Subduction Influence on Oxygen Fugacity and Trace and Volatile Elements in Basalts Across the Cascade Volcanic Arc

Fluids or melts derived from a subducting plate are often citedas a mechanism for the oxidation of arc magmas. What remainsunclear is the link between the fluid, oxygen fugacity, andother major and trace components, as well as the spatial distributionof the impact of those fluids. To test the potential effectsof addition of a subduction-derived fluid or melt to the sub-arcmantle, olivine-hosted melt inclusions from primitive basalticlavas sampled from across the central Oregon Cascades (43°–45°N)have been analyzed for major, trace and volatile elements andfO₂. Oxygen fugacity was determined in melt inclusions fromsulfur speciation determined by electron microprobe and fromolivine–chromite oxygen geobarometry. The overall rangein fO₂ based on sulfur speciation measurements is from <–0·25log units to + 1·9 log units (FMQ, where FMQ is fayalite–magnetite–quartzbuffer). Oxygen fugacity is positively correlated with fluid-mobiletrace element and light rare earth element contents in basaltsgenerated by relatively low-degree partial melting. Establishinga further correlation between fO₂ and fluid-mobile trace elementabundances with position along the arc requires the basaltsto be subdivided into shoshonitic, calc-alkaline, low-K tholeiiteand enriched intraplate basalt groups. Melt inclusions fromenriched intraplate and shoshonitic lavas show increasing fO₂and trace element abundances closer to the trench, whereas calc-alkalinemelt inclusions exhibit no significant across-arc variations.Low-K tholeiitic melt inclusions record an increase in incompatibletrace elements closer to the trench; however, there is no correlatedincrease in fO₂. The correlation observed in enriched intraplateand shoshonitic melt inclusions is interpreted to reflect aprogressively greater proportion of a fluid-rich, oxidized subductioncomponent in magmas generated nearer the subduction zone. Significantly,calc-alkaline melt inclusions with high ratios of large ionlithophile elements to high field strength elements, characteristicof ‘typical’ arc magmas, have oxidation states indistinguishablefrom low-K tholeiite and enriched intraplate basalt melt inclusions.The lack of across-arc geochemical variation in calc-alkalinemelt inclusions may suggest that these basalts are not necessarilythe most appropriate magmas for examining recent addition ofa subduction component to the sub-arc mantle. Flux and batchmelt model results produce a wide range of predicted amountsof melting and subduction component added to the mantle source;however, general trends characterized by increased melting andproportion of the subduction component from enriched intraplate,to low-K tholeiite, to calc-alkaline are robust. The model resultsdo not require enriched intraplate, low-K tholeiite and calc-alkalinemagmas to be produced from the same more fertile mantle source.However, enriched intraplate magmas, in contrast to calc-alkalineand low-K tholeiite magmas, cannot be generated from a depletedmantle source. Flux or batch melting of either the more fertileor depleted mantle sources used to generate the low-K tholeiite,calc-alkaline, and enriched intraplate magmas cannot reproduceshoshonitic compositions, which require a significantly depletedmantle source strongly metasomatized by a subduction component.The potential mantle source for shoshonitic basalts has a predictedfO₂ (after oxidation) from + 0·3 to + 2·4 logunits (FMQ) whereas the mantle source for low-K tholeiite, calc-alkaline,and enriched intraplate magmas may range from –1·1to + 0·7 log units (FMQ). KEY WORDS: basalt; Cascades; melt inclusions; oxidation state; volatiles     

Lang Trang Cave (Northern Vietnam): Pleistocene Mammalian Locality with Gigantopithecus Finds

Doklady Earth Sciences - Speleological, geological and paleontological characteristics of the Lang Trang cave in northern Vietnam are presented. Primates Gigantopithecus blacki von Koenigswald,...     

Short timescale UV variability study in NGC 4151 using IUE data

IUE has made very successful long term and intense short time-scale monitoring spectroscopic study of NGC 4151, a Seyfert 1 galaxy for over nearly 18 years from its launch in 1978 to 1996. The long-term observations have been useful in understanding the complex relation between UV continuum and emission line variability Seyfert galaxies. In this paper, we present the results of our studies on the short-timescale intense monitoring campaign of NGC 4151 undertaken during December 1–15, 1993. A most intense monitoring observation of NGC 4151 was carried out by IUE in 1993, when the source was at its historical high flux state with a shortest interval of 70 min between two successive observations. We present our results on emission line and continuum variability amplitudes characterized by \(F_{\mathrm{var}}\) method. We found highest variability of nearly 8.3% at 1325 \(\AA \) continuum with a smallest amplitude of 4% at 2725 \(\AA \). The relative variability amplitudes (\(R_\mathrm{max}\)) have been found to be 1.372, 1.319, 1.302 and 1.182 at 1325, 1475, 1655 and 2725 \(\AA \) continuum respectively. The continuum and emission line variability characteristics obtained in the present analysis are in very good agreement with the results obtained by Edelson et al. (1996) and Crenshaw et al. (1996) from the analysis of the same observational spectral data. The large amplitude rapid variability characteristics obtained in our study have been attributed to the continuum reprocessing of X-rays absorbed by the material in the accretion disk as proposed by Shakura and Sunyaev (1973). The continuum and emission light curves have shown four distinct high amplitude events of flux maxima during the intense monitoring campaign of 15 days, providing a good limit on the amplitude of UV variability and the BLR size in low luminosity Seyfert galaxies and are useful for constraining the continuum emission models. The decreasing \(F_{\mathrm{var}}\) amplitude of UV continuum with respect to increasing wavelength obtained in the present study and consistent with similar observations by Edelson et al. (1996) and Crenshaw et al. (1996) is a significant result of the intense monitoring observations.