Dives into outer Coronado Canyon System

Dives in Lockheed's submarine “Deep Quest” followed the floor of the fan valley and outer gorge of Coronado Canyon, southwest of the California—Baja California border. Both the fan valley and outer gorge have meandering courses. Basin depressions and intermittent steep descents characterize the outer gorge. No indications were found of recent activity of turbidity currents at either location, but a sand layer 30 cm below the surface is interpreted as related to a lower stand of sea level at the close of the last ice age. Abundant organisms were seen on the valley floor and in the overlying water.     

Deep tow studies of the Tamayo transform fault

The Tamayo transform fault occurs at the north end of the East Pacific Rise where it enters the Gulf of California. The two deep-tow surveys reported here show that the transform fault zone changes significantly as a function of distance from the spreading center intersections. At site 1, near the intersection, one side of the fault is young and the fault zone is narrow and well-defined. Strike slip occurs in a zone approximately 1-km wide suggesting a correspondingly narrow zone of decoupling between the Pacific and North American plates. On the young side of the strike-slip zone, normal faults occur along shear zones which are 45°–50° oblique to the transform strike. They occur parallel to the short axis of the strain ellipse for transform fault strain here, i.e., perpendicular to the least compressive stress. The transform walls are formed by normal faulting as has been pointed out in previous detailed surveys. Here, however, the age contrast of 2.5 m.y. across the transform valley is apparent in the morphology of the normal fault scarps. While the scarps are steep and well-defined on the young side, the scarps on the older side have gradual 10°–30° slopes and appear to be primarily talus ramps. Apparently, the scarps have been tectonically eroded by continued strike slip activity after the initial stages of normal faulting. Thus, transform valleys should be quite asymmetric in cross-section where there is a significant age contrast and one side is less than approximately 0.5 m.y. old. Also, along older sections of the transform valley walls, normal faulting may not be at all obvious due to degradation of the scarps by tectonic erosion. This phenomenon makes the likelihood of transform faults providing windows into the oceanic crust most unlikely except in special cases.The picture of transform deformation is more complex at site 2 in the central portion of the fault where both sides of the fault are greater than 1 m.y. old. Here the transform valley is wider (25–30 km as opposed to 2–5 km). There is no clear simple zone of strike slip tectonics. In fact, the only clear evidence for deformation is the intrusion of magmatic or serpentinite diapirs through the sediments of the transform valley floor. The diapirs have deformed the turbidite layers flooring the valley and in one carefully studied case the turbidite sequence has been uplifted, perched atop the diapir. The pattern of deformation on this outcropping diapir shows radial and concentric fractures which can be modeled by a vertical intrusion circular in plan view. Magnetic studies limit the possible composition to basalt or serpentinite. A 60-km-long median ridge is also likely to be the product of intrusion along the transform fault. The survey at site 2 pointed out the importance of vertical tectonics in the transform valley floor and in particular the importance of diapiric intrusions of either basaltic or serpentinite composition.Based on initial boundary conditions and present tectonic elements in the Tamayo fault zone, a possible history of the mouth of the Gulf of California is outlined. The median ridge was emplaced starting approximately 0.8 m.y. ago by regional extension across the transform fault, the result of leaky transform faulting. The diapirs occur along a possible relay zone of extension midway along the fault which began approximately 0.15 m.y. ago. The extension in this case is parallel to the trend of the transform fault, is still occurring at present, and may evolve into a true spreading center.Contribution of the Scripps Institution of Oceanography, new series.     

Comparison of three oxidation methods used for the analysis of the dissolved organic carbon in seawater

Three methods for the determination of dissolved organic carbon in seawater were compared. Samples were analysed using persulphate oxidation, high-temperature combustion, and ultraviolet photo-oxidation. The dissolved organic carbon content of the seawater samples ranged from 0.6 to 1.6 mg C/I. This study shows that results of high-temperature oxidation and photo-oxidation procedures differ by less than 5%, whereas results with persulphate oxidation are about 15% less than those obtained with the high-temperature oxidation. The relative merits of each of the oxidation techniques for the determination of organic matter in seawater are discussed.     

Ridge development as revealed by sub-bottom profiles on the central New Jersey shelf

Closely-spaced 3.5 kHz seismic profiles were collected over the north-easterly trending ridge and swale system 50 km east-southeast of Atlantic City, New Jersey. They yield information on the Late Quaternary depositional history of the area, and on the origin of the ridge system. Four of the sub-bottom reflectors identified were sufficiently persistent to warrant investigation and interpretation. These reflectors, which have been cored, lithologically identified, and radiocarbon dated, are stratigraphically higher than the reflectors dealt with by the majority of previous studies. The upper three reflectors are definitely mid- and post-Wisconsin in age and present a record of the most recent glacial cycle. The upper three units associated with the observed reflectors appear to exert a pronounced influence on the bathymetry. The gently corrugated ridge system of Holocene sand is formed over the regionally flat-lying upper unit, an Early Holocene lagoonal silty clay. The characteristically flat, broad depressions of the area are floored by this lagoonal material. Locally, however, marine scour has cut through the silty clay into an underlying unit of unconsolidated fine Pleistocene sand. Several stages of trough development appear to be represented. After penetrating the lagoonal clay, troughs are initially narrow, but when incised through the sand into a lower, Pleistocene, silty-clay unit, the troughs become notably wider. As downcutting is inhibited by the lower clay, the upper clay is undercut as the trough widens in a fashion similar to a desert blowout.

The sub-bottom reflectors indicate that ridge development on the central shelf has involved aggradation as well as erosion. Some ridges seem to have grown by vertical and lateral accretion from small cores. The internal structure of other ridges suggests that they formed by the coalescence of several small ridges. Others appear to have undergone appreciable lateral migration.

The ridges appear to be in a state of continuing adjustment to the hydraulic regime of the deepening post-Pleistocene water column.     

Seasonal variation of zinc in the barnacle, Balanus balanoides (L.) maintained on a raft in the Menai Strait

A population of the intertidal barnacle, Balanus balanoides (L.) maintained on a raft in the Menai Strait was sampled regularly over a two-year period and pooled fractions analysed for zinc and other trace metals. The seasonal variation of zinc in three fractions (body, other soft tissues and shell) has been followed and related to physiological condition. The body accumulates zinc almost continuously whilst this trace metal accumulates in the ovary only as it develops and is lost in the gametes when these are laid. The newly formed egg-masses therefore may be the more useful sample for indicating zinc pollution.     

The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.     

Hydrophysical state of the Large Aral Sea in the autumn of 2013: Thermal structure,currents, and internal waves

This paper is focused on the hydrophysical state of the western basin of the Large Aral Sea in its present conditions of ecological crisis. The investigation is based on the direct observations carried out during a field survey in the Aral Sea in October of 2013. The analysis of the distribution of the temperature values across the western basin is given. Time series of the water currents variability were recorded at four mooring stations. The pattern of the basin-scale circulation response to the wind forcing was described. Based on the in situ measurements of the time variability of the temperature fields, the principal characteristics of the internal waves were specified for the present-day Aral Sea for the first time.     

Numerical modeling of ocean hydrodynamics with variational assimilation of observational data

Models and methods of the numerical modeling of ocean hydrodynamics dating back to the pioneering works of A.S. Sarkisyan are considered, with emphasis on the formulation of problems and algorithms of mathematical modeling and the four-dimensional variational assimilation of observational data. An algorithm is proposed for studying the sensitivity of the optimal solution to observational data errors in a seasurface temperature assimilation problem in order to retrieve heat fluxes on the surface. An example of a solution of the optimal problem of the World Ocean hydrodynamics with the assimilation of climatic temperature and salinity observations is offered.     

Observations of a cycle of intense coastal upwelling and downwelling at the research site of the Shirshov Institute of Oceanology in the Black Sea

The paper presents the results of joint analysis of the response of vertical temperature and current velocity profile distributions in the coastal zone of the Gelendzhik region of the Black Sea to strong wind forcing in the third ten-day period of September 2013. This forcing was caused by the propagation of an atmospheric cyclone, which first initiated coastal upwelling that was later replaced by downwelling. We formulate a criterion for the development of full coastal upwelling and demonstrate its efficiency. We assume that frequent events of incomplete coastal upwelling and downwelling are associated with changes in the water dynamics (variations in the intensity and direction of the alongshore current) generally not related to local wind forcing.     

Modeling photosynthesis and the growth of marine phytoplankton

The paper analyzes the most popular models of photosynthesis and growth of marine phytoplankton in the literature and demonstrates their limitations. A new approach to modeling is proposed and used to obtain new models of marine phytoplankton photosynthesis and growth. An important feature of the proposed models is their ability to describe coupled multisubstrate cyclical interactions typical of biochemical and physiological processes. As a first approximation, the mathematical models are represented by equations of nonrectangular hyperbolas. The models describe the stoichiometry of extraction of elements from the medium, whatever the degree of their limitation, an important feature in describing biogeochemical cycles of elements. This stoichiometry is governed by measurable internal parameters of an organism (substrate parameters) and can be a key cause of stoichiometric formation of elements in the ambient medium, described, for example, by the Redfield ratio. The substrate constants are fundamental characteristics of the models, which form “automatically” in the construction of model equations in arbitrary units.