Mn-oxides and sequestration of heavy metals in a suburban catchment basin of the Chesapeake Bay watershed

The Chesapeake Bay is greatly impacted by numerous pollutants including heavy metals and understanding the controls on the distribution of heavy metals in the watershed is critical to mitigation and remediation efforts in controlling this type of pollution. Clasts from a stormwater catchment basin draining a subdivision near George Mason University, Fairfax VA (38°50.090°N 78°19.204°W) were investigated using X-ray diffraction (XRD), Scanning electron microcopy (SEM) and energy dispersive spectroscopy (EDS) to determine the nature of Mn-oxide coatings and relationship to bound heavy metals. Mn-oxides are poorly crystalline and occur as subhedral to anhedral platy particles and more rarely as euhedral plates. Micronodules are a commonly observed texture. Chemical compositions of coatings are variable with average major constituent concentrations being Mn (33.38 wt%), Fe (11.88 wt%), Si (7.33 wt%), Al (5.03 wt%), and Ba (0.90 wt%). Heavy metals are found in the coatings with Zn being most prevalent, occurring in approximately 58% of analyses with an average concentration of (0.66 wt%). Minor amounts of Co, Ni, Pb, and Cl are observed. Heavy metals and Cl are interpreted as being derived from road pollution. Mn-oxides can serve as a sequestration mechanism for pollution but may also release heavy metals. Field and laboratory observations indicate Mn-oxides occurring on the surface of the clasts can be mechanically mobilized. This is a mechanism for transporting heavy metals into the Chesapeake Bay watershed. Deicing agents may serve as a mechanism to release heavy metals through cation exchange and increased ionic strength. This is the first detailed mineralogical investigation of Mn-oxides and the roles they may play in pollution in the Chesapeake Bay.     

Anomalous increase in the foF2 critical frequency prior to the Spanish earthquake of May 11, 2011

A study of variations in the critical frequency of the F2 layer (foF2) prior to a shallow-focus eartquake with a magnitude M = 5.1 which occurred in Spain on May 11, 2011, is carried out. The obtained results show that a positive disturbance in the foF2 value was observed at the ionospheric Del’ebre station, which is the closest to the earthquake epicenter. At the same time, no disturbances in foF2 are revealed at ionospheric stations located at a greater distance from the epicenter. This fact makes it possible to conclude that the positive disturbance in the F2 layer observed at the Del’ebre station could have a sesmogenic nature.     

Solar and meteoritic abundance of silicon

Recent lifetime measurements on excited electronic states of neutral silicon (Beckeret al., Phys. Lett. In press, 1980) lead to a reassessment of widely used experimental transition probabilities Garz, Astron. Astrophys., 26, 471–477, 1973 of Si I lines. This translates into a 25% downward revision of the Si abundance determined from the solar spectrum.A solar atomic ratio, Si/Ca = 15.5 is inferred. This value coincides with that found in carbonaceous chondrites, but contrasts with ordinary and enstatite chondrites.     

Tinnunculite,C<Subscript>5</Subscript>H<Subscript>4</Subscript>N<Subscript>4</Subscript>O<Subscript>3</Subscript> · 2H<Subscript>2</Subscript>O: Occurrences on the Kola Peninsula and Redefinition and Validation as a Mineral Species

Based on a study of samples found in the Khibiny (Mt. Rasvumchorr: the holotype) and Lovozero (Mts Alluaiv and Vavnbed) alkaline complexes on the Kola Peninsula, Russia, tinnunculite was approved by the IMA Commission on New Minerals, Nomenclature, and Classification as a valid mineral species (IMA no. 2015-02la) and, taking into account a revisory examination of the original material from burnt dumps of coal mines in the southern Urals, it was redefined as crystalline uric acid dihydrate (UAD), C₅H₄N₄O₃ · 2H₂O. Tinnunculite is poultry manure mineralized in biogeochemical systems, which could be defined as “guano microdeposits.” The mineral occurs as prismatic or tabular crystals up to 0.01 × 0.1 × 0.2 mm in size and clusters of them, as well as crystalline or microglobular crusts. Tinnunculite is transparent or translucent, colorless, white, yellowish, reddish or pale lilac. Crystals show vitreous luster. The mineral is soft and brittle, with a distinct (010) cleavage. D_calc = 1.68 g/cm³ (holotype). Tinnunculite is optically biaxial (–), α = 1.503(3), β = 1.712(3), γ = 1.74(1), 2V_obs = 40(10)°. The IR spectrum is given. The chemical composition of the holotype sample (electron microprobe data, content of H is calculated by UAD stoichiometry) is as follows, wt %: 37.5 О, 28.4 С, 27.0 N, 3.8 H_calc, total 96.7. The empirical formula calculated on the basis of (C + N+ O) = 14 apfu is: C_4.99H₈N_4.07O_4.94. Tinnunculite is monoclinic, space group (by analogy with synthetic UAD) P2₁/c. The unit cell parameters of the holotype sample (single crystal XRD data) are a = 7.37(4), b = 6.326(16), c = 17.59(4) Å, β = 90(1)°, V = 820(5) ų, Z = 4. The strongest reflections in the XRD pattern (d, Å–I[hkl]) are 8.82–84[002], 5.97–15[011], 5.63–24[102?, 102], 4.22–22[112], 3.24–27[114?,114], 3.18–100[210], 3.12–44[211?, 211], 2.576–14[024].     

Light curves of the trans-Neptunian objects 1996 TP66 and 1994 VK8

We have obtained a number of CCD images of two trans-Neptunian objects, 1994 VK8 and 1996 TP66, over two nights. The changes in magnitude of these objects have been examined, in a search for periodic variation. In the case of 1996 TP66, nothing other than random noise can be found to within the errors of ∼0.04 mag. Although a periodic signal is found for 1994 VK8, it appears to be an artefact, as the same frequency appears in the variation of sky brightness and is probably due to the sampling of the data. However, 1994 VK8 does exhibit a variation of ∼0.5 mag. This would suggest either significant non-sphericity or a change in surface composition over a large area. In either case 1994 VK8 warrants further investigation.     

The Use of Geographically Weighted Regression for Spatial Prediction: An Evaluation of Models Using Simulated Data Sets

Increasingly, the geographically weighted regression (GWR) model is being used for spatial prediction rather than for inference. Our study compares GWR as a predictor to (a) its global counterpart of multiple linear regression (MLR); (b) traditional geostatistical models such as ordinary kriging (OK) and universal kriging (UK), with MLR as a mean component; and (c) hybrids, where kriging models are specified with GWR as a mean component. For this purpose, we test the performance of each model on data simulated with differing levels of spatial heterogeneity (with respect to data relationships in the mean process) and spatial autocorrelation (in the residual process). Our results demonstrate that kriging (in a UK form) should be the preferred predictor, reflecting its optimal statistical properties. However the GWR-kriging hybrids perform with merit and, as such, a predictor of this form may provide a worthy alternative to UK for particular (non-stationary relationship) situations when UK models cannot be reliably calibrated. GWR predictors tend to perform more poorly than their more complex GWR-kriging counterparts, but both GWR-based models are useful in that they provide extra information on the spatial processes generating the data that are being predicted.     

Observational maps of the moments of strong line profiles on the solar disk

Using the method of solar bidimensional spectroscopy based on the Universal Birefringent Filter (UBF), we have determined the bidimensional maps of moments of some chromospheric lines. The observational material, referring to a quiet region on the disk center, have been acquired with the UBF of the NSO at Sacramento Peak on Aug. 27,1985. In this note we present the work in progress and the new observational aspects arising from this diagnostic method.Visiting astronomers at the National Solar Observatory/Sacramento Peak, operated by the AURA under contract with the NSF     

Effects of cloud types on cloud-radiation interaction over the Asian monsoon region

This paper quantifies the sensitivity of radiation budget quantities to different cloud types over the Asian monsoon region using the International Satellite Cloud Climatology Project. Multiple regression was used to estimate the radiative effects of individual cloud type. It was observed that the regression performed better when the solution was constrained with clear sky fluxes, which is evident by an improvement in R ² statistics. The sensitivity coefficients calculated for the Asian monsoon region reveal that, while the LWCRCF and SWCRF will be most vulnerable to changes in cloud cover of deep convective clouds, NETCRF will be susceptible to changes in the nimbostratus clouds. Although the cloud radiative forcing of individual cloud types are found to be similar in sign to previous global findings, their magnitudes are found to vary. It is seen that cirrus clouds play an important role in governing the radiative behavior of this region.