High resolution gravimetric geoid heights and gravimetric vertical deflections of Europe including marine areas

Gravimetric geoid heights and gravimetric vertical deflections have been detemined for Europe including the Mediterranean Sea, North Sea, Norwegian Sea, Baltic Sea and parts of the North Atlantic Ocean in a 12′×20′ grid. The computation has been carried out by least squares spectral combination using closed integral formulas, combining 104 000 mean free air gravity anomalies in 6′×10′ blocks, 12 000 mean free air gravity anomalies in 1⁰×1⁰ blocks and the sherical harmonic model GEM9. The precision of the computed geoid heights has been estimated to ±1 m, the precision of the computed vertical deflections has been estimated to ±2″. Comparisons of the gravimetric geoid heights and vertical deflections with a number of other solutions have been carried out, confirming the precision estimation.     

Trace metal-binding proteins in marine molluscs and crustaceans

Some marine invertebrates, such as the American oyster, Crassostrea virginica, the blue crab, callinectes sapidus and the American lobster, Homarusamericanus, concentrate trace metals in their tissues. The occurrence of metallothionein, a low molecular weight, sulfur-containing metal-binding protein, has been correlated with elevated levels of trace metals in these organisms. It is our hypothesis that, whilst metallothioneins are involved in the sequestration of elevated levels of trace metals, they primarily function in regulating normal metal metabolism. In this paper we describe recent field and laboratory experiments designed to examine how oysters, blue crabs and lobsters manage accumulated cadmium, copper and zinc. The possible rôles of metallothionein, as well as the tissue distribution of metals, are emphasized. Metallothioneins were found in all animals we examined; concentrations of metallothioneins and the the amount of bound trace metals are related to time of exposure. We have also demonstrated that the laboratory developed metallothionein models for blue crabs and lobsters may be useful in predicting the partitioning of trace metals in animals living in environments polluted with trace metals.     

Plastic buckling of ring-stiffened conical shells under external hydrostatic pressure

The paper describes experimental tests carried out on three ring-stiffened cones that were tested to destruction under external hydrostatic pressure. The cones were carefully machined from EN1A Steel. All three cones failed by plastic non-symmetric bifurcation buckling in a mode commonly known as general instability. In this mode the entire ring-shell combination buckles bodily.The paper also provides a design chart using the results obtained from these three vessels, together with the results of six other vessels obtained from other tests. The design chart allows the possibility of obtaining a plastic knock down factor, so that the theoretical buckling pressures, based on elastic theory, can be divided by the plastic knockdown factor, to give the predicted buckling pressure. This method can also be used for the design of full-scale vessels.     

Cloning of a chub metallothionein cDNA and development of competitive RT-PCR of chub metallothionein mRNA as a potential biomarker of heavy metal exposure

Metallothionein has been assayed in a range of aquatic animal tissues as an indicator of metal exposure. We sequenced chub (Leuciscus cephalus) metallothionein cDNA which showed over 90% homology to common carp, goldfish and stone loach and 77% homology to rainbow trout sequences for metallothionein. We then used the extended primer method to develop an accurate quantitative competitive RT-PCR assay for metallothionein mRNA. RT-PCR was used to measure metallothionein mRNA in feral chub from a range of field sites, with different levels of heavy metal pollution, in the West Midlands, UK. Measurements were complemented by analysis of liver and gill metallothionein protein by capillary electrophoresis. There was no significant difference in the metallothionein protein levels between fish of different rivers and there was no evidence of elevation of mRNA at the sites of highest metal exposure. The level of metal exposure (e.g. zinc, nickel and cadmium each ranging between 15 and 28 microg/l ) at the pH (7.5-8.5) of these rivers appears insufficient to elevate hepatic or gill metallothionein in chub. A lack of elevation of hepatic metallothionein mRNA in chub exposed to zinc, copper and manganese for 24 h and 10 days in the laboratory also suggests a non-responsiveness of this species.     

Post-Miocene stratigraphy and depositional environments of valley-fill sequences at the mouth of Tampa Bay, Florida

Post-Miocene sea-level low stands allowed rivers and karst processes to incise the exposed carbonate platform along the Gulf Coast of Florida. Few Miocene to mid-Pleistocene deposits survived erosion along the present coast except within incised valleys. Since their formation, these valleys have been filled and incised multiple times in response to sea-level changes. The thick sedimentary sequences underlying the mouth of Tampa Bay have been recorded as a range of depositional environments and multiple sea-level incursions and excursions during pre-Holocene time and subsequent to the accumulation of the Miocene carbonate sequences. Sediment analysis of cores collected from a north–south transect across the mouth of Tampa Bay has enabled the identification of lithofacies, ranging from well-sorted, quartz sand to dense, fossiliferous, phosphatic grainstone. These facies were deposited in freshwater, estuarine, and shallow, open marine environments. As a result of channel development and migration within the paleovalley, and cut-and-fill associated with individual transgressions and regressions, correlation of the lithofacies does not extend across the entire transect. Fining-upward sequences truncated by tidal ravinement surfaces that extend throughout the paleovalley can, however, be identified. Age determinations based on 14-C analysis, amino-acid racemization, and strontium isotope analysis dating of numerous samples yield ages of Miocene, Pliocene, early Pleistocene, and late Pleistocene, as well as Holocene for sequences that accumulated and were preserved in this valley-fill complex. Numerous inconsistencies in the stratigraphic organization of the age determinations indicate that there are bad dates, considerable reworking of shells that were dated, or both. For this reason as well as the lack of detailed correlation among the three relatively complete cores, it is not possible to place these strata in a sequence stratigraphic framework.     

The Potential for Environmentally Sound Development of Marine Deposits of Potassic and Phosphatic Minerals Offshore, Southern Africa

Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits.     

Effects of organic toxicants on the anoxic energy metabolism of the mussel Mytilus edulis

The anoxic rates of heat dissipation by mussels (Mytilus edulis) were enhanced after exposure to pentachlorophenol (PCP) and tributyltin (TBT), both known uncouplers of oxidative phosphorylation. The degree of metabolic activation under anoxia was dependent upon the amount of toxicant accumulated in the tissues, but the concentration-response relationship was different to that under aerobic conditions. Biochemical measurements indicated that the anaerobic metabolic pathways were significantly disturbed by PCP and TBT. There was a decline in succinate, an increase in the fumarate: succinate ratio, and an increase in the accumulation of lactate, indicating a shift from succinate to lactate anaerobic pathways. A consequence of organic toxicant exposure was a reduction in anoxic survival time of mussels.     

The importance of extratropical and tropical cyclones on the short-term evolution of barrier islands along the northern Gulf of Mexico, USA

Data are presented indicating the complexity and highly variable response of beaches to cold front passages along the northern Gulf of Mexico, in addition to the impacts of tropical cyclones and winter storms. Within the past decade, an increase in the frequency of tropical storms and hurricanes impacting the northern Gulf has dramatically altered the long-term equilibrium of a large portion of this coast. A time series of net sediment flux for subaerial and nearshore environments has been established for a section of this coast in Florida, and to a lesser extent, Mississippi. The data incorporate the morphological signature of six tropical storms/hurricanes and more than 200 frontal passages.

Data indicate that (1) barrier islands can conserve mass during catastrophic hurricanes (e.g., Hurricane Opal, a strong category 4 hurricane near landfall); (2) less severe hurricanes and tropical storms can promote rapid dune aggradation and can contribute sediment to the entire barrier system; (3) cold fronts play a critical role in the poststorm adjustment of the barrier by deflating the subaerial portion of the overwash terrace and eroding its marginal lobe along the bayside beach through locally generated, high frequency, steep waves; and (4) barrier systems along the northern Gulf do not necessarily enter an immediate poststorm recovery phase, although nested in sediment-rich nearshore environments. While high wave energy conditions associated with cold fronts play an integral role in the evolution and maintenance of barriers along the northern Gulf, these events are more effective in reworking sediment after the occurrence of extreme events such as hurricanes. This relationship is even more apparent during the clustering of tropical cyclones.

It is anticipated that these findings will have important implications for the longer term evolution of barrier systems in midlatitude, microtidal settings where the clustering of storms is apparent, and winter storms are significant in intensity and frequency along the coast.