in a wide range of 10^–8–10^–10Sim^–2. In this study, we investigated how the type of auroral structure affects the K values. We look at onset and westwards-travelling surge (WTS) events and make comparisons with earlier results from observations of more stable auroral arcs. A new analysis technique for studying those magnetospheric parameters using ground-based measurements is introduced. Electron density measurements are taken with the EISCAT radar, and through an inversion technique the flux-energy spectra are calculated. Source densities, thermal energies and potential drops are estimated from fittings of accelerated Maxwellian distributions. With this radar technique we have the possibility to study the changes of the mentioned parameters during the development of onsets and the passage of surges over EISCAT. The study indicates that the linearization of the full Knight formulation holds even for the very high potential drops and thermal temperatures found in the dynamic onset and WTS events. The values of K are found to be very low, around 10^–11Sm^–2 in onset cases as well as WTS events. The results may establish a new technique where ionospheric measurements are used for studying the ionosphere-magnetosphere coupling processes.     

The use of7LiOH-impregnated filters for the collection of acidic gases and analysis by instrumental neutron activation analysis

A simple system was designed using⁷LiOH-impregnated filters to collect acidic gases from ambient air and from highly concentrated volcanic plumes or gas streams. These filters were developed for analysis using instrumental neutron activation analysis, but other analytical techniques could be used as well. The sampling system was designed to use a series of 1–3 M⁷LiOH-impregnated filters to collect high concentrations of acidic gases found in gas plumes of active volcanoes. The filters are quantitative for SO₂ and the halide acids when sufficient base is present to neutralize the acidic species. Extremely high concentrations of SO₂ may not be collected quantitatively since SO₂ is a relatively weak Lewis acid compared to the halide acids. The acidic oxides of Sb, As, and Se were also collected quantitatively. A particle filter preceded the impregnated filters in order to remove particles from the fumes. This system has proven effective under difficult sampling conditions and, since it is portable and light weight, it could be used for many volcanological applications where high levels of acidic gaseous phase species need to be collected.     

Trace metals in the North Sea

The distribution of zinc, manganese, nickel, copper and cadmium in water and biological material has been measured in the southern North Sea and Straits of Dover, and off the north-east coast of England. These investigations provide baseline values against which future pollution changes can be measured.     

Die Massenentwicklung der Geißelalge Uroglena americana (Alk.) Lemm in Trinkwassertalsperren Thüringens und ihre Bekämpfung

A mass development of Uroglena americana with cellular densities of up to 13.5 · 10⁶ and 86.10⁶ cells/l, was observed in two drinking-water reservoirs. In the first case the development remained confined to the upper 20 m, in the second case there occurred a gradual shift of the maximum to deeper zones from May to July with decreasing cellular densities down to a depth of 35 m. Laboratory experiments for the control of the algae development were performed in order to protect the drinking-water resources from potential impairments of odour and taste. Samples of the storage-reservoir water with 20.10⁶ cells/l of Uroglena were concentrated up to 1.25 … 12.5 mg/l Ca(OH)₂ (pH-values of 7.2 … 9.6) by addition of calcium hydroxide and observed for 39 h. First impairment of the cells of Uroglena is detectable at 5 mg/l Ca(OH)₂ after 15 h, an immediate effect can be observed at 7.5 mg/l Ca(OH)₂ together with increased sedimentation, also Gymnodinium and Cryptomonas having been damaged. Thereupon a successful control of Uroglena by liming up to pH-values above 8.0 is possible. The application of lime to outdoor areas was not necessary, in the final analysis, since the drinking-water quality could be secured by the optimum choice of the intake depth of raw water with a maximum of 4.10³ to 77.10³ cells/l.